出典(authority):フリー百科事典『ウィキペディア（Wikipedia）』「2016/11/25 23:37:21」(JST)
| Names | |
|---|---|
| IUPAC name
Zinc acetate
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| Other names
Acetic acid, Zinc salt
Acetic acid, Zinc(II) salt |
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| Identifiers | |
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CAS Number
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557-34-6 Y 5970-45-6 N |
| 3D model (Jmol) | Interactive image |
| ChEMBL | ChEMBL1200928 N |
| ChemSpider | 10719 Y |
| ECHA InfoCard | 100.008.338 |
| E number | E650 (flavour enhancer) |
| PubChem | 11192 |
| RTECS number | ZG8750000 |
| UNII | H2ZEY72PME Y |
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InChI
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SMILES
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| Properties | |
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Chemical formula
|
ZnC4H6O4 (dihydrate) |
| Molar mass | 219.50 g/mol (dihydrate) 183.48 g/mol (anhydrous) |
| Appearance | White solid (all forms) |
| Density | 1.735 g/cm3 (dihydrate) |
| Melting point | Decomposes at 237 °C (459 °F; 510 K) (dihydrate loses water at 100 °C) |
| Boiling point | decomposes |
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Solubility in water
|
43 g/100 mL (20 °C, dihydrate) |
| Solubility | soluble in alcohol |
| Structure | |
|
Coordination geometry
|
octahedral (dihydrate) |
|
Molecular shape
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tetrahedral |
| Pharmacology | |
|
ATC code
|
A16AX05 (WHO) |
| Hazards | |
| Main hazards | mildly toxic |
| R-phrases | R22 R36 R50/53 |
| S-phrases | S26 S60 S61 |
| Related compounds | |
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Other anions
|
Zinc chloride |
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Other cations
|
Copper(II) acetate |
|
Related compounds
|
Basic beryllium acetate |
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Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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| N verify (what is YN ?) | |
| Infobox references | |
Zinc acetate is a salt with the formula Zn(O2CCH3)2, which commonly occurs as the dihydrate Zn(O2CCH3)2(H2O)2. Both the hydrate and the anhydrous forms are colorless solids that are commonly used in chemical synthesis and as dietary supplements. Zinc acetates are prepared by the action of acetic acid on zinc carbonate or zinc metal. When used as a food additive, it has the E number E650.
In anhydrous zinc acetate the zinc is coordinated to four oxygen atoms to give a tetrahedral environment, these tetrahedral polyhedra are then interconnected by acetate ligands to give a range of polymeric structures.[1][2][3] In contrast, most metal diacetates feature metals in octahedral coordination with bidentate acetate groups.
In zinc acetate dihydrate the zinc is octahedral, wherein both acetate groups are bidentate.[4][5]
Heating Zn(CH3CO2)2 in a vacuum results in a loss of acetic anhydride, leaving a residue of basic zinc acetate, with the formula Zn4O(CH3CO2)6. This cluster compound has the tetrahedral structure shown below. This species closely resembles the corresponding beryllium compound, although it is slightly expanded with Zn-O distances ~1.97 vs ~1.63 Å for Be4O(OAc)6.[6]
Zinc acetate has been used in lozenges for treating the common cold. Pooling the results of three high dose zinc acetate trials indicates an average 42% reduction in the duration of colds (see figure).[7]
Zinc acetate is a particularly useful salt in lozenges since acetate has relatively low affinity for zinc, with the result that essentially all zinc from the lozenges is freely released upon solvation in the saliva.[8][9]
Although zinc acetate lozenges appear to be able to shorten the duration of colds, some zinc lozenges may be more effective than others. Among the factors affecting the usefulness of a zinc lozenge are the total dose of zinc provided as well as the presence of substances like citric acid which may bind up much of the zinc that the lozenge is providing.[10]
Zinc acetate can also be used to treat zinc deficiencies. As an oral daily supplement it is used to inhibit the body's absorption of copper as part of the treatment for Wilson's disease. Zinc acetate is also sold as an astringent in the form of an ointment, a topical lotion, or combined with an antibiotic such as erythromycin for the topical treatment of acne. It is commonly sold as a topical anti-itch ointment.
In chewing gum, zinc acetate is a breath freshener[11][12] and, when combined with hexetidine, a plaque inhibitor.[13]
Industrial applications include wood preservation, manufacturing other zinc salts, polymers, manufacture of ethylene acetate, as a dye mordant, and analytical reagent. It is used in commercial nuclear power plants as a plating inhibitor on primary water piping.
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| リンク元 | 「亜鉛」 |