WordNet

fix or determine the value of; assign a value to; "value the jewelry and art work in the estate"
the amount (of money or goods or services) that is considered to be a fair equivalent for something else; "he tried to estimate the value of the produce at normal prices" (同)economic value
(music) the relative duration of a musical note (同)time value, note value
relative darkness or lightness of a color; "I establish the colors and principal values by organizing the painting into three values--dark, medium...and light"-Joe Hing Lowe
the quality (positive or negative) that renders something desirable or valuable; "the Shakespearean Shylock is of dubious value in the modern world"
a numerical quantity measured or assigned or computed; "the value assigned was 16 milliseconds"
an ideal accepted by some individual or group; "he has old-fashioned values"
(usually used in combination) having value of a specified kind; "triple-valued"
held in great esteem for admirable qualities especially of an intrinsic nature; "a valued friend"; "precious memories" (同)precious
a nonmetallic element belonging to the halogens; used especially in medicine and photography and in dyes; occurs naturally only in combination in small quantities (as in sea water or rocks) (同)iodin, I, atomic number 53
beliefs of a person or social group in which they have an emotional investment (either for or against something); "he has very conservatives values"

PrepTutorEJDIC

〈U〉(…の)『価値』,値打ち,有用性,重要性《+of+名》 / 〈U〉〈C〉(…の)『価格』,値段《+of+名》 / 〈U〉〈C〉《米》《修飾語句を伴って》(払った金銭に対する)正当な値打ち / 〈C〉(単語の)意味,意義 / 〈C〉値,数値 / 〈C〉音の長短 / 〈C〉色価,(色の)明暗の度 / 〈C〉《複数形で》(道義・倫理などの)価値基準,価値観 / (ある金額に)…‘を'『評価する』,見積もる《+名+at+名〈金額〉》 / …‘を'『高く評価する』,尊重する,重んじる
貴重な,高く評価される,大切な
ヨード,ヨウ素(非金属元素;化学記号は『I』)

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出典(authority):フリー百科事典『ウィキペディア（Wikipedia）』「2016/08/06 09:05:33」(JST)

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The iodine value (or "iodine adsorption value" or "iodine number" or "iodine index") in chemistry is the mass of iodine in grams that is consumed by 100 grams of a chemical substance. Iodine numbers are often used to determine the amount of unsaturation in fatty acids. This unsaturation is in the form of double bonds, which react with iodine compounds. The higher the iodine number, the more C=C bonds are present in the fat.^[1] It can be seen from the table that coconut oil is very saturated, which means it is good for making soap. On the other hand, linseed oil is highly unsaturated, which makes it a drying oil, well suited for making oil paints.

Table of iodine values

Fat	Iodine number^[1]
Tung oil	7002163000000000000♠163 – 173
Grape seed oil	7002124000000000000♠124 – 143
Palm oil	7001440000000000000♠44 – 51
Olive oil	7001800000000000000♠80 – 88
Coconut oil	7000700000000000000♠7 – 12
Palm kernel oil	7001160000000000000♠16 – 19
Cocoa butter	7001350000000000000♠35 – 40
Jojoba oil	7001800000000000000♠80 ~80
Poppyseed oil	7002133000000000000♠133 ~133
Cottonseed oil	7002100000000000000♠100 – 117
Corn oil	7002109000000000000♠109 – 133
Wheat germ oil^[2]	7002115000000000000♠115 – 134
Sunflower oil	7002125000000000000♠125 – 144
Linseed oil	7002136000000000000♠136 – 178
Soybean oil	7002120000000000000♠120 – 136
Peanut oil	7001840000000000000♠84 – 105
Rice bran oil	7001950000000000000♠95 – 108
Walnut oil^[3]	7002120000000000000♠120 – 140

Methodology

This particular analysis is an example of iodometry. A solution of iodine is yellow/brown in color. When this is added to a solution to be tested, however, any chemical group (usually in this test C=C double bonds) that react with iodine effectively reduce the strength, or magnitude of the colour (by taking iodine out of solution). Thus the amount of iodine required to make a solution retain the characteristic yellow/brown colour can effectively be used to determine the amount of iodine sensitive groups present in the solution.

The chemical reaction associated with this method of analysis involves formation of the diiodo alkane (R and R' symbolize alkyl or other organic groups):

The precursor alkene (RCH=CHR') is colourless and so is the organoiodine product (RCHI-CHIR').

In a typical procedure, the fatty acid is treated with an excess of the Hanuš or Wijs solution, which are, respectively, solutions of iodine monobromide (IBr) and iodine monochloride (ICl) in glacial acetic acid. Unreacted iodine monobromide (or monochloride) is then allowed to react with potassium iodide, converting it to iodine, whose concentration can be determined by titration with sodium thiosulfate.^[4] ^[5]

Methods for the determination of iodine value

Huebl's iodine

Introduced the iodine value was Hübl which titrated fats in the presence of mercuric chloride with iodine, but with the actual reagent (probably iodine chloride) is formed in situ from mercuric chloride and iodine. Pure iodine accumulates concerned not to alkenes, which is why the still valid definition of iodine is only a formal one.

Wijs iodine value after

Addition of iodine chloride and back-titration with sodium by DIN 53241-1:1995-05.

Iodine by H. P. Kaufmann

(Bromination of the double bonds in the dark, reducing the excess bromine with iodide, backtitration of iodine with thiosulfate)

The fat is mixed with an excess of bromine. This bromine is added to the double bonds in the unsaturated fats. This reaction must be carried out in the dark, since the formation of bromine radicals is suppressed by light. This would lead to undesirable side reactions, and thus falsifying a result consumption of bromine.

Then the unused bromine is reduced to bromide with iodide.

Now, the amount of iodine formed is determined by titration with sodium thiosulfate solution.

Related methods of analysis

Saponification value
Acid number
Bromine number
Hydroxyl value
Hydrogen number

References

^ ^a ^b Thomas, Alfred (2002). "Fats and Fatty Oils". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a10_173.
^ http://online.personalcarecouncil.org/ctfa-static/online/lists/cir-pdfs/pr248.pdf
^ http://thesoapdish.com/oil-properties-chart.htm
^ Firestone D (May–Jun 1994). "Determination of the iodine value of oils and fats: summary of collaborative study". J AOAC Int. 77 (3): 674–6. PMID 8012219.
^ Obtaining the Iodine Value of Various Oils via Bromination with Pyridinium Tribromide Michael Simurdiak, Olushola Olukoga, and Kirk Hedberg Journal of Chemical Education Article ASAP doi:10.1021/acs.jchemed.5b00283

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