マロン酸、マロン酸塩、マロン酸エステル
- 関
- malonic acid
Wikipedia preview
出典(authority):フリー百科事典『ウィキペディア(Wikipedia)』「2014/12/19 20:43:18」(JST)
[Wiki en表示]
Chemical structure of the malonate ion.
The malonate or propanedioate ion is CH2(COO)22− (malonic acid minus two hydrogen ions). Malonate compounds include salts and esters of malonic acid, such as
- diethyl malonate, (C2H5)2(C3H2O4),
- dimethyl malonate, (CH3)2(C3H2O4),
- disodium malonate, Na2(C3H2O4).
Malonate is a competitive inhibitor of the enzyme succinate dehydrogenase: malonate binds to the active site of the enzyme without reacting, and so competes with succinate, the usual substrate of the enzyme. The observation that malonate is a competitive inhibitor of succinate dehydrogenase was used to deduce the structure of the active site in that enzyme.[1][2]
See also
References
- ^ Potter, V. R.; Dubois, K. P. (1943). "Studies on the Mechanism of Hydrogen Transport in Animal Tissues : Vi. Inhibitor Studies with Succinic Dehydrogenase". The Journal of General Physiology 26 (4): 391–404. doi:10.1085/jgp.26.4.391. PMC 2142566. PMID 19873352. edit
- ^ Dervartanian DV, Veeger C. (November 1964). "Studies on succinate dehydrogenase. I. Spectral properties of the purified enzyme and formation of enzyme-competitive inhibitor complexes". Biochim. Biophys. Acta 92: 233–47. PMID 14249115.
English Journal
- Simultaneous determination of urea and melamine in milk powder by nonlinear chemical fingerprint technique.
- Ma Y1, Dong W2, Bao H3, Fang Y2, Fan C4.
- Food chemistry.Food Chem.2017 Apr 15;221:898-906. doi: 10.1016/j.foodchem.2016.11.076. Epub 2016 Nov 19.
- This paper proposed a nonlinear chemical fingerprint method for simultaneous determination of urea and melamine in milk powder using "H++Ce4++BrO3-+malonic acid" as reaction system. A multiple linear relationship was obtained between the adulterants content in milk powder and inductive time of corre
- PMID 27979291
- Spectral and colorimetric characteristics of metal chelates of acylated cyanidin derivatives.
- Sigurdson GT1, Robbins RJ2, Collins TM2, Giusti MM3.
- Food chemistry.Food Chem.2017 Apr 15;221:1088-1095. doi: 10.1016/j.foodchem.2016.11.052. Epub 2016 Nov 11.
- Colorants derived from nature are increasingly popular due to consumer demand. Anthocyanins are a class of naturally occurring pigments that produce red-purple-blue hues in nature, especially when interacting with metal ions and co-pigments. The role of various acylations of cyanidin (Cy) derivative
- PMID 27979063
- Polyketide bio-derivatization using the promiscuous acyltransferase KirCII.
- Musiol-Kroll EM, Zubeil F, Schafhauser T, Härtner T, Kulik A, McArthur JB, Koryakina I, Wohlleben W, Grond S, Williams GJ, Lee SY, Weber T.
- ACS synthetic biology.ACS Synth Biol.2017 Feb 16. doi: 10.1021/acssynbio.6b00341. [Epub ahead of print]
- During polyketide biosynthesis, acyltransferases (ATs) are the essential gatekeepers which provide the assembly lines with precursors and thus contribute greatly to structural diversity. Previously, we demonstrated that the discrete AT KirCII from the kirromycin antibiotic pathway accesses non-malon
- PMID 28206741
Japanese Journal
- Convenient synthesis of spiroindole derivatives via palladium-catalyzed cyclization of propargyl chlorides
- Novel Molecular Resist for EUV and Electron Beam Lithography
- Journal of Photopolymer Science and Technology 28(4), 537-540, 2015
- NAID 130005101112
Related Links
- [Dimethyl Malonate] [108-59-8] | 価格や在庫、物性値などの詳細情報ページです。 ... ・川口の在庫は即日,つくばの在庫は2〜3日以内の出荷となります。・詳細につきましては,お手数ですが営業部までお問い合わせください。
- malonateとは。意味や和訳。[名]《化学》マロン酸塩,マロン酸エステル. - goo英和辞書は14万項目以上を収録し、発音、音声、慣用句、例文が分かる英和辞書です。
Related Pictures
★リンクテーブル★
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- 英
- malonate, malonic acid
- 同
- プロパン二酸 propanedioic acid
- 関
- ジカルボン酸、コハク酸。メチルマロン酸
- コハク酸の構造に類似 → コハク酸脱水素酵素の働きを競合的に阻害 → ミトコンドリアの呼吸阻害薬
[★]
- 英
- malonate
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- マロン酸、マロン酸エステル
[★]
- 英
- malonate
- 関
- マロン酸、マロン酸塩
[★]
マロン酸
- 関
- malonate
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マロン酸セミアルデヒド脱水素酵素、マロン酸セミアルデヒドデヒドロゲナーゼ
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- 関
- perazine、perazine fendizoate、perazine maleate
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メチルマロン酸セミアルデヒド脱水素酵素
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- 関
- bopindolol