出典(authority):フリー百科事典『ウィキペディア（Wikipedia）』「2014/01/31 15:21:39」(JST)
Reverse osmosis (RO) is a water purification technology that uses a semipermeable membrane. This membrane technology is not properly a filtration method. In reverse osmosis, an applied pressure is used to overcome osmotic pressure, a colligative property, that is driven by chemical potential, a thermodynamic parameter. Reverse osmosis can remove many types of molecules and ions from solutions, and is used in both industrial processes and producing potable water. The result is the solute is retained on the pressurized side of the membrane and the pure solvent is allowed to pass to the other side. To be "selective", this membrane should not allow large molecules or ions through the pores (holes), but should allow smaller components of the solution (such as the solvent) to pass freely.
In the normal osmosis process, the solvent naturally moves from an area of low solute concentration (high water potential), through a membrane, to an area of high solute concentration (low water potential). The movement of a pure solvent is driven to reduce the free energy of the system by equalizing solute concentrations on each side of a membrane, generating osmotic pressure. Applying an external pressure to reverse the natural flow of pure solvent, thus, is reverse osmosis. The process is similar to other membrane technology applications. However, key differences are found between reverse osmosis and filtration. The predominant removal mechanism in membrane filtration is straining, or size exclusion, so the process can theoretically achieve perfect exclusion of particles regardless of operational parameters such as influent pressure and concentration. Moreover, reverse osmosis involves a diffusive mechanism, so that separation efficiency is dependent on solute concentration, pressure, and water flux rate.[1] Reverse osmosis is most commonly known for its use in drinking water purification from seawater, removing the salt and other effluent materials from the water molecules.
The process of osmosis through semipermeable membranes was first observed in 1748 by Jean-Antoine Nollet. For the following 200 years, osmosis was only a phenomenon observed in the laboratory. In 1949, the University of California at Los Angeles (UCLA) first investigated desalination of seawater using semipermeable membranes. Researchers from both UCLA and the University of Florida successfully produced fresh water from seawater in the mid-1950s, but the flux was too low to be commercially viable[2] until the discovery at UCLA by Sidney Loeb[3] and Srinivasa Sourirajan at the National Research Council of Canada, Ottawa, of techniques for making asymmetric membranes characterized by an effectively thin "skin" layer supported atop a highly porous and much thicker substrate region of the membrane. By the end of 2001, about 15,200 desalination plants were in operation or in the planning stages worldwide.[1]
Osmosis is a natural process. When two liquids with different concentrations of a solute are separated by a semipermeable membrane, the fluid has a tendency to move from low to high solute concentrations for chemical potential equilibrium.
Formally, reverse osmosis is the process of forcing a solvent from a region of high solute concentration through a semipermeable membrane to a region of low solute concentration by applying a pressure in excess of the osmotic pressure. The largest and most important application of reverse osmosis is the separation of pure water from seawater and brackish waters; seawater or brackish water is pressurized against one surface of the membrane, causing transport of salt-depleted water across the membrane and emergence of potable drinking water from the low-pressure side.
The membranes used for reverse osmosis have a dense layer in the polymer matrix—either the skin of an asymmetric membrane or an interfacially polymerized layer within a thin-film-composite membrane—where the separation occurs. In most cases, the membrane is designed to allow only water to pass through this dense layer, while preventing the passage of solutes (such as salt ions). This process requires that a high pressure be exerted on the high concentration side of the membrane, usually 2–17 bar (30–250 psi) for fresh and brackish water, and 40–82 bar (600–1200 psi) for seawater, which has around 27 bar (390 psi)[4] natural osmotic pressure that must be overcome. This process is best known for its use in desalination (removing the salt and other minerals from sea water to get fresh water), but since the early 1970s, it has also been used to purify fresh water for medical, industrial, and domestic applications.
Around the world, household drinking water purification systems, including a reverse osmosis step, are commonly used for improving water for drinking and cooking.
Such systems typically include a number of steps:
In some systems, the carbon prefilter is omitted, and cellulose triacetate membrane (CTA) is used. The CTA membrane is prone to rotting unless protected by chlorinated water, while the TFC membrane is prone to breaking down under the influence of chlorine. In CTA systems, a carbon postfilter is needed to remove chlorine from the final product, water.
Portable reverse osmosis (RO) water processors are sold for personal water purification in various locations. To work effectively, the water feeding to these units should be under some pressure (40 pounds per square inch (280 kPa) or greater is the norm).[citation needed] Portable reverse osmosis water processors can be used by people who live in rural areas without clean water, far away from the city's water pipes. Rural people filter river or ocean water themselves, as the device is easy to use (saline water may need special membranes). Some travelers on long boating, fishing, or island camping trips, or in countries where the local water supply is polluted or substandard, use reverse osmosis water processors coupled with one or more UV sterilizers. Reverse osmosis systems are also now extensively used by marine aquarium enthusiasts. In the production of bottled mineral water, the water passes through an reverse osmosis water processor to remove pollutants and microorganisms. In European countries, though, such processing of natural mineral water (as defined by a European Directive[5]) is not allowed under European law. In practice, a fraction of the living bacteria can and do pass through reverse osmosis membranes through minor imperfections, or bypass the membrane entirely through tiny leaks in surrounding seals. Thus, complete reverse osmosis systems may include additional water treatment stages that use ultraviolet light or ozone to prevent microbiological contamination.
Membrane pore sizes can vary from 0.1 to 5,000 nm (3.9×10−9 to 0.0001968504 in) depending on filter type. "Particle filtration" removes particles of 1 µm (3.9×10−5 in) or larger. Microfiltration removes particles of 50 nm or larger. Ultrafiltration removes particles of roughly 3 nm or larger. "Nanofiltration" removes particles of 1 nm or larger. Reverse osmosis is in the final category of membrane filtration, "hyperfiltration", and removes particles larger than 0.1 nm.
A reverse osmosis water purification unit (ROWPU) is a portable, self-contained water treatment plant. Designed for military use, it can provide potable water from nearly any water source. There are many models in use by the United States armed forces and the Canadian Forces. Some models are containerized, some are trailers, and some are vehicles unto themselves.
Each branch of the United States armed forces has their own series of reverse osmosis water purification unit models, but they are all similar. The water is pumped from its raw source into the reverse osmosis water purification unit module, where it is treated with a polymer to initiate coagulation. Next, it is run through a multi-media filter where it undergoes ion exchange. It is then pumped through a cartridge filter which is usually spiral-wound cotton. This process clarifies the water of any particles larger than 5 micrometres (0.00020 in) and eliminates almost all turbidity.
The clarified water is then fed through a high-pressure piston pump into a series of vessels where it is subject to reverse osmosis. The product water is free of 90.00–99.98% of the raw water's total dissolved solids and by military standards, should have no more than 1000–1500 parts per million by measure of electrical conductivity. It is then disinfected with chlorine and stored for later use.
Within the United States Marine Corps, the reverse osmosis water purification unit has been replaced by both the Lightweight Water Purification System and Tactical Water Purification Systems .[6] The Lightweight Water Purification Systems can be transported by Humvee and filters 125 US gallons (470 l) per hour. The Tactical Water Purification Systems can be carried on a Medium Tactical Vehicle Replacement truck, and can filter 1,200 to 1,500 US gallons (4,500 to 5,700 l) per hour.
Rain water collected from storm drains is purified with reverse osmosis water processors and used for landscape irrigation and industrial cooling in Los Angeles and other cities, as a solution to the problem of water shortages.
In industry, reverse osmosis removes minerals from boiler water at power plants. The water is distilled multiple times. It must be as pure as possible so it does not leave deposits on the machinery or cause corrosion. The deposits inside or outside the boiler tubes may result in underperformance of the boiler, bringing down its efficiency and resulting in poor steam production, hence poor power production at the turbine.
It is also used to clean effluent and brackish groundwater. The effluent in larger volumes (more than 500 m3/d) should be treated in an effluent treatment plant first, and then the clear effluent is subjected to reverse osmosis system. Treatment cost is reduced significantly and membrane life of the reverse osmosis system is increased.[citation needed]
The process of reverse osmosis can be used for the production of deionized water.
Reverse osmosis process for water purification does not require thermal energy. Flow-through reverse osmosis systems can be regulated by high-pressure pumps. The recovery of purified water depends upon various factors, including membrane sizes, membrane pore size, temperature, operating pressure, and membrane surface area.
In 2002, Singapore announced that a process named NEWater would be a significant part of its future water plans. It involves using reverse osmosis to treat domestic wastewater before discharging the NEWater back into the reservoirs.
In addition to desalination, reverse osmosis is a more economical operation for concentrating food liquids (such as fruit juices) than conventional heat-treatment processes. Research has been done on concentration of orange juice and tomato juice. Its advantages include a lower operating cost and the ability to avoid heat-treatment processes, which makes it suitable for heat-sensitive substances such as the protein and enzymes found in most food products.
Reverse osmosis is extensively used in the dairy industry for the production of whey protein powders and for the concentration of milk to reduce shipping costs. In whey applications, the whey (liquid remaining after cheese manufacture) is concentrated with reverse osmosis from 6% total solids to 10–20% total solids before ultrafiltration (UF) processing. The ultrafiltration retentate can then be used to make various whey powders, including whey protein isolate. Additionally, the ultrafiltration permeate, which contains lactose, is concentrated by reverse osmosis from 5% total solids to 18–22% total solids to reduce crystallization and drying costs of the lactose powder.
Although use of the process was once avoided in the wine industry, it is now widely understood and used. An estimated 60 reverse osmosis machines were in use in Bordeaux, France, in 2002. Known users include many of the elite classed growths (Kramer) such as Château Léoville-Las Cases in Bordeaux.[citation needed]
In 1946, some maple syrup producers started using reverse osmosis to remove water from sap before the sap is boiled down to syrup. The use of reverse osmosis allows about 75-90% of the water to be removed from the sap, reducing energy consumption and exposure of the syrup to high temperatures. Microbial contamination and degradation of the membranes must be monitored.
For small-scale hydrogen production, reverse osmosis is sometimes used to prevent formation of minerals on the surface of electrodes.
Many reef aquarium keepers use reverse osmosis systems for their artificial mixture of seawater. Ordinary tap water can contain excessive chlorine, chloramines, copper, nitrates, nitrites, phosphates, silicates, or many other chemicals detrimental to the sensitive organisms in a reef environment. Contaminants such as nitrogen compounds and phosphates can lead to excessive and unwanted algae growth. An effective combination of both reverse osmosis and deionization (RO/DI) is the most popular among reef aquarium keepers, and is preferred above other water purification processes due to the low cost of ownership and minimal operating costs. Where chlorine and chloramines are found in the water, carbon filtration is needed before the membrane, as the common residential membrane used by reef keepers does not cope with these compounds.
An increasingly popular method of cleaning windows is the so-called "water-fed pole" system. Instead of washing the windows with detergent in the conventional way, they are scrubbed with highly purified water, typically containing less than 10 ppm dissolved solids, using a brush on the end of a long pole which is wielded from ground level. Reverse osmosis is commonly used to purify the water.[7]
Areas that have either no or limited surface water or groundwater may choose to desalinate. Reverse osmosis is an increasingly common method of desalination, because of its relatively low energy consumption. In recent years, energy consumption has dropped to around 3 kWh/m3, with the development of more efficient energy recovery devices and improved membrane materials. According to the International Desalination Association, for 2011, reverse osmosis was used in 66% of installed desalination capacity (44.5 of 67.4 Mm3/day), and nearly all new plants.[8] Other plants mainly use thermal distillation methods: Multiple-effect distillation and multi-stage flash.
Sea water reverse osmosis (SWRO) desalination, a membrane process, has been commercially used since the early 1970s. Its first practical use was demonstrated by Sidney Loeb from UCLA in Coalinga, California, and Srinivasa Sourirajan of NRC, Canada. Because no heating or phase changes are needed, energy requirements are low, around 3 kWh/m3, in comparison to other processes of desalination, but are still much higher than those required for other forms of water supply, including reverse osmosis treatment of wastewater, at 0.1 to 1 kWh/m3. See WIKI "Desalination". Up to 50% of the seawater input can be recovered as fresh water, though lower recoveries may reduce membrane fouling and energy consumption.
Brackish water reverse osmosis refers to desalination of water with a lower salt content than sea water, usually from river estuaries or saline wells. The process is substantially the same as sea water reverse osmosis, but requires lower pressures and therefore less energy. Up to 80% of the feed water input can be recovered as fresh water, depending on feed salinity.
The Ashkelon sea water reverse osmosis desalination plant in Israel is the largest in the world.[9][10] The project was developed as a build-operate-transfer by a consortium of three international companies: Veolia water, IDE Technologies, and Elran.[11]
The typical single-pass sea water reverse osmosis system consists of:
Pretreatment is important when working with reverse osmosis and nanofiltration (NF) membranes due to the nature of their spiral-wound design. The material is engineered in such a fashion as to allow only one-way flow through the system. As such, the spiral-wound design does not allow for backpulsing with water or air agitation to scour its surface and remove solids. Since accumulated material cannot be removed from the membrane surface systems, they are highly susceptible to fouling (loss of production capacity). Therefore, pretreatment is a necessity for any reverse osmosis or nanofiltration system. Pretreatment in sea water reverse osmosis systems has four major components:
The high pressure pump supplies the pressure needed to push water through the membrane, even as the membrane rejects the passage of salt through it. Typical pressures for brackish water range from 225 to 375 psi (15.5 to 26 bar, or 1.6 to 2.6 MPa). In the case of seawater, they range from 800 to 1,180 psi (55 to 81.5 bar or 6 to 8 MPa). This requires a large amount of energy. Where energy recovery is used, all or part of the high pressure pump's work is done by the energy recovery device, reducing the system energy input.
The membrane assembly consists of a pressure vessel with a membrane that allows feedwater to be pressed against it. The membrane must be strong enough to withstand whatever pressure is applied against it. reverse osmosis membranes are made in a variety of configurations, with the two most common configurations being spiral-wound and hollow-fiber.
Only a part of the saline feed water pumped into the membrane assembly passes through the membrane with the salt removed. The remaining "concentrate" flow passes along the saline side of the membrane to flush away the concentrated salt solution. The percentage of desalinated water produced versus the saline water feed flow is known as the "recovery ratio". This varies with the salinity of the feed water and the system design parameters: typically 20% for small seawater systems, 40% for larger seawater systems, and 80% for brackish water. The concentrate flow is at typically only 3 bar / 50 psi less than the feed pressure, and thus still carries much of the high pressure pump input energy.
The desalinated water purity is a function of the system design. Higher purity needs more equipment and more energy. Purity expressed as total dissolved solids typically varies from 100 to 400 parts per million (ppm or milligram/litre). A level of 500 ppm is generally accepted as the upper limit for drinking water, while the US Food and Drug Administration classifies mineral water as water containing at least 250 ppm.
Energy recovery can reduce energy consumption by 50% or more. Much of the high pressure pump input energy can be recovered from the concentrate flow, and the increasing efficiency of energy recovery devices has greatly reduced the energy needs of reverse osmosis desalination. Devices used, in order of invention, are...
Schematics of a reverse osmosis desalination system using a pressure exchanger.
1: Sea water inflow,
2: Fresh water flow (40%),
3: Concentrate flow (60%),
4: Sea water flow (60%),
5: Concentrate (drain),
Schematic of a reverse osmosis desalination system using a pressure recovery pump.
1: Sea water inflow (100%, 1 bar),
2: Sea water flow (100%, 50 bar),
3: Concentrate flow (60%, 48 bar),
4: Fresh water flow (40%, 1 bar),
5: Concentrate to drain (60%,1 bar),
The desalinated water is "stabilized" to protect downstream pipelines and storages, usually by adding lime or caustic to prevent corrosion of concrete-lined surfaces. Liming material is used to adjust pH between 6.8 and 8.1 to meet the potable water specifications, primarily for effective disinfection and for corrosion control. Remineralisation may be needed to replace minerals removed from the water by desalination.
Post-treatment consists of preparing the water for distribution after filtration. Reverse osmosis is an effective barrier to pathogens, but post-treatment provides secondary protection against compromised membranes and downstream problems. Disinfection by means of UV lamps (sometimes called germicidal or bactericidal) may be employed to sterilize pathogens which bypassed the reverse osmosis process. Chlorination or chloramination (chlorine and ammonia) protects against pathogens which may have lodged in the distribution system downstream, such as from new construction, backwash, compromised pipes, etc.[citation needed]
Household reverse osmosis units use a lot of water because they have low back pressure. As a result, they recover only 5 to 15% of the water entering the system. The remainder is discharged as waste water. Because waste water carries with it the rejected contaminants, methods to recover this water are not practical for household systems. Wastewater is typically connected to the house drains and will add to the load on the household septic system. An reverse osmosis unit delivering five gallons of treated water per day may discharge between 20 and 90 gallons of waste water per day.[18]
Large-scale industrial/municipal systems recover typically 75% to 80% of the feed water, or as high as 90%, because they can generate the high pressure needed for higher recovery reverse osmosis filtration. On the other hand, as recovery of wastewater increases in commercial operations, effective contaminant removal rates tend to become reduced, as evidenced by product water total dissolved solids levels.
Due to its fine membrane construction, reverse osmosis not only removes harmful contaminants present in the water, but it also may strip many of the good, healthy minerals from the water. A number of peer-reviewed studies have looked at the long-term health effects of drinking demineralized water.[19] However, demineralized water can be remineralized and this process has been done in instances when processing demineralized water for consumption. An example of this process is Dasani, which adds sodium chloride (salt) and potassium chloride to its water for "taste", according to the company.[20]
Prefiltration of high-fouling waters with another, larger-pore membrane with less hydraulic energy requirement, has been evaluated and sometimes used, since the 1970s. However, this means the water passes through two membranes and is often repressurized, requiring more energy input in the system, increasing the cost.
Other recent development work has focused on integrating reverse osmosis with electrodialysis to improve recovery of valuable deionized products or minimize concentrate volume requiring discharge or disposal.
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