プロピル基
WordNet
- arrange into a group or groups; "Can you group these shapes together?"
- (chemistry) two or more atoms bound together as a single unit and forming part of a molecule (同)radical, chemical group
- any number of entities (members) considered as a unit (同)grouping
- a set that is closed, associative, has an identity element and every element has an inverse (同)mathematical group
- form a group or group together (同)aggroup
- the activity of putting things together in groups
- a system for classifying things into groups (同)pigeonholing
- a support placed beneath or against something to keep it from shaking or falling
- the monovalent organic group C3H7- obtained from propane (同)propyl_group, propyl radical
- arranged into groups (同)sorted
PrepTutorEJDIC
- (…の)『群れ』,集まり,小集団《+of+名》 / (主義・系統・種類などを同じくする人・物の)『派』,『団体』 / (ポミュラーソング歌手の)グループ / (動・植物分類上の)群;(化学の)基,原子団;(地質学上の)界;(数学の)群;(言語学上の)語派 / …‘を'一群に集める,一団にする《+『名』+『together』》 / (系統的に)…‘を'分類する,調和よく配合する《+『名』+『together』》 / 集まる,群(集団)をなす
- グループに分けること;分類法 / (集まった物の)配置,配合
- 支柱,支え / 支えとなる人(物) / …‘を'支える / (…に)…‘を'寄りかからせる《+『名』+『against』+『名』》
- (劇場の)小道具
- プロペラ
Wikipedia preview
出典(authority):フリー百科事典『ウィキペディア(Wikipedia)』「2019/07/10 22:06:23」(JST)
[Wiki en表示]
From left to right: the two isomeric groups propyl and 1-methylethyl (iPr or isopropyl), and the non-isomeric cyclopropyl group.
In organic chemistry, propyl is a three-carbon alkyl substituent with chemical formula –CH
2CH
2CH
3 for the linear form. This substituent form is obtained by removing one hydrogen atom attached to the terminal carbon of propane. [1] A propyl substituent is often represented in organic chemistry with the symbol Pr (not to be confused with the element praseodymium).
An isomeric form of propyl is obtained by moving the point of attachment from a terminal carbon atom to the central carbon atom, named 1-methylethyl or isopropyl. To maintain four substituents on each carbon atom, one hydrogen atom has to be moved from the middle carbon atom to the carbon atom which served as attachment point in the n-propyl variant, written as –CH(CH
3)2.[2]
Linear propyl is sometimes termed normal and hence written with a prefix n- (i.e., n-propyl), as the absence of the prefix n- does not indicate which attachment point is chosen, i.e. absence of prefix does not automatically exclude the possibility of it being the branched version (i.e. i-propyl or isopropyl).[3]
In addition, there is a third, cyclic, form called cyclopropyl, or c-propyl. It is not isomeric with the other two forms, having the chemical formula -C3H5.
Examples
n-Propyl acetate is an ester which has the n-propyl group attached to the oxygen atom of the acetate group.
Chemical structure of propyl acetate.
Other examples
References
- ^ IUPAC Nomenclature - Acyclic Hydrocarbons Rule A-1.
- ^ IUPAC Nomenclature - Acyclic Hydrocarbons Rule A-2.
- ^ IUPAC Nomenclature - Acyclic Hydrocarbons Rule A-1.
Functional groups |
---|
Only carbon, hydrogen, and oxygen | Hydrocarbons |
- Allene
- Alkene (Allyl, Vinyl)
- Alkyl (Methyl, Ethyl, Propyl, Butyl, Pentyl)
- Alkyne
- Benzyl
- Carbene
- Cumulene
- Methylene bridge
- Methylene group
- Methine
- Phenyl
|
---|
Other |
- Acetoxy
- Acetyl
- Acryloyl
- Acyl
- Aldehyde
- Alkoxy (Methoxy)
- Benzoyl
- Carbonyl
- Carboxyl
- Carboxylic anhydride
- Dioxirane
- Epoxide
- Ester
- Ether
- Ethylenedioxy
- Hydroxy
- Ketone
- Methylenedioxy
- Peroxide (Organic)
- Ynone
|
---|
|
---|
Only one element apart from C, H, O | Nitrogen |
- Amine
- Azo compound
- Cyanate
- Hydrazone
- Imide
- Imine
- Isocyanate
- Isonitrile
- Nitrene
- Nitrile
- Nitro compound
- Nitroso compound
- Organic amide
- Oxime
|
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Phosphorus | |
---|
Sulfur |
- Disulfide
- Sulfone
- Sulfonic acid
- Sulfoxide
- Thial
- Thioester
- Thioether
- Thioketone
- Thiol
|
---|
Selenium |
- Selenol
- Selenonic acid
- Seleninic acid
- Selenenic acid
- Selone
|
---|
Tellurium | |
---|
|
---|
Other |
- Isothiocyanate
- Phosphoramide
- Sulfenyl chloride
- Sulfonamide
- Thiocyanate
|
---|
|
See also chemical classification, chemical nomenclature (inorganic, organic) |
UpToDate Contents
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English Journal
- In vivo oestrogenic modulation of Egr1 and Pitx1 gene expression in female rat pituitary gland.
- Gajewska A1, Herman AP2, Wolińska-Witort E2, Kochman K2, Zwierzchowski L2.
- Journal of molecular endocrinology.J Mol Endocrinol.2014 Dec;53(3):355-66. doi: 10.1530/JME-14-0092. Epub 2014 Sep 25.
- EGR1 and PITX1 are transcription factors required for gonadotroph cell Lhb promoter activation. To determine changes in Egr1 and Pitx1 mRNA levels in central and peripheral pituitary stimulations, an in vivo model based on i.c.v. pulsatile (1 pulse/0.5 h over 2 h) GnRH agonist (1.5 nM busereli
- PMID 25258388
- Roles of Estrogen in the Formation of Intracranial Aneurysms in Ovariectomized Female Mice.
- Tada Y1, Makino H, Furukawa H, Shimada K, Wada K, Liang EI, Murakami S, Kudo M, Kung DK, Hasan DM, Kitazato KT, Nagahiro S, Lawton MT, Hashimoto T.
- Neurosurgery.Neurosurgery.2014 Dec;75(6):690-695.
- BACKGROUND:: Epidemiological studies have indicated that postmenopausal women have a higher incidence of intracranial aneurysms than men in the same age group.OBJECTIVE:: To investigate whether estrogen or estrogen receptors (ERs) mediate protective effects against the formation of intracranial aneu
- PMID 25181430
- A multiresidue method for the determination of selected endocrine disrupting chemicals in human breast milk based on a simple extraction procedure.
- Rodríguez-Gómez R1, Jiménez-Díaz I1, Zafra-Gómez A2, Ballesteros O1, Navalón A1.
- Talanta.Talanta.2014 Dec;130:561-70. doi: 10.1016/j.talanta.2014.07.047. Epub 2014 Jul 26.
- In recent decades, in parallel to industrial development, a large amount of new chemicals have emerged that are able to produce disorders in human endocrine system. These groups of substances, so-called endocrine disrupting chemicals (EDCs), include many families of compounds, such as parabens, benz
- PMID 25159447
Japanese Journal
- Journal of Toxicologic Pathology
- Masubuchi Yasunori,Koyanagi Mihoko,Hayashi Shim-mo,Shibutani Makoto,Tanaka Takaharu,Okada Rena,Ito Yuko,Nakahara Junta,Kikuchi Satomi,Watanabe Yousuke,Yoshida Toshinori,Maronpot Robert R.
- Journal of Toxicologic Pathology 32(3), 165-180, 2019
- … Mated female Sprague Dawley rats were either untreated (control) or treated with 12 ppm 6-propyl-2-thiouracil (PTU), an anti-thyroid agent, in drinking water from gestational day 6 to postnatal day (PND) 21, the latter group being subjected to feeding basal diet alone or diet containing AGIQ at 5,000 ppm or ALA at 2,000 ppm during PTU exposure. …
- NAID 130007682142
- Journal of Health Science
- Kim Seon Woong,Lee Taeho,Oh Yoon Sin,Shin Sang Mi,Lee Joo-Youn,Kim Sanghee,Baek Dong Jae,Park Eun-Young
- CHEMICAL & PHARMACEUTICAL BULLETIN 67(6), 599-603, 2019
- … In a recently reported study by Pfizer on the synthesis of PF-543 derivatives and the SK inhibitory effects, the introduction of propyl moiety into sulfonyl group of PF-543 in the case of <b>26b</b> …
- NAID 130007657410
- Tris (1,3-dichloro-2-propyl) phosphate treatment induces DNA damage, cell cycle arrest and apoptosis in murine RAW264.7 macrophages
- Zhang Wei,Wang Ruiguo,Giesy John P.,Li Yang,Wang Peilong
- The Journal of Toxicological Sciences 44(3), 133-144, 2019
- … <p>Tris (1,3-dichloro-2-propyl) phosphate (TDCPP) is the most widely used organophosphorus flame retardant, which is now used instead of polybrominated diphenyl ethers (PBDEs). … TDCPP increased the intracellular reactive oxygen species (ROS) level in RAW264.7 cells up to 1.44-fold compared to the control group at 12 hr. …
- NAID 130007608297
Related Links
- Propyl group Related terms: Acetyl group, activating group, acyl group, alkanoyl group, alkoxy group, alkyl group, allyl group, amino group , benzoyl group, benzyl group, butyl group, carbonyl group, ...
- Propyl group is the name given to the portion of an organic molecule that is derived from propane and has the molecular structure -CH 2 CH 3. A propyl group can be abbreviated -Pr. The propyl group is one of the alkyl groups defined ...
- 4-Ethyl-4-methyloctane 96 is a simple chiral hydrocarbon, where methyl, ethyl, propyl, and butyl groups are bonded to a quaternary carbon of chiral center (Fig. 7.25). The four alkyl groups are similar to each other, and hence its ...
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