出典(authority):フリー百科事典『ウィキペディア（Wikipedia）』「2015/11/04 02:00:13」(JST)
Sulfites or sulphites are compounds that contain the sulfite ion SO32−. The sulfite ion is the conjugate base of bisulfite. Although its acid (sulfurous acid) is elusive,[1] its salts are widely used.
Sulfites are substances that naturally occur in some foods and the human body. They are also used as regulated food additives.[2]
The structure of the sulfite anion can be described with three equivalent resonance structures. In each resonance structure, the sulfur atom is double-bonded to one oxygen atom with a formal charge of zero (neutral), and sulfur is singly bonded to the other two oxygen atoms, which each carry a formal charge of −1, together accounting for the −2 charge on the anion. There is also a non-bonded lone pair on the sulfur, so the structure predicted by VSEPR theory is trigonal pyramidal, as in ammonia (NH3). In the hybrid resonance structure, the S-O bonds are equivalently of bond order one and one-third.
Evidence from 17O NMR spectroscopic data suggests that protonation of the sulfite ion gives a mixture of isomers:[1]
Sulfites are used as a food preservative or enhancer. They may come in various forms, such as:[3]
Sulfites occur naturally in all wines to some extent.[4] Sulfites are commonly introduced to arrest fermentation at a desired time, and may also be added to wine as preservatives to prevent spoilage and oxidation at several stages of the winemaking. Sulfur dioxide (SO2, sulfur with two atoms of oxygen) protects wine from not only oxidation, but also from bacteria. Without sulfites, grape juice would quickly turn to vinegar.[5]
Organic wines are not necessarily sulfite-free, but generally have lower amounts and regulations stipulate lower maximum sulfite contents for these wines. In general, white wines contain more sulfites than red wines and sweeter wines contain more sulfites than drier ones.[6]
In the United States, wines bottled after mid-1987 must have a label stating that they contain sulfites if they contain more than 10 parts per million.[7]
In the European Union an equivalent regulation came into force in November 2005.[8] In 2012, a new regulation for organic wines came into force.
Sulfites are often used as preservatives in dried fruits, preserved radish, and dried potato products.
Most beers no longer contain sulfites, although some alcoholic ciders contain them. Although shrimp are sometimes treated with sulfites on fishing vessels, the chemical may not appear on the label. In 1986, the Food and Drug Administration in the United States banned the addition of sulfites to all fresh fruit and vegetables that are eaten raw.[9]
E numbers for sulfites as food additives are:
| E150b | Caustic sulfite caramel |
| E150d | Sulfite ammonia caramel |
| E220 | Sulfur dioxide |
| E221 | Sodium sulfite |
| E222 | Sodium bisulfite (sodium hydrogen sulfite) |
| E223 | Sodium metabisulfite |
| E224 | Potassium metabisulfite |
| E225 | Potassium sulfite |
| E226 | Calcium sulfite |
| E227 | Calcium hydrogen sulfite (preservative) |
| E228 | Potassium hydrogen sulfite |
Sulfites are counted among the top nine food allergens,[10] but a reaction to sulfite is not a true allergy.[11] Some people have positive skin allergy tests to sulfites indicating true (IgE-mediated) allergy.[12]
It may cause breathing difficulty within minutes after eating a food containing it.[13] Asthmatics[14][15] and possibly people with salicylate sensitivity (or aspirin sensitivity)[16][17] are at an elevated risk for reaction to sulfites. Anaphylaxis and life-threatening reactions are rare.[12] Other potential symptoms include sneezing, swelling of the throat, hives, and migraine.[17][18][19]
In 1986, the U.S. Food and Drug Administration banned the use of sulfites as preservatives on foods intended to be eaten fresh (such as salad ingredients).[9] This has contributed to the increased use of erythorbic acid and its salts as preservatives.[20]
In the U.S., labeling regulations do not require products to indicate the presence of sulfites in foods unless it is added specifically as a preservative;[9] however, many companies voluntarily label sulfite-containing foods.[21] Sulfites used in food processing, but not specifically added as a preservative, are only required to be listed if there are more than 10 parts per million (ppm) in the finished product.
The products most likely to contain sulfites (fruits and alcoholic beverages less than 10ppm) do not require ingredients labels, so the presence of sulfites usually is undisclosed.
In Australia and New Zealand, sulfites must be declared in the statement of ingredients when present in packaged foods in concentrations of 10 mg/kg (ppm) or more as an ingredient; or as an ingredient of a compound ingredient; or as a food additive or component of a food additive; or as a processing aid or component of a processing aid.[22]
The sulphites that can be added to foods in Canada are potassium bisulphite, potassium metabisulphite, sodium bisulphite, sodium dithionite, sodium metabisulphite, sodium sulphite, sulphur dioxide and sulphurous acid. These can also be declared using the common names sulfites, sulphites, sulfiting agents or sulphiting agents.[2]
High sulfite content in the blood and urine of babies can be caused by molybdenum cofactor deficiency disease which leads to neurological damage and early death unless treated. Treatment, requiring daily injections, became available in 2009.[23]
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| リンク元 | 「亜硫酸」「sulfurous acid」「sulfurous」「亜硫酸塩」 |
| 拡張検索 | 「hydrogensulfite reductase」「sulfite oxidase」「sulfite reductase」「sodium bisulfite」「sodium pyrosulfite」 |
[★] 亜硫酸水素還元酵素、亜硫酸水素レダクターゼ、重亜硫酸還元酵素、重亜硫酸レダクターゼ