金化合物

WordNet

pass, fare, or elapse; of a certain state of affairs or action; "How is it going?"; "The day went well until I got your call"
a time for working (after which you will be relieved by someone else); "its my go"; "a spell of work" (同)spell, tour, turn
be abolished or discarded; "These ugly billboards have to go!"; "These luxuries all had to go under the Khmer Rouge"
a board game for two players who place counters on a grid; the object is to surround and so capture the opponents counters (同)go game
move away from a place into another direction; "Go away before I start to cry"; "The train departs at noon" (同)go away, depart
lead, extend, or afford access; "This door goes to the basement"; "The road runs South" (同)lead
follow a procedure or take a course; "We should go farther in this matter"; "She went through a lot of trouble"; "go about the world in a certain manner"; "Messages must go through diplomatic channels" (同)proceed, move
be awarded; be allotted; "The first prize goes to Mary"; "Her money went on clothes"
be contained in; "How many times does 18 go into 54?"
be or continue to be in a certain condition; "The children went hungry that day"
be ranked or compare; "This violinist is as good as Juilliard-trained violinists go"
be sounded, played, or expressed; "How does this song go again?"
be spent; "All my money went for food and rent"
functioning correctly and ready for action; "all systems are go"
create by mixing or combining
(chemistry) a substance formed by chemical union of two or more elements or ingredients in definite proportion by weight (同)chemical_compound
put or add together; "combine resources" (同)combine
an enclosure of residences and other building (especially in the Orient)
a whole formed by a union of two or more elements or parts
combine so as to form a whole; mix; "compound the ingredients" (同)combine
calculate principal and interest
composed of more than one part; "compound leaves are composed of several lobes; "compound flower heads"
consisting of two or more substances or ingredients or elements or parts; "soap is a compound substance"; "housetop is a compound word"; "a blackberry is a compound fruit"
made from or covered with gold; "gold coins"; "the gold dome of the Capitol"; "the golden calf"; "gilded icons" (同)golden, gilded
a soft yellow malleable ductile (trivalent and univalent) metallic element; occurs mainly as nuggets in rocks and alluvial deposits; does not react with most chemicals but is attacked by chlorine and aqua regia (同)Au, atomic number 79
coins made of gold
great wealth; "Whilst that for which all virtue now is sold, and almost every vice--almighty gold"--Ben Jonson
something likened to the metal in brightness or preciousness or superiority etc.; "the child was as good as gold"; "she has a heart of gold"
combined into or constituting a chemical compound

PrepTutorEJDIC

《方向・場所を表す副詞[句]を伴って》『行く』,動く;(目的地に関係なく)進む,動く / (ある事をしに)『行く』: / 《副詞[句]を伴って》『立ち去る』,出かける,出発する / 〈機械などが〉(順調に)動く / 《副詞[句]を伴って》〈事が〉『運ぶ』,進展する / (ある状態に)『なる』,変わる / 《『go』+『名』(『形,過分』)〈補〉》(ある状態の)『ままである』 / (…から…に)向かっている,延びている《+『from』+『名』+『to』+『名』》(進行形にできない) / 〈賞品・財産などが〉(…の)ものとなる,(…の手に)渡る《+『to』+『名』》 / 〈金などが〉(…に)使用される,充当される》+『for』(『on,to』)+『名』》 / 有郊である,役立つ / 《副詞[句]を伴って》〈時間が〉過ぎる / 売られる,売れる / なくなる,つぶれる,死ぬ / 《must,can,have toと共に》捨てられる,無用にされる / 《副詞[句]を伴って》(あるべき場所に)位置する,納まる / 〈数量などが〉(…に)等しい《+『to』+『名』》;〈数が〉(…に)含まれる《+『into』+『名』》 / 《副詞[句]を伴って》音を出す,鳴る / 始める,行動に移る / 《副詞[句]を伴って》〈事が〉(…と)なっている(進行形にできない) / 《『as』+『名』+『go』の形で》普通…である,一般には…である / 《『go』『and』 do》《話》 / …しに行く / (愚かにも,不運にも)…をする / 《単なる強調で》…する / 《『go』『going』『to』 do》 / 《話している人の意志》(…する,させる)『つもりである』 / 《可能性・見込み》(…し)『そうである』 / 《近い未来》(…し)ようとしている / 《『go』 do『ing』》 / 《否定文・疑問文で》…するようなことをする / 《『go』+『名』》(…を,に) / 〈C〉行くこと,去ること,進行 / 〈U〉《話》活力,精力 / 〈C〉《話》試し,試み / 〈C〉《単数形で》(ゲームなどでの)番,順番
(…になるように)〈要素・成分など〉'を'混ぜ合わせる《+『名』+『into』+『名』》;(…から)〈薬など〉'を'調合する,混ぜ合わせて作る《+『名』+『from』(『of』)+『名』》 / 《しばしば受動態で》〈めんどうな事・損害など〉'を'もっとひどくする / 〈利子〉'を'複利で計算する / (…と)話し合いをつける,妥協する《+『with』+『名』》 / 複合の,合成の / 『合成物』,混合物,調合物;化合物 / 複合語,合成語(classroom, heart-to-heartなどをいう)
(異民族の家屋・商館などがある)囲み地区,構内
『金』,黄金(おうごん) / 《集合的に》『金貨』(gold coins) / 金銭,富,財宝 / 黄金色,金色 / 《しばしば…of goldの形で》(金のように)価値のあるもの;純真,親切 / 『金の』,金製の / 金色の

Wikipedia preview

出典(authority):フリー百科事典『ウィキペディア（Wikipedia）』「2016/09/14 12:47:48」(JST)

wiki en

Gold is a chemical element with the symbol Au (from Latin: aurum) and the atomic number 79. In its purest form, it is a bright, slightly reddish yellow, dense, soft, malleable and ductile metal. Chemically, gold is a transition metal and a group 11 element. It is one of the least reactive chemical elements, and is solid under standard conditions. The metal therefore occurs often in free elemental (native) form, as nuggets or grains, in rocks, in veins and in alluvial deposits. It occurs in a solid solution series with the native element silver (as electrum) and also naturally alloyed with copper and palladium. Less commonly, it occurs in minerals as gold compounds, often with tellurium (gold tellurides).

Gold's atomic number of 79 makes it one of the higher atomic number elements that occur naturally in the universe. It is thought to have been produced in supernova nucleosynthesis and from the collision of neutron stars^[4] and to have been present in the dust from which the Solar System formed. Because the Earth was molten when it was just formed, almost all of the gold present in the early Earth probably sank into the planetary core. Therefore, most of the gold that is present today in the Earth's crust and mantle is thought to have been delivered to Earth later, by asteroid impacts during the Late Heavy Bombardment, about 4 billion years ago.^[5]^[6]

Gold resists attack by individual acids, but aqua regia (literally "royal water", a mixture of nitric acid and hydrochloric acid) can dissolve it. The acid mixture causes the formation of a soluble tetrachloroaurate anion. It is insoluble in nitric acid, which dissolves silver and base metals, a property that has long been used to refine gold and to confirm the presence of gold in metallic objects, giving rise to the term acid test. Gold also dissolves in alkaline solutions of cyanide, which are used in mining and electroplating. Gold dissolves in mercury, forming amalgam alloys, but this is not a chemical reaction.

Gold is a precious metal used for coinage, jewelry, and other arts throughout recorded history. In the past, a gold standard was often implemented as a monetary policy within and between nations, but gold coins ceased to be minted as a circulating currency in the 1930s, and the world gold standard was abandoned for a fiat currency system after 1976. The historical value of gold was rooted in its relative rarity, easy handling and minting, easy smelting and fabrication, resistance to corrosion and other chemical reactions (nobility), and distinctive color^{[citation needed]}.

A total of 183,600 tonnes of gold is in existence above ground, as of 2014.^[7] This is equivalent to 9513 m³ of gold. The world consumption of new gold produced is about 50% in jewelry, 40% in investments, and 10% in industry.^[8] Gold's high malleability, ductility, resistance to corrosion and most other chemical reactions, and conductivity of electricity have led to its continued use in corrosion resistant electrical connectors in all types of computerized devices (its chief industrial use). Gold is also used in infrared shielding, colored-glass production, gold leafing, and tooth restoration. Certain gold salts are still used as anti-inflammatories in medicine.

1 Etymology
2 Characteristics
3 Chemistry
- 3.1 Less common oxidation states
- 3.2 Mixed valence compounds
- 3.3 Color
- 3.4 Isotopes
4 Modern applications
- 4.1 Jewelry
- 4.2 Investment
- 4.3 Electronics connectors
- 4.4 Non-electronic industry
- 4.5 Commercial chemistry
- 4.6 Medicine
- 4.7 Food and drink
5 Monetary exchange (historical)
6 Cultural history
7 Occurrence
- 7.1 Seawater
- 7.2 Specimens of crystalline native gold
8 Production
9 Mining
- 9.1 Prospecting
10 Bioremediation
11 Extraction
- 11.1 Refining
12 Synthesis from other elements
13 Consumption
14 Pollution
15 Toxicity
16 Price
- 16.1 History
17 Symbolism
18 See also
19 References
20 Further reading
21 External links

Etymology

"Gold" is cognate with similar words in many Germanic languages, deriving via Proto-Germanic *gulþą from Proto-Indo-European *ǵʰelh₃- ("to shine, to gleam; to be yellow or green").^[9]^[10]

The symbol Au is from the Latin: aurum, the Latin word for "gold".^[11] The Proto-Indo-European ancestor of aurum was *h₂é-h₂us-o-, meaning "glow". This word is derived from the same root (Proto-Indo-European *h₂u̯es- "to dawn") as *h₂éu̯sōs, the ancestor of the Latin word Aurora, "dawn".^[12] This etymological relationship is presumably behind the frequent claim in scientific publications that aurum meant "shining dawn".^[13]

Characteristics

Gold is the most malleable of all metals; a single gram can be beaten into a sheet of 1 square meter, and an ounce into 300 square feet. Gold leaf can be beaten thin enough to become transparent. The transmitted light appears greenish blue, because gold strongly reflects yellow and red.^[14] Such semi-transparent sheets also strongly reflect infrared light, making them useful as infrared (radiant heat) shields in visors of heat-resistant suits, and in sun-visors for spacesuits.^[15] Gold is a good conductor of heat and electricity and reflects infrared radiation strongly.

In addition, gold is very dense: it has a density of 19,300 kg/m³. By comparison, the density of lead is 11,340 kg/m³, and that of the densest element, osmium, is 22,588 ± 15 kg/m³.^[16]

Chemistry

Gold (III) chloride solution in water

Although gold is the most noble of the noble metals,^[17]^[18] it still forms many diverse compounds. The oxidation state of gold in its compounds ranges from −1 to +5, but Au(I) and Au(III) dominate its chemistry. Au(I), referred to as the aurous ion, is the most common oxidation state with soft ligands such as thioethers, thiolates, and tertiary phosphines. Au(I) compounds are typically linear. A good example is Au(CN)₂⁻, which is the soluble form of gold encountered in mining. The binary gold halides, such as AuCl, form zigzag polymeric chains, again featuring linear coordination at Au. Most drugs based on gold are Au(I) derivatives.^[19]

Au(III) (auric) is a common oxidation state, and is illustrated by gold(III) chloride, Au₂Cl₆. The gold atom centers in Au(III) complexes, like other d⁸ compounds, are typically square planar, with chemical bonds that have both covalent and ionic character.

Gold does not react with oxygen at any temperature;^[20] similarly, it does not react with ozone^{[citation needed]}. Gold is strongly attacked by fluorine at dull-red heat^[21] to form gold(III) fluoride.

Some free halogens react with gold.^[22] Powdered gold reacts with chlorine at 180 °C to form AuCl₃.^[23] Gold reacts with bromine at 140 °C to form gold(III) bromide, but reacts only very slowly with iodine to form the monoiodide.

Gold does not react with sulfur directly,^[24] but gold(III) sulfide can be made by passing hydrogen sulfide through a dilute solution of gold(III) chloride or chlorauric acid.

Gold readily dissolves in mercury at room temperature to form an amalgam, and forms alloys with many other metals at higher temperatures. These alloys can be produced to modify the hardness and other metallurgical properties, to control melting point or to create exotic colors.^[25]

Gold reacts with potassium, rubidium, caesium, or tetramethylammonium, to form the respective auride salts, containing the Au⁻ ion. Caesium auride is perhaps the most famous.

Gold is unaffected by most acids. It does not react with hydrofluoric, hydrochloric, hydrobromic, hydriodic, sulfuric, or nitric acid. It does react with aqua regia, a mixture of nitric and hydrochloric acids, and with selenic acid. Aqua regia, a 1:3 mixture of nitric acid and hydrochloric acid, dissolves gold. Nitric acid oxidizes the metal to +3 ions, but only in minute amounts, typically undetectable in the pure acid because of the chemical equilibrium of the reaction. However, the ions are removed from the equilibrium by hydrochloric acid, forming AuCl₄⁻ ions, or chloroauric acid, thereby enabling further oxidation.

Gold is similarly unaffected by most bases. It does not react with aqueous, solid, or molten sodium or potassium hydroxide. It does however, react with sodium or potassium cyanide under alkaline conditions when oxygen is present to form soluble complexes.^[24]

Common oxidation states of gold include +1 (gold(I) or aurous compounds) and +3 (gold(III) or auric compounds). Gold ions in solution are readily reduced and precipitated as metal by adding any other metal as the reducing agent. The added metal is oxidized and dissolves, allowing the gold to be displaced from solution and be recovered as a solid precipitate.

Less common oxidation states

Less common oxidation states of gold include −1, +2, and +5.

The −1 oxidation state occurs in compounds containing the Au⁻ anion, called aurides. Caesium auride (CsAu), for example, crystallizes in the caesium chloride motif.^[26] Other aurides include those of Rb⁺, K⁺, and tetramethylammonium (CH₃)₄N⁺.^[27] Gold has the highest Pauling electronegativity of any metal, with a value of 2.54, making the auride anion relatively stable.

Gold(II) compounds are usually diamagnetic with Au–Au bonds such as [Au(CH₂)₂P(C₆H₅)₂]₂Cl₂. The evaporation of a solution of Au(OH)
3 in concentrated H
2SO
4 produces red crystals of gold(II) sulfate, Au₂(SO₄)₂. Originally thought to be a mixed-valence compound, it has been shown to contain Au4+
2 cations, analogous to the better-known mercury(I) ion, Hg2+
2 .^[28]^[29] A gold(II) complex, the tetraxenonogold(II) cation, which contains xenon as a ligand, occurs in [AuXe₄](Sb₂F₁₁)₂.^[30]

Gold pentafluoride, along with its derivative anion, AuF−
6, and its difluorine complex, gold heptafluoride, is the sole example of gold(V), the highest verified oxidation state.^[31]

Some gold compounds exhibit aurophilic bonding, which describes the tendency of gold ions to interact at distances that are too long to be a conventional Au–Au bond but shorter than van der Waals bonding. The interaction is estimated to be comparable in strength to that of a hydrogen bond.

Mixed valence compounds

Well-defined cluster compounds are numerous.^[27] In such cases, gold has a fractional oxidation state. A representative example is the octahedral species {Au(P(C₆H₅)₃)}₆²⁺. Gold chalcogenides, such as gold sulfide, feature equal amounts of Au(I) and Au(III).

Color

Different colors of Ag-Au-Cu alloys

Whereas most other pure metals are gray or silvery white, gold is slightly reddish yellow.^[32] This color is determined by the density of loosely bound (valence) electrons; those electrons oscillate as a collective "plasma" medium described in terms of a quasiparticle called a plasmon. The frequency of these oscillations lies in the ultraviolet range for most metals, but it falls into the visible range for gold due to subtle relativistic effects that affect the orbitals around gold atoms.^[33]^[34] Similar effects impart a golden hue to metallic caesium.

Common colored gold alloys such as rose gold can be created by the addition of various amounts of copper and silver, as indicated in the triangular diagram to the left. Alloys containing palladium or nickel are also important in commercial jewelry as these produce white gold alloys. Less commonly, addition of manganese, aluminium, iron, indium and other elements can produce more unusual colors of gold for various applications.^[25]

Isotopes

Gold has only one stable isotope, 197
Au, which is also its only naturally occurring isotope, so gold is both a mononuclidic and monoisotopic element. Thirty-six radioisotopes have been synthesized ranging in atomic mass from 169 to 205. The most stable of these is 195
Au with a half-life of 186.1 days. The least stable is 171
Au, which decays by proton emission with a half-life of 30 µs. Most of gold's radioisotopes with atomic masses below 197 decay by some combination of proton emission, α decay, and β⁺ decay. The exceptions are 195
Au, which decays by electron capture, and 196
Au, which decays most often by electron capture (93%) with a minor β⁻ decay path (7%).^[35] All of gold's radioisotopes with atomic masses above 197 decay by β⁻ decay.^[36]

At least 32 nuclear isomers have also been characterized, ranging in atomic mass from 170 to 200. Within that range, only 178
Au, 180
Au, 181
Au, 182
Au, and 188
Au do not have isomers. Gold's most stable isomer is 198m2
Au with a half-life of 2.27 days. Gold's least stable isomer is 177m2
Au with a half-life of only 7 ns. 184m1
Au has three decay paths: β⁺ decay, isomeric transition, and alpha decay. No other isomer or isotope of gold has three decay paths.^[36]

Modern applications

The world consumption of new gold produced is about 50% in jewelry, 40% in investments, and 10% in industry.^[8]

Jewelry

Moche gold necklace depicting feline heads. Larco Museum Collection. Lima-Peru

Because of the softness of pure (24k) gold, it is usually alloyed with base metals for use in jewelry, altering its hardness and ductility, melting point, color and other properties. Alloys with lower karat rating, typically 22k, 18k, 14k or 10k, contain higher percentages of copper or other base metals or silver or palladium in the alloy. Copper is the most commonly used base metal, yielding a redder color.^[37]

Eighteen-karat gold containing 25% copper is found in antique and Russian jewelry and has a distinct, though not dominant, copper cast, creating rose gold. Fourteen-karat gold-copper alloy is nearly identical in color to certain bronze alloys, and both may be used to produce police and other badges. Blue gold can be made by alloying with iron and purple gold can be made by alloying with aluminium, although rarely done except in specialized jewelry. Blue gold is more brittle and therefore more difficult to work with when making jewelry.^[37]

Fourteen- and eighteen-karat gold alloys with silver alone appear greenish-yellow and are referred to as green gold. White gold alloys can be made with palladium or nickel. White 18-karat gold containing 17.3% nickel, 5.5% zinc and 2.2% copper is silvery in appearance. Nickel is toxic, however, and its release from nickel white gold is controlled by legislation in Europe.^[37]

Alternative white gold alloys are available based on palladium, silver and other white metals,^[37] but the palladium alloys are more expensive than those using nickel. High-karat white gold alloys are far more resistant to corrosion than are either pure silver or sterling silver. The Japanese craft of Mokume-gane exploits the color contrasts between laminated colored gold alloys to produce decorative wood-grain effects.

By 2014 the gold jewelry industry was escalating despite a dip in gold prices. Demand in the first quarter of 2014 pushed turnover to $23.7 billion according to a World Gold Council report.

Investment

Gold prices (US$ per troy ounce), in nominal US$ and inflation adjusted US$.

Many holders of gold store it in form of bullion coins or bars as a hedge against inflation or other economic disruptions. However, economist Martin Feldstein does not believe gold serves as a hedge against inflation or currency depreciation.^[38]

The ISO 4217 currency code of gold is XAU.^[39]

Modern bullion coins for investment or collector purposes do not require good mechanical wear properties; they are typically fine gold at 24k, although the American Gold Eagle and the British gold sovereign continue to be minted in 22k (0.92) metal in historical tradition, and the South African Krugerrand, first released in 1967, is also 22k (0.92).^[40] The special issue Canadian Gold Maple Leaf coin contains the highest purity gold of any bullion coin, at 99.999% or 0.99999, while the popular issue Canadian Gold Maple Leaf coin has a purity of 99.99%.

Several other 99.99% pure gold coins are available. In 2006, the United States Mint began producing the American Buffalo gold bullion coin with a purity of 99.99%. The Australian Gold Kangaroos were first coined in 1986 as the Australian Gold Nugget but changed the reverse design in 1989. Other modern coins include the Austrian Vienna Philharmonic bullion coin and the Chinese Gold Panda.

Electronics connectors

Only 10% of the world consumption of new gold produced goes to industry,^[8] but by far the most important industrial use for new gold is in fabrication of corrosion-free electrical connectors in computers and other electrical devices. For example, according to the World Gold council, a typical cell phone may contain 50 mg of gold, worth about 50 cents. But since nearly one billion cell phones are produced each year, a gold value of 50 cents in each phone adds to $500 million in gold from just this application.^[41]

Though gold is attacked by free chlorine, its good conductivity and general resistance to oxidation and corrosion in other environments (including resistance to non-chlorinated acids) has led to its widespread industrial use in the electronic era as a thin-layer coating on electrical connectors, thereby ensuring good connection. For example, gold is used in the connectors of the more expensive electronics cables, such as audio, video and USB cables. The benefit of using gold over other connector metals such as tin in these applications has been debated; gold connectors are often criticized by audio-visual experts as unnecessary for most consumers and seen as simply a marketing ploy. However, the use of gold in other applications in electronic sliding contacts in highly humid or corrosive atmospheres, and in use for contacts with a very high failure cost (certain computers, communications equipment, spacecraft, jet aircraft engines) remains very common.^[42]

Besides sliding electrical contacts, gold is also used in electrical contacts because of its resistance to corrosion, electrical conductivity, ductility and lack of toxicity.^[43] Switch contacts are generally subjected to more intense corrosion stress than are sliding contacts. Fine gold wires are used to connect semiconductor devices to their packages through a process known as wire bonding.

The concentration of free electrons in gold metal is 5.90×10²² cm⁻³. Gold is highly conductive to electricity, and has been used for electrical wiring in some high-energy applications (only silver and copper are more conductive per volume, but gold has the advantage of corrosion resistance). For example, gold electrical wires were used during some of the Manhattan Project's atomic experiments, but large high-current silver wires were used in the calutron isotope separator magnets in the project.

It's estimated that 16% of the world's gold and 22% of the world's silver is contained in electronic technology in Japan.^[44]

Non-electronic industry

Mirror for the future James Webb Space Telescope coated in gold to reflect infrared light

The world's largest gold bar has a mass of 250 kg. Toi museum, Japan.

A gold nugget of 5 mm in diameter (bottom) can be expanded through hammering into a gold foil of about 0.5 square meters. Toi museum, Japan.

Gold solder is used for joining the components of gold jewelry by high-temperature hard soldering or brazing. If the work is to be of hallmarking quality, gold solder must match the carat weight of the work, and alloy formulas are manufactured in most industry-standard carat weights to color match yellow and white gold. Gold solder is usually made in at least three melting-point ranges referred to as Easy, Medium and Hard. By using the hard, high-melting point solder first, followed by solders with progressively lower melting points, goldsmiths can assemble complex items with several separate soldered joints.
Gold can be made into thread and used in embroidery.
Gold produces a deep, intense red color when used as a coloring agent in cranberry glass.
In photography, gold toners are used to shift the color of silver bromide black-and-white prints towards brown or blue tones, or to increase their stability. Used on sepia-toned prints, gold toners produce red tones. Kodak published formulas for several types of gold toners, which use gold as the chloride.^[45]
Gold is a good reflector of electromagnetic radiation such as infrared and visible light, as well as radio waves. It is used for the protective coatings on many artificial satellites, in infrared protective faceplates in thermal-protection suits and astronauts' helmets, and in electronic warfare planes such as the EA-6B Prowler.
Gold is used as the reflective layer on some high-end CDs.
Automobiles may use gold for heat shielding. McLaren uses gold foil in the engine compartment of its F1 model.^[46]
Gold can be manufactured so thin that it appears transparent. It is used in some aircraft cockpit windows for de-icing or anti-icing by passing electricity through it. The heat produced by the resistance of the gold is enough to deter ice from forming.^[47]

Commercial chemistry

Gold is attacked by and dissolves in alkaline solutions of potassium or sodium cyanide, to form the salt gold cyanide—a technique that has been used in extracting metallic gold from ores in the cyanide process. Gold cyanide is the electrolyte used in commercial electroplating of gold onto base metals and electroforming.

Gold chloride (chloroauric acid) solutions are used to make colloidal gold by reduction with citrate or ascorbate ions. Gold chloride and gold oxide are used to make cranberry or red-colored glass, which, like colloidal gold suspensions, contains evenly sized spherical gold nanoparticles.^[48]

Medicine

Metallic and gold compounds have been used for medicinal purposes historically and are still in use. The apparent paradox of the actual toxicology of the substance suggests the possibility of serious gaps in the understanding of the action of gold in physiology.^[49]

Gold (usually as the metal) is perhaps the most anciently administered medicine (apparently by shamanic practitioners)^[50] and known to Dioscorides.^[51]^[52] In medieval times, gold was often seen as beneficial for the health, in the belief that something so rare and beautiful could not be anything but healthy. Even some modern esotericists and forms of alternative medicine assign metallic gold a healing power.^[53]

In the 19th century gold had a reputation as a "nervine," a therapy for nervous disorders. Depression, epilepsy, migraine, and glandular problems such as amenorrhea and impotence were treated, and most notably alcoholism (Keeley, 1897).^[54]

Only salts and radioisotopes of gold are of pharmacological value, since elemental (metallic) gold is inert to all chemicals it encounters inside the body (i.e., ingested gold cannot be attacked by stomach acid). Some gold salts do have anti-inflammatory properties and at present two are still used as pharmaceuticals in the treatment of arthritis and other similar conditions in the US (sodium aurothiomalate and auranofin). These drugs have been explored as a means to help to reduce the pain and swelling of rheumatoid arthritis, and also (historically) against tuberculosis and some parasites.^[55]

Gold alloys are used in restorative dentistry, especially in tooth restorations, such as crowns and permanent bridges. The gold alloys' slight malleability facilitates the creation of a superior molar mating surface with other teeth and produces results that are generally more satisfactory than those produced by the creation of porcelain crowns. The use of gold crowns in more prominent teeth such as incisors is favored in some cultures and discouraged in others.

Colloidal gold preparations (suspensions of gold nanoparticles) in water are intensely red-colored, and can be made with tightly controlled particle sizes up to a few tens of nanometers across by reduction of gold chloride with citrate or ascorbate ions. Colloidal gold is used in research applications in medicine, biology and materials science. The technique of immunogold labeling exploits the ability of the gold particles to adsorb protein molecules onto their surfaces. Colloidal gold particles coated with specific antibodies can be used as probes for the presence and position of antigens on the surfaces of cells.^[56] In ultrathin sections of tissues viewed by electron microscopy, the immunogold labels appear as extremely dense round spots at the position of the antigen.^[57]

Gold, or alloys of gold and palladium, are applied as conductive coating to biological specimens and other non-conducting materials such as plastics and glass to be viewed in a scanning electron microscope. The coating, which is usually applied by sputtering with an argon plasma, has a triple role in this application. Gold's very high electrical conductivity drains electrical charge to earth, and its very high density provides stopping power for electrons in the electron beam, helping to limit the depth to which the electron beam penetrates the specimen. This improves definition of the position and topography of the specimen surface and increases the spatial resolution of the image. Gold also produces a high output of secondary electrons when irradiated by an electron beam, and these low-energy electrons are the most commonly used signal source used in the scanning electron microscope.^[58]

The isotope gold-198 (half-life 2.7 days) is used, in nuclear medicine, in some cancer treatments and for treating other diseases.^[59]^[60]

Food and drink

Gold can be used in food and has the E number 175.^[61] In 2016, the European Food Safety Authority published an opinion on the re-evaluation of gold (E 175) as a food additive. Concerns included the possible presence of minute amounts of gold nanoparticles in the food additive, and that gold nanoparticles have been shown to be genotoxic in mammalian cells in vitro.^[62]
Gold leaf, flake or dust is used on and in some gourmet foods, notably sweets and drinks as decorative ingredient.^[63] Gold flake was used by the nobility in medieval Europe as a decoration in food and drinks, in the form of leaf, flakes or dust, either to demonstrate the host's wealth or in the belief that something that valuable and rare must be beneficial for one's health.
Danziger Goldwasser (German: Gold water of Danzig) or Goldwasser (English: Goldwater) is a traditional German herbal liqueur^[64] produced in what is today Gdańsk, Poland, and Schwabach, Germany, and contains flakes of gold leaf. There are also some expensive (~$1000) cocktails which contain flakes of gold leaf.^[65] However, since metallic gold is inert to all body chemistry, it has no taste, it provides no nutrition, and it leaves the body unaltered.^[66]
Vark is a foil composed of a pure metal that is sometimes gold,^[67] and is used for garnishing sweets in South Asian cuisine.

Monetary exchange (historical)

Gold is commonly formed into bars for use in monetary exchange.

Two golden 20 kr coins from the Scandinavian Monetary Union, which was based on a gold standard. The coin to the left is Swedish and the right one is Danish.

Gold has been widely used throughout the world as money, for efficient indirect exchange (versus barter), and to store wealth in hoards. For exchange purposes, mints produce standardized gold bullion coins, bars and other units of fixed weight and purity.

The first known coins containing gold were struck in Lydia, Asia Minor, around 600 BC.^[68] The talent coin of gold in use during the periods of Grecian history both before and during the time of the life of Homer weighed between 8.42 and 8.75 grams.^[69] From an earlier preference in using silver, European economies re-established the minting of gold as coinage during the thirteenth and fourteenth centuries.^[70]

Bills (that mature into gold coin) and gold certificates (convertible into gold coin at the issuing bank) added to the circulating stock of gold standard money in most 19th century industrial economies. In preparation for World War I the warring nations moved to fractional gold standards, inflating their currencies to finance the war effort. Post-war, the victorious countries, most notably Britain, gradually restored gold-convertibility, but international flows of gold via bills of exchange remained embargoed; international shipments were made exclusively for bilateral trades or to pay war reparations.

After World War II gold was replaced by a system of nominally convertible currencies related by fixed exchange rates following the Bretton Woods system. Gold standards and the direct convertibility of currencies to gold have been abandoned by world governments, led in 1971 by the United States' refusal to redeem its dollars in gold. Fiat currency now fills most monetary roles. Switzerland was the last country to tie its currency to gold; it backed 40% of its value until the Swiss joined the International Monetary Fund in 1999.^[71]

Central banks continue to keep a portion of their liquid reserves as gold in some form, and metals exchanges such as the London Bullion Market Association still clear transactions denominated in gold, including future delivery contracts. Today, gold mining output is declining.^[72] With the sharp growth of economies in the 20th century, and increasing foreign exchange, the world's gold reserves and their trading market have become a small fraction of all markets and fixed exchange rates of currencies to gold have been replaced by floating prices for gold and gold future contract. Though the gold stock grows by only 1 or 2% per year, very little metal is irretrievably consumed. Inventory above ground would satisfy many decades of industrial and even artisan uses at current prices.

The gold content of alloys is measured in carats (k). Pure gold is designated as 24k. English gold coins intended for circulation from 1526 into the 1930s were typically a standard 22k alloy called crown gold,^[73] for hardness (American gold coins for circulation after 1837 contained the slightly lower amount of 0.900 fine gold, or 21.6 kt).^[74]

Although the prices of some platinum group metals can be much higher, gold has long been considered the most desirable of precious metals, and its value has been used as the standard for many currencies. Gold has been used as a symbol for purity, value, royalty, and particularly roles that combine these properties. Gold as a sign of wealth and prestige was ridiculed by Thomas More in his treatise Utopia. On that imaginary island, gold is so abundant that it is used to make chains for slaves, tableware, and lavatory seats. When ambassadors from other countries arrive, dressed in ostentatious gold jewels and badges, the Utopians mistake them for menial servants, paying homage instead to the most modestly dressed of their party.

Cultural history

The Turin Papyrus Map

Funerary mask of Tutankhamun

Jason returns with the golden fleece on an Apulian red-figure calyx krater, ca. 340–330 BC.

Ancient golden Kritonios Crown, funerary or marriage material, 370–360 BC. From a grave in Armento, Campania

Gold artifacts found at the Nahal Kana cave cemetery dated during the 1980s, showed these to be from within the Chalcolithic, and considered the earliest find from the Levant (Gopher et al. 1990).^[75] Gold artifacts in the Balkans also appear from the 4th millennium BC, such as those found in the Varna Necropolis near Lake Varna in Bulgaria, thought by one source (La Niece 2009) to be the earliest "well-dated" find of gold artifacts.^[76] Gold artifacts such as the golden hats and the Nebra disk appeared in Central Europe from the 2nd millennium BC Bronze Age.

Egyptian hieroglyphs from as early as 2600 BC describe gold, which King Tushratta of the Mitanni claimed was "more plentiful than dirt" in Egypt.^[77] Egypt and especially Nubia had the resources to make them major gold-producing areas for much of history. One of the earliest known maps, known as the Turin Papyrus Map, shows the plan of a gold mine in Nubia together with indications of the local geology. The primitive working methods are described by both Strabo and Diodorus Siculus, and included fire-setting. Large mines were also present across the Red Sea in what is now Saudi Arabia.

The legend of the golden fleece may refer to the use of fleeces to trap gold dust from placer deposits in the ancient world. Gold is mentioned frequently in the Old Testament, starting with Genesis 2:11 (at Havilah), the story of The Golden Calf and many parts of the temple including the Menorah and the golden altar. In the New Testament, it is included with the gifts of the magi in the first chapters of Matthew. The Book of Revelation 21:21 describes the city of New Jerusalem as having streets "made of pure gold, clear as crystal". Exploitation of gold in the south-east corner of the Black Sea is said to date from the time of Midas, and this gold was important in the establishment of what is probably the world's earliest coinage in Lydia around 610 BC.^[78] From the 6th or 5th century BC, the Chu (state) circulated the Ying Yuan, one kind of square gold coin.

In Roman metallurgy, new methods for extracting gold on a large scale were developed by introducing hydraulic mining methods, especially in Hispania from 25 BC onwards and in Dacia from 106 AD onwards. One of their largest mines was at Las Medulas in León (Spain), where seven long aqueducts enabled them to sluice most of a large alluvial deposit. The mines at Roşia Montană in Transylvania were also very large, and until very recently, still mined by opencast methods. They also exploited smaller deposits in Britain, such as placer and hard-rock deposits at Dolaucothi. The various methods they used are well described by Pliny the Elder in his encyclopedia Naturalis Historia written towards the end of the first century AD.

During Mansa Musa's (ruler of the Mali Empire from 1312 to 1337) hajj to Mecca in 1324, he passed through Cairo in July 1324, and was reportedly accompanied by a camel train that included thousands of people and nearly a hundred camels where he gave away so much gold that it depressed the price in Egypt for over a decade.^[79] A contemporary Arab historian remarked:

Gold was at a high price in Egypt until they came in that year. The mithqal did not go below 25 dirhams and was generally above, but from that time its value fell and it cheapened in price and has remained cheap till now. The mithqal does not exceed 22 dirhams or less. This has been the state of affairs for about twelve years until this day by reason of the large amount of gold which they brought into Egypt and spent there [...].

— Chihab Al-Umari, Kingdom of Mali^[80]

The European exploration of the Americas was fueled in no small part by reports of the gold ornaments displayed in great profusion by Native American peoples, especially in Mesoamerica, Peru, Ecuador and Colombia. The Aztecs regarded gold as the product of the gods, calling it literally "god excrement" (teocuitlatl in Nahuatl), and after Moctezuma II was killed, most of this gold was shipped to Spain.^[81] However, for the indigenous peoples of North America gold was considered useless and they saw much greater value in other minerals which were directly related to their utility, such as obsidian, flint, and slate.^[82] Rumors of cities filled with gold fueled legends of El Dorado.

Gold played a role in western culture, as a cause for desire and of corruption, as told in children's fables such as Rumpelstiltskin, where the peasant's daughter turns hay into gold, in return for giving up her child when she becomes a princess; and the stealing of the hen that lays golden eggs in Jack and the Beanstalk.

The top prize at the Olympic games is the gold medal.

75% of the presently accounted for gold has been extracted since 1910. It has been estimated that the currently known amount of gold internationally would form a single cube 20 m (66 ft) on a side (equivalent to 8,000 m³).^[83]

Circled dot, the alchemical symbol for gold

One main goal of the alchemists was to produce gold from other substances, such as lead — presumably by the interaction with a mythical substance called the philosopher's stone. Although they never succeeded in this attempt, the alchemists did promote an interest in systematically finding out what can be done with substances, and this laid the foundation for today's chemistry. Their symbol for gold was the circle with a point at its center (☉), which was also the astrological symbol and the ancient Chinese character for the Sun.

Golden treasures have been rumored to be found at various locations, following tragedies such as the Jewish temple treasures in the Vatican, following the temple's destruction in 70 AD, a gold stash on the Titanic, the Nazi gold train – following World War II.

The Dome of the Rock on the Jerusalem temple site is covered with an ultra-thin golden glasure.^{[clarification needed]} The Sikh Golden temple, the Harmandir Sahib, is a building covered with gold. Similarly the Wat Phra Kaew emerald Buddhist temple (wat) in Thailand has ornamental gold-leafed statues and roofs. Some European king and queen's crowns were made of gold, and gold was used for the bridal crown since antiquity. An ancient Talmudic text circa 100 AD describes Rachel, wife of Rabbi Akiva, receiving a "Jerusalem of Gold" (diadem). A Greek burial crown made of gold was found in a grave circa 370 BC.

Occurrence

This 156-troy-ounce (4.9 kg) nugget, known as the Mojave Nugget, was found by an individual prospector in the Southern California Desert using a metal detector.

Gold's atomic number of 79 makes it one of the higher atomic number elements that occur naturally. Traditionally, gold is thought to have formed by the R-process in supernova nucleosynthesis,^[84] but a relatively recent paper suggests that gold and other elements heavier than iron may also be produced in quantity by the collision of neutron stars.^[85] In both cases, satellite spectrometers only indirectly detect the resulting gold: "we have no spectroscopic evidence that [such] elements have truly been produced."^[86]

These gold nucleogenesis theories hold that the resulting explosions scattered metal-containing dusts (including heavy elements such as gold) into the region of space in which they later condensed into our solar system and the Earth.^[87] Because the Earth was molten when it was just formed, almost all of the gold present on Earth sank into the core. Most of the gold that is present today in the Earth's crust and mantle is thought to have been delivered to Earth later, by asteroid impacts during the Late Heavy Bombardment.^[5]^[6]

A schematic diagram of a NE (left) to SW (right) cross-section through the 2.020 billion year old Vredefort impact crater in South Africa and how it distorted the contemporary geological structures. The present erosion level is shown. Johannesburg is located where the Witwatersrand Basin (the yellow layer) is exposed at the "present surface" line, just inside the crater rim, on the left. Not to scale.

The asteroid that formed Vredefort crater 2.020 billion years ago is often credited with seeding the Witwatersrand basin in South Africa with the richest gold deposits on earth.^[88]^[89]^[90]^[91] However, the gold-bearing Witwatersrand rocks were laid down between 700 and 950 million years before the Vredefort impact.^[92]^[93] These gold-bearing rocks had furthermore been covered by a thick layer of Ventersdorp lavas and the Transvaal Supergroup of rocks before the meteor struck. What the Vredefort impact achieved, however, was to distort the Witwatersrand basin in such a way that the gold-bearing rocks were brought to the present erosion surface in Johannesburg, on the Witwatersrand, just inside the rim of the original 300 km diameter crater caused by the meteor strike. The discovery of the deposit in 1886 launched the Witwatersrand Gold Rush. Some 22% of all the gold that is ascertained to exist today on Earth has been extracted from these Witwatersrand rocks.^[93]

On Earth, gold is found in ores in rock formed from the Precambrian time onward.^[76] It most often occurs as a native metal, typically in a metal solid solution with silver (i.e. as a gold silver alloy). Such alloys usually have a silver content of 8–10%. Electrum is elemental gold with more than 20% silver. Electrum's color runs from golden-silvery to silvery, dependent upon the silver content. The more silver, the lower the specific gravity.

Native gold occurs as very small to microscopic particles embedded in rock, often together with quartz or sulfide minerals such as "Fool's Gold", which is a pyrite.^[94] These are called lode deposits. The metal in a native state is also found in the form of free flakes, grains or larger nuggets^[76] that have been eroded from rocks and end up in alluvial deposits called placer deposits. Such free gold is always richer at the surface of gold-bearing veins^{[clarification needed]} owing to the oxidation of accompanying minerals followed by weathering, and washing of the dust into streams and rivers, where it collects and can be welded by water action to form nuggets.

Relative sizes of an 860 kg block of gold ore, and the 30 g of gold that can be extracted from it. Toi gold mine, Japan.

Gold left behind after a pyrite cube was oxidized to hematite. Note cubic shape of cavity.

Gold sometimes occurs combined with tellurium as the minerals calaverite, krennerite, nagyagite, petzite and sylvanite (see telluride minerals), and as the rare bismuthide maldonite (Au₂Bi) and antimonide aurostibite (AuSb₂). Gold also occurs in rare alloys with copper, lead, and mercury: the minerals auricupride (Cu₃Au), novodneprite (AuPb₃) and weishanite ((Au, Ag)₃Hg₂).

Recent research suggests that microbes can sometimes play an important role in forming gold deposits, transporting and precipitating gold to form grains and nuggets that collect in alluvial deposits.^[95]

Another recent study has claimed water in faults vaporizes during an earthquake, depositing gold. When an earthquake strikes, it moves along a fault. Water often lubricates faults, filling in fractures and jogs. About 6 miles (10 kilometers) below the surface, under incredible temperatures and pressures, the water carries high concentrations of carbon dioxide, silica, and gold. During an earthquake, the fault jog suddenly opens wider. The water inside the void instantly vaporizes, flashing to steam and forcing silica, which forms the mineral quartz, and gold out of the fluids and onto nearby surfaces.^[96]

Seawater

The world's oceans contain gold. Measured concentrations of gold in the Atlantic and Northeast Pacific are 50–150 femtomol/L or 10–30 parts per quadrillion (about 10–30 g/km³). In general, gold concentrations for south Atlantic and central Pacific samples are the same (~50 femtomol/L) but less certain. Mediterranean deep waters contain slightly higher concentrations of gold (100–150 femtomol/L) attributed to wind-blown dust and/or rivers. At 10 parts per quadrillion the Earth's oceans would hold 15,000 tonnes of gold.^[97] These figures are three orders of magnitude less than reported in the literature prior to 1988, indicating contamination problems with the earlier data.

A number of people have claimed to be able to economically recover gold from sea water, but so far they have all been either mistaken or acted in an intentional deception. Prescott Jernegan ran a gold-from-seawater swindle in the United States in the 1890s. A British fraudster ran the same scam in England in the early 1900s.^[98] Fritz Haber (the German inventor of the Haber process) did research on the extraction of gold from sea water in an effort to help pay Germany's reparations following World War I.^[99] Based on the published values of 2 to 64 ppb of gold in seawater a commercially successful extraction seemed possible. After analysis of 4,000 water samples yielding an average of 0.004 ppb it became clear that the extraction would not be possible and he stopped the project.^[100] No commercially viable mechanism for performing gold extraction from sea water has yet been identified. Gold synthesis is not economically viable and is unlikely to become so in the foreseeable future.

Specimens of crystalline native gold

Native gold nuggets
"Rope gold" from Lena River, Sakha Republic, Russia. Size: 2.5×1.2×0.7 cm.
Crystalline gold from Mina Zapata, Santa Elena de Uairen, Venezuela. Size: 3.7×1.1×0.4 cm.
Gold leaf from Harvard Mine, Jamestown, California, USA. Size 9.3×3.2× >0.1 cm.

Production

Gold Exports by Country (2014) from Harvard Atlas of Economic Complexity

The entrance to an underground gold mine in Victoria, Australia

Pure gold precipitate produced by the aqua regia refining process

Time trend of gold production

The World Gold Council states that as of the end of 2014, "there were 183,600 tonnes of stocks in existence above ground". This can be represented by a cube with an edge length of about 21 meters.^[101] At $1,075 per troy ounce, 183,600 metric tonnes of gold would have a value of $6.3 trillion.

World production for 2014 totaled 2,990 tonnes,^[102] compared to 2,300 tonnes for 2008.^[103]

Mining

Since the 1880s, South Africa has been the source for a large proportion of the world's gold supply, with about 50% of the presently accounted for gold having come from South Africa. Production in 1970 accounted for 79% of the world supply, producing about 1,480 tonnes. In 2007 China (with 276 tonnes) overtook South Africa as the world's largest gold producer, the first time since 1905 that South Africa has not been the largest.^[104]

As of 2013, China was the world's leading gold-mining country, followed in order by Australia, the United States, Russia, and Peru. South Africa, which had dominated world gold production for most of the 20th Century, had declined to sixth place.^[105] Other major producers are the Ghana, Burkina Faso, Mali, Indonesia and Uzbekistan.

In South America, the controversial project Pascua Lama aims at exploitation of rich fields in the high mountains of Atacama Desert, at the border between Chile and Argentina.

Today about one-quarter of the world gold output is estimated to originate from artisanal or small scale mining.^[106]

The city of Johannesburg located in South Africa was founded as a result of the Witwatersrand Gold Rush which resulted in the discovery of some of the largest natural gold deposits in recorded history. The gold fields are confined to the northern and north-western edges of the Witwatersrand basin, which is a 5–7 km thick layer of archean rocks located, in most places, deep under the Free State, Gauteng and surrounding provinces.^[107] These Witwatersrand rocks are exposed at the surface on the Witwatersrand, in and around Johannesburg, but also in isolated patches to the south-east and south-west of Johannesburg, as well as in an arc around the Vredefort Dome which lies close to the center of the Witwatersrand basin.^[92]^[107] From these surface exposures the basin dips extensively, requiring some of the mining to occur at depths of nearly 4000 m, making them, especially the Savuka and TauTona mines to the south-west of Johannesburg, the deepest mines on earth. The gold is found only in six areas where archean rivers from the north and north-west formed extensive pebbly braided river deltas before draining into the "Witwatersrand sea" where the rest of the Witwatersrand sediments were deposited.^[107]

The Second Boer War of 1899–1901 between the British Empire and the Afrikaner Boers was at least partly over the rights of miners and possession of the gold wealth in South Africa.

Prospecting

During the 19th century, gold rushes occurred whenever large gold deposits were discovered. The first documented discovery of gold in the United States was at the Reed Gold Mine near Georgeville, North Carolina in 1803.^[108] The first major gold strike in the United States occurred in a small north Georgia town called Dahlonega.^[109] Further gold rushes occurred in California, Colorado, the Black Hills, Otago in New Zealand, Australia, Witwatersrand in South Africa, and the Klondike in Canada.

A miner underground at Pumsaint gold mine Wales; c. 1938?.

Bioremediation

A sample of the fungus Aspergillus niger was found growing from gold mining solution; and was found to contain cyano metal complexes; such as gold, silver, copper iron and zinc. The fungus also plays a role in the solubilization of heavy metal sulfides.^[110]

Extraction

Gold extraction is most economical in large, easily mined deposits. Ore grades as little as 0.5 mg/kg (0.5 parts per million, ppm) can be economical. Typical ore grades in open-pit mines are 1–5 mg/kg (1–5 ppm); ore grades in underground or hard rock mines are usually at least 3 mg/kg (3 ppm). Because ore grades of 30 mg/kg (30 ppm) are usually needed before gold is visible to the naked eye, in most gold mines the gold is invisible.

The average gold mining and extraction costs were about US$317/oz in 2007, but these can vary widely depending on mining type and ore quality; global mine production amounted to 2,471.1 tonnes.^[111]

Refining

After initial production, gold is often subsequently refined industrially by the Wohlwill process which is based on electrolysis or by the Miller process, that is chlorination in the melt. The Wohlwill process results in higher purity, but is more complex and is only applied in small-scale installations.^[112]^[113] Other methods of assaying and purifying smaller amounts of gold include parting and inquartation as well as cupellation, or refining methods based on the dissolution of gold in aqua regia.^[114]

Synthesis from other elements

Gold was synthesized from mercury by neutron bombardment in 1941, but the isotopes of gold produced were all radioactive.^[115] In 1924, a Japanese physicist, Hantaro Nagaoka, accomplished the same feat.^[116]

Gold can currently be manufactured in a nuclear reactor by irradiation either of platinum or mercury.

Only the mercury isotope ¹⁹⁶Hg, which occurs with a frequency of 0.15% in natural mercury, can be converted to gold by neutron capture, and following electron capture-decay into ¹⁹⁷Au with slow neutrons. Other mercury isotopes are converted when irradiated with slow neutrons into one another, or formed mercury isotopes which beta decay into thallium.

Using fast neutrons, the mercury isotope ¹⁹⁸Hg, which composes 9.97% of natural mercury, can be converted by splitting off a neutron and becoming ¹⁹⁷Hg, which then disintegrates to stable gold. This reaction, however, possesses a smaller activation cross-section and is feasible only with un-moderated reactors.

It is also possible to eject several neutrons with very high energy into the other mercury isotopes in order to form ¹⁹⁷Hg. However such high-energy neutrons can be produced only by particle accelerators.^{[clarification needed]}

Consumption

The consumption of gold produced in the world is about 50% in jewelry, 40% in investments, and 10% in industry.^[8]^[117]

According to World Gold Council, China is the world's largest single consumer of gold in 2013 and toppled India for the first time with Chinese consumption increasing by 32 percent in a year, while that of India only rose by 13 percent and world consumption rose by 21 percent. Unlike India where gold is used for mainly for jewellery, China uses gold for manufacturing and retail.^[118]

Gold jewelry consumption by country in tonnes^[119]^[120]^[121]
Country	2009	2010	2011	2012	2013
India	442.37	745.70	986.3	864	974
China	376.96	428.00	921.5	817.5	1120.1
United States	150.28	128.61	199.5	161	190
Turkey	75.16	74.07	143	118	175.2
Saudi Arabia	77.75	72.95	69.1	58.5	72.2
Russia	60.12	67.50	76.7	81.9	73.3
United Arab Emirates	67.60	63.37	60.9	58.1	77.1
Egypt	56.68	53.43	36	47.8	57.3
Indonesia	41.00	32.75	55	52.3	68
United Kingdom	31.75	27.35	22.6	21.1	23.4
Other Persian Gulf Countries	24.10	21.97	22	19.9	24.6
Japan	21.85	18.50	−30.1	7.6	21.3
South Korea	18.83	15.87	15.5	12.1	17.5
Vietnam	15.08	14.36	100.8	77	92.2
Thailand	7.33	6.28	107.4	80.9	140.1
Total	1508.70	1805.60
Other Countries	251.6	254.0	390.4	393.5	450.7
World Total	1760.3	2059.6	3487.5	3163.6	3863.5

Pollution

Gold production is associated with contribution to hazardous pollution.^[122]^[123]

Low-grade gold ore may contain less than one ppm gold metal; such ore is ground and mixed with sodium cyanide dissolve the gold. Cyanide is a highly poisonous chemical, which can kill living creatures when exposed in minute quantities. Many cyanide spills^[124] from gold mines have occurred in both developed and developing countries which killed aquatic life in long stretches of affected rivers. Environmentalists consider these events major environmental disasters.^[125]^[126] Thirty tons of used ore is dumped as waste for producing one troy ounce of gold.^[127] Gold ore dumps are the source of many heavy elements such as cadmium, lead, zinc, copper, arsenic, selenium and mercury. When sulfide bearing minerals in these ore dumps are exposed to air and water, the sulfide transforms into sulfuric acid which in turn dissolves these heavy metals facilitating their passage into surface water and ground water. This process is called acid mine drainage. These gold ore dumps are long term, highly hazardous wastes second only to nuclear waste dumps.^[127]

It was once common to use mercury to recover gold from ore, but today the use of mercury is largely limited to small-scale individual miners.^[128] Minute quantities of mercury compounds can reach water bodies, causing heavy metal contamination. Mercury can then enter into the human food chain in the form of methylmercury. Mercury poisoning in humans causes incurable brain function damage and severe retardation.

Gold extraction is also a highly energy intensive industry, extracting ore from deep mines and grinding the large quantity of ore for further chemical extraction requires nearly 25 kW·h of electricity per gram of gold produced.^[129]

Toxicity

Pure metallic (elemental) gold is non-toxic and non-irritating when ingested^[130] and is sometimes used as a food decoration in the form of gold leaf. Metallic gold is also a component of the alcoholic drinks Goldschläger, Gold Strike, and Goldwasser. Metallic gold is approved as a food additive in the EU (E175 in the Codex Alimentarius). Although the gold ion is toxic, the acceptance of metallic gold as a food additive is due to its relative chemical inertness, and resistance to being corroded or transformed into soluble salts (gold compounds) by any known chemical process which would be encountered in the human body.

Soluble compounds (gold salts) such as gold chloride are toxic to the liver and kidneys. Common cyanide salts of gold such as potassium gold cyanide, used in gold electroplating, are toxic by virtue of both their cyanide and gold content. There are rare cases of lethal gold poisoning from potassium gold cyanide.^[131]^[132] Gold toxicity can be ameliorated with chelation therapy with an agent such as dimercaprol.

Gold metal was voted Allergen of the Year in 2001 by the American Contact Dermatitis Society. Gold contact allergies affect mostly women.^[133] Despite this, gold is a relatively non-potent contact allergen, in comparison with metals like nickel.^[134]

Price

Gold price history in 1960–2011

As at December 2015, gold is valued at around US$39,000 per kilogram (US$1,200 per troy ounce).

Like other precious metals, gold is measured by troy weight and by grams. When it is alloyed with other metals the term carat or karat is used to indicate the purity of gold present, with 24 carats being pure gold and lower ratings proportionally less. The purity of a gold bar or coin can also be expressed as a decimal figure ranging from 0 to 1, known as the millesimal fineness, such as 0.995 being very pure.

History

The price of gold is determined through trading in the gold and derivatives markets, but a procedure known as the Gold Fixing in London, originating in September 1919, provides a daily benchmark price to the industry. The afternoon fixing was introduced in 1968 to provide a price when US markets are open.^[135]

Historically gold coinage was widely used as currency; when paper money was introduced, it typically was a receipt redeemable for gold coin or bullion. In a monetary system known as the gold standard, a certain weight of gold was given the name of a unit of currency. For a long period, the United States government set the value of the US dollar so that one troy ounce was equal to $20.67 ($664.56/kg), but in 1934 the dollar was devalued to $35.00 per troy ounce ($1125.27/kg). By 1961, it was becoming hard to maintain this price, and a pool of US and European banks agreed to manipulate the market to prevent further currency devaluation against increased gold demand.^[136]

On 17 March 1968, economic circumstances caused the collapse of the gold pool, and a two-tiered pricing scheme was established whereby gold was still used to settle international accounts at the old $35.00 per troy ounce ($1.13/g) but the price of gold on the private market was allowed to fluctuate; this two-tiered pricing system was abandoned in 1975 when the price of gold was left to find its free-market level.^{[citation needed]} Central banks still hold historical gold reserves as a store of value although the level has generally been declining.^{[citation needed]} The largest gold depository in the world is that of the U.S. Federal Reserve Bank in New York, which holds about 3%^[137] of the gold known to exist and accounted for today, as does the similarly laden U.S. Bullion Depository at Fort Knox. In 2005 the World Gold Council estimated total global gold supply to be 3,859 tonnes and demand to be 3,754 tonnes, giving a surplus of 105 tonnes.^[138]

Sometime around 1970^[vague] the price began in trend to greatly increase,^[139] and between 1968 and 2000 the price of gold ranged widely, from a high of $850/oz ($27,300/kg) on 21 January 1980, to a low of $252.90/oz ($8,131/kg) on 21 June 1999 (London Gold Fixing).^[140] Prices increased rapidly from 2001, but the 1980 high was not exceeded until 3 January 2008 when a new maximum of $865.35 per troy ounce was set.^[141] Another record price was set on 17 March 2008 at $1023.50/oz ($32,900/kg).^[141]

In late 2009, gold markets experienced renewed momentum upwards due to increased demand and a weakening US dollar.^{[citation needed]} On 2 December 2009, Gold reached a new high closing at $1,217.23.^[142] Gold further rallied hitting new highs in May 2010 after the European Union debt crisis prompted further purchase of gold as a safe asset.^[143]^[144] On 1 March 2011, gold hit a new all-time high of $1432.57, based on investor concerns regarding ongoing unrest in North Africa as well as in the Middle East.^[145]

From April 2001 to August 2011, spot gold prices more than quintupled in value against the US dollar, hitting a new all-time high of $1,913.50 on 23 August 2011,^[146] prompting speculation that the long secular bear market had ended and a bull market had returned.^[147] However, the price then began a slow decline to the $1200-per-ounce range in late 2014 and 2015.

Symbolism

Gold bars at the Emperor Casino in Macau

Great human achievements are frequently rewarded with gold, in the form of gold medals, golden trophies and other decorations. Winners of athletic events and other graded competitions are usually awarded a gold medal. Many awards such as the Nobel Prize are made from gold as well. Other award statues and prizes are depicted in gold or are gold plated (such as the Academy Awards, the Golden Globe Awards, the Emmy Awards, the Palme d'Or, and the British Academy Film Awards).

Aristotle in his ethics used gold symbolism when referring to what is now commonly known as the golden mean. Similarly, gold is associated with perfect or divine principles, such as in the case of the golden ratio and the golden rule.

Gold is further associated with the wisdom of aging and fruition. The fiftieth wedding anniversary is golden. Our most valued or most successful latter years are sometimes considered "golden years". The height of a civilization is referred to as a "golden age".

In some forms of Christianity and Judaism, gold has been associated both with holiness and evil. In the Book of Exodus, the Golden Calf is a symbol of idolatry, while in the Book of Genesis, Abraham was said to be rich in gold and silver, and Moses was instructed to cover the Mercy Seat of the Ark of the Covenant with pure gold. In Byzantine iconography the halos of Christ, Mary and the Christian saints are often golden.

According to Christopher Columbus, those who had something of gold were in possession of something of great value on Earth and a substance to even help souls to paradise.^[148]

Wedding rings have long been made of gold. It is long lasting and unaffected by the passage of time and may aid in the ring symbolism of eternal vows before God and the perfection the marriage signifies. In Orthodox Christian wedding ceremonies, the wedded couple is adorned with a golden crown (though some opt for wreaths, instead) during the ceremony, an amalgamation of symbolic rites.

In popular culture gold has many connotations but is most generally connected to terms such as good or great, such as in the phrases: "has a heart of gold", "that's golden!", "golden moment", "then you're golden!" and "golden boy". It remains a cultural symbol of wealth and through that, in many societies, success.

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External links

"Gold". Encyclopædia Britannica. 11 (11th ed.). 1911.
Chemistry in its element podcast (MP3) from the Royal Society of Chemistry's Chemistry World: Gold www.rsc.org
Gold at The Periodic Table of Videos (University of Nottingham)
Getting Gold 1898 book, www.lateralscience.co.uk
Technical Document on Extraction and Mining of Gold at the Wayback Machine (archived 7 March 2008), www.epa.gov
Picture in the Element collection from Heinrich Pniok, www.pniok.de
The Art of Precolumbian Gold: The Jan Mitchell Collection, an exhibition catalog from The Metropolitan Museum of Art (fully available online as PDF)

UpToDate Contents

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1. リウマチ性疾患への金化合物の使用 use of gold compounds in rheumatic diseases
2. 金治療の主な副作用 major side effects of gold therapy
3. 金誘発性肺疾患 gold induced pulmonary disease
4. Component testing for animal-derived food allergies
5. Component testing for pollen-related, plant-derived food allergies

English Journal

Peptide-Au Clusters Induced Tumor Cells Apoptosis via Targeting Glutathione Peroxidase-1: The Molecular Dynamics Assisted Experimental Studies.

Liu M1,2, Gao L3, Zhao L4, He J1, Yuan Q1, Zhang P1, Zhao Y1, Gao X5,6.
Scientific reports.Sci Rep.2017 Dec;7(1):131. doi: 10.1038/s41598-017-00278-6. Epub 2017 Mar 9.
PMID 28273930

Tailoring gas sensor arrays via the design of short peptides sequences as binding elements.

Mascini M1, Pizzoni D2, Perez G3, Chiarappa E2, Di Natale C4, Pittia P2, Compagnone D5.
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PMID 27665168

Novel 96-well quantitative bioelectrocatalytic analysis platform reveals highly efficient direct electrode regeneration of cytochrome P450 BM3 on indium tin oxide.

Frank R1, Klenner M1, Azendorf R1, Bartz M1, Jahnke HG1, Robitzki AA2.
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PMID 27594699

Japanese Journal

Effect of multi-purpose primers on the bond durability between tri-n-butylborane initiated resin and gold alloy

Hiraba Haruto,Nogawa Hiroshi,Koizumi Hiroyasu,Kodaira Akihisa,Akahane Shunsuke
日本補綴歯科学会雑誌 63(1), 95-99, 2019
… This study investigated the influence of an interaction between sulfur-containing monomers and other monomers in multipurpose primers on the bond durability of a tri-n-butylborane (TBB)-initiated acrylic resin to a gold alloy.Methods: … The disk-shaped adherend materials were prepared from a gold alloy (Casting Gold M.C. Type IV). …
NAID 130007604363

An Application of Photoactivatable Substrate for the Evaluation of Epithelial-mesenchymal Transition Inhibitors

NAKANISHI Jun,SUGIYAMA Kenji,MATSUO Hirotaka,TAKAHASHI Yoko,OMURA Satoshi,NAKASHIMA Takuji
Analytical Sciences 35(1), 65-69, 2019
… In this study, we report a method for the evaluation of EMT inhibitors by using a photoactivatable gold substrate, which changes from non-cell-adhesive to cell-adhesive in response to light. …
NAID 130007554884

Tyrosinase-mediated Peptide Conjugation with Chitosan-coated Gold Nanoparticles

SAKONO Naomi,NAKAMURA Kosuke,OHSHIMA Tatsuki,HAYAKAWA Ryoto,SAKONO Masafumi
Analytical Sciences 35(1), 79-83, 2019
… In this study, we aim to enzymatically immobilize a functional peptide on gold nanoparticles (AuNPs) using a single-step reaction. … We performed immobilization experiments of a fluorescent compound-linked caspase-3 substrate peptide using tyrosinase on chitosan-coated AuNPs. …
NAID 130007554835

Related Pictures

★リンクテーブル★

リンク元	「金製剤」
関連記事	「go」「compound」「gold」

「金製剤」

Gold, ₇₉Au
General properties
Name, symbol	gold, Au
Pronunciation	/ˈɡoʊld/; GOHLD
Appearance	metallic yellow
Gold in the periodic table
	platinum ← gold → mercury
Atomic number (Z)	79
Group, block	group 11, d-block
Period	period 6
Element category	transition metal
Standard atomic weight (±) (Ar)	196.966569(5)
Electron configuration	[Xe] 4f14 5d10 6s1
per shell	2, 8, 18, 32, 18, 1
Physical properties
Phase	solid
Melting point	1337.33 K (1064.18 °C, 1947.52 °F)
Boiling point	3243 K (2970 °C, 5378 °F)
Density near r.t.	19.30 g/cm3
when liquid, at m.p.	17.31 g/cm3
Heat of fusion	12.55 kJ/mol
Heat of vaporization	342 kJ/mol
Molar heat capacity	25.418 J/(mol·K)
Atomic properties
Oxidation states	5, 3, 2, 1, −1, −2, −3 (an amphoteric oxide)
Electronegativity	Pauling scale: 2.54
Ionization energies	1st: 890.1 kJ/mol; 2nd: 1980 kJ/mol
Atomic radius	empirical: 144 pm
Covalent radius	136±6 pm
Van der Waals radius	166 pm
Miscellanea
Crystal structure	face-centered cubic (fcc)
Speed of sound thin rod	2030 m/s (at r.t.)
Thermal expansion	14.2 µm/(m·K) (at 25 °C)
Thermal conductivity	318 W/(m·K)
Electrical resistivity	22.14 nΩ·m (at 20 °C)
Magnetic ordering	diamagnetic
Tensile strength	120 MPa
Young's modulus	79 GPa
Shear modulus	27 GPa
Bulk modulus	180 GPa
Poisson ratio	0.4
Mohs hardness	2.5
Vickers hardness	188–216 MPa
Brinell hardness	188–245 MPa
CAS Number	7440-57-5
History
Naming	from Latin aurum, meaning gold
Discovery	In the Middle East (before 6000 BCE)
Most stable isotopes of gold
	Decay modes in parentheses are predicted, but have not yet been observed
	view; talk; edit; \| references

　　[★]

英
関

英: gold compound

「go」

　　[★]

v.

(過去went-過去分詞gone)行く、進む、し始める、及ぶ、なる

関: advance、become、come、extend、get、navigate、proceed、range、reach、span、turn

「compound」

　　[★]

化合物、配合、複方の、配合する

関: combination、compositus、mixture

「gold」

　　[★]

n.

(元素)金
関: Au、golden

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