出典(authority):フリー百科事典『ウィキペディア（Wikipedia）』「2017/07/30 04:47:17」(JST)
A blast furnace is a type of metallurgical furnace used for smelting to produce industrial metals, generally iron, but also others such as lead or copper.
In a blast furnace, fuel, ores, and flux (limestone) are continuously supplied through the top of the furnace, while a hot blast of air (sometimes with oxygen enrichment) is blown into the lower section of the furnace through a series of pipes called tuyeres, so that the chemical reactions take place throughout the furnace as the material moves downward. The end products are usually molten metal and slag phases tapped from the bottom, and flue gases exiting from the top of the furnace. The downward flow of the ore and flux in contact with an upflow of hot, carbon monoxide-rich combustion gases is a countercurrent exchange and chemical reaction process.[1]
In contrast, air furnaces (such as reverberatory furnaces) are naturally aspirated, usually by the convection of hot gases in a chimney flue. According to this broad definition, bloomeries for iron, blowing houses for tin, and smelt mills for lead would be classified as blast furnaces. However, the term has usually been limited to those used for smelting iron ore to produce pig iron, an intermediate material used in the production of commercial iron and steel, and the shaft furnaces used in combination with sinter plants in base metals smelting.[2][3]
Blast furnaces existed in China from about 1st century AD[4] and in the West from the High Middle Ages. They spread from the region around Namur in Wallonia (Belgium) in the late 15th century, being introduced to England in 1491. The fuel used in these was invariably charcoal. The successful substitution of coke for charcoal is widely attributed to Abraham Darby in 1709. The efficiency of the process was further enhanced by the practice of preheating the combustion air (hot blast), patented by James Beaumont Neilson in 1828.[5]
The oldest extant blast furnaces were built during the Han Dynasty of China in the 1st century AD. However, cast iron farm tools and weapons were widespread in China by the 5th century BC,[6] while 3rd century BC iron smelters employed an average workforce of over two hundred men.[6] These early furnaces had clay walls and used phosphorus-containing minerals as a flux.[7] The effectiveness of the Chinese blast furnace was enhanced during this period by the engineer Du Shi (c. 31 AD), who applied the power of waterwheels to piston-bellows in forging cast iron.[8]
While it was long thought that the Chinese had developed the blast furnace and cast iron as their first method of iron production, Donald Wagner (the author of the above referenced study) has published a more recent paper[9] that supersedes some of the statements in the earlier work; the newer paper still places the date of the first cast-iron artifacts at the 5th and 4th centuries BC, but also provides evidence of earlier bloomery furnace use, which migrated from China to Western parts and Central Asia during the beginning of the Chinese Bronze Age of the late Longshan culture (2000 BC). He suggests that early blast furnace and cast iron production evolved from furnaces used to melt bronze. Certainly, though, iron was essential to military success by the time the State of Qin had unified China (221 BC). Usage of the blast and cupola furnace remained widespread during the Song and Tang Dynasties.[10] By the 11th century AD, the Song Dynasty Chinese iron industry made a remarkable switch of resources from charcoal to bituminous coal in casting iron and steel, sparing thousands of acres of woodland from felling. This may have happened as early as the 4th century AD.[11][12]
The Chinese blast furnace remained in use well until the 20th century. The backyard furnaces favoured by Mao Zedong during the Great Leap Forward were of this type. In the regions with strong traditions of metallurgy, the steel production actually increased during this period. In the regions where there was no tradition of steelmaking or where the ironmasters knowing the traditional skills or the scientific principles of the blast furnace process had been killed, the results were less than satisfactory.
Recent evidence,shows that bloomeries were used in China, migrating in from the west as early as 800 BC, before being supplanted by the locally developed blast furnace. Supporting this theory was the discovery of 'more than ten' iron digging implements found in the tomb of Duke Jing of Qin (d. 537 BCE), whose tomb is located in Fengxiang County, Shaanxi (a museum exists on the site today).[13] In Europe, the Greeks, Celts, Romans, and Carthaginians all used this process. Several examples have been found in France, and materials found in Tunisia suggest they were used there as well as in Antioch (south-central Turkey, between Syria and the Mediterranean Sea) during the Hellenistic Period. Though little is known of it during the Dark Ages, the process probably continued in use.[citation needed] Similarly, smelting in bloomery-type furnaces in West Africa and forging for tools appear in the Nok culture in Africa by 500 BC.[14] The earliest records of bloomery-type furnaces in East Africa are discoveries of smelted iron and carbon in Nubia and that date back between 1,000–500 BCE.[15][16] Particularly in Meroë, there are known to have been ancient bloomeries that produced metal tools for the Nubians and Kushites and produced surplus for their economy.
Bloomeries have also been discovered and recorded to have been created in medieval West Africa with some of the metalworking Bantu civilizations such as the Bunyoro Empire and the Nyoro people.[17]
The simplest forge, known as the Corsican, was used prior to the advent of Christianity. Examples of improved bloomeries are the Stückofen[fr][18] (sometimes called wolf-furnace[19]) or the Catalan forge, which remained until the beginning of the 19th century. The Catalan forge was invented in Catalonia, Spain, during the 8th century. Instead of using natural draught, air was pumped in by a trompe, resulting in better quality iron and an increased capacity. This pumping of airstream in with bellows is known as cold blast, and it increases the fuel efficiency of the bloomery and improves yield. The Catalan forges can also be built bigger than natural draught bloomeries.
Modern experimental archaeology and history re-enactment have shown there is only a very short step from the Catalan forge to the true blast furnace, where the iron is gained as pig iron in liquid phase. Usually, obtaining the iron in liquid phase is actually undesired, and the temperature is intentionally kept below the melting point of iron, since while removing the solid bloom mechanically is tedious and means batch process instead of continuous process, it is almost pure iron and can be worked immediately. On the other hand, pig iron is the eutectic mixture of carbon and iron and needs to be decarburized to produce steel or wrought iron, which was extremely tedious in the Middle Ages.
The oldest known blast furnaces in the West were built in Dürstel in Switzerland, the Märkische Sauerland in Germany, and at Lapphyttan in Sweden, where the complex was active between 1205 and 1300.[20] At Noraskog in the Swedish parish of Järnboås, there have also been found traces of blast furnaces dated even earlier, possibly to around 1100.[21] These early blast furnaces, like the Chinese examples, were very inefficient compared to those used today. The iron from the Lapphyttan complex was used to produce balls of wrought iron known as osmonds, and these were traded internationally – a possible reference occurs in a treaty with Novgorod from 1203 and several certain references in accounts of English customs from the 1250s and 1320s. Other furnaces of the 13th to 15th centuries have been identified in Westphalia.[22]
The technology required for blast furnaces may have either been transferred from China, or may have been an indigenous innovation. Al-Qazvini in the 13th century and other travellers subsequently noted an iron industry in the Alburz Mountains to the south of the Caspian Sea. This is close to the silk route, so that the use of technology derived from China is conceivable. Much later descriptions record blast furnaces about three metres high.[23] As the Varangian Rus' people from Scandinavia traded with the Caspian (using their Volga trade route, it is possible that the technology reached Sweden by this means.[24] High quality ores, water power for bellows for blast and wood for charcoal are readily obtainable in Sweden. However, since blast furnace has also been invented independently in Africa by the Haya people, it is more likely the process has been invented in Scandinavia independently. The step from bloomery to true blast furnace is not big. Simply just building a bigger furnace and using bigger bellows to increase the volume of the blast and hence the amount of oxygen leads inevitably into higher temperatures, bloom melting into liquid iron and, cast iron flowing from the smelters. Already the Vikings are known to have used double bellows, which greatly increases the volumetric flow of the blast.[25]
This Caspian region may also separately be the technological source for at furnace at Ferriere, described by Filarete.[26] Water-powered bellows at Semogo in northern Italy in 1226 in a two-stage process. In this, the molten iron was tapped twice a day into water thereby granulating it.[27]
One means by which certain technological advances were transmitted within Europe was a result of the General Chapter of the Cistercian monks. This may have included the blast furnace, as the Cistercians are known to have been skilled metallurgists.[28] According to Jean Gimpel, their high level of industrial technology facilitated the diffusion of new techniques: "Every monastery had a model factory, often as large as the church and only several feet away, and waterpower drove the machinery of the various industries located on its floor." Iron ore deposits were often donated to the monks along with forges to extract the iron, and within time surpluses were being offered for sale. The Cistercians became the leading iron producers in Champagne, France, from the mid-13th century to the 17th century,[29] also using the phosphate-rich slag from their furnaces as an agricultural fertilizer.[30]
Archaeologists are still discovering the extent of Cistercian technology.[31] At Laskill, an outstation of Rievaulx Abbey and the only medieval blast furnace so far identified in Britain, the slag produced was low in iron content.[32] Slag from other furnaces of the time contained a substantial concentration of iron, whereas Laskill is believed to have produced cast iron quite efficiently.[32][33][34] Its date is not yet clear, but it probably did not survive until Henry VIII's Dissolution of the Monasteries in the late 1530s, as an agreement (immediately after that) concerning the "smythes" with the Earl of Rutland in 1541 refers to blooms.[35] Nevertheless, the means by which the blast furnace spread in medieval Europe has not finally been determined.
The direct ancestor of these used in France and England was in the Namur region in what is now Wallonia (Belgium). From there, they spread first to the Pays de Bray on the eastern boundary of Normandy and from there to the Weald of Sussex, where the first furnace (called Queenstock) in Buxted was built in about 1491, followed by one at Newbridge in Ashdown Forest in 1496. They remained few in number until about 1530 but many were built in the following decades in the Weald, where the iron industry perhaps reached its peak about 1590. Most of the pig iron from these furnaces was taken to finery forges for the production of bar iron.[36]
The first British furnaces outside the Weald appeared during the 1550s, and many were built in the remainder of that century and the following ones. The output of the industry probably peaked about 1620, and was followed by a slow decline until the early 18th century. This was apparently because it was more economic to import iron from Sweden and elsewhere than to make it in some more remote British locations. Charcoal that was economically available to the industry was probably being consumed as fast as the wood to make it grew.[37] The Backbarrow blast furnace built in Cumbria in 1711 has been described as the first efficient example.[who?]
The first blast furnace in Russia opened in 1637 near Tula and was called the Gorodishche Works. The blast furnace spread from here to the central Russia and then finally to the Urals.[38]
In 1709, at Coalbrookdale in Shropshire, England, Abraham Darby began to fuel a blast furnace with coke instead of charcoal. Coke's initial advantage was its lower cost, mainly because making coke required much less labor than cutting trees and making charcoal, but using coke also overcame localized shortages of wood, especially in Britain and on the Continent. Metallurgical grade coke will bear heavier weight than charcoal, allowing larger furnaces.[39][40] A disadvantage is that coke contains more impurities than charcoal, with sulfur being especially detrimental to the iron's quality.
Coke iron was initially only used for foundry work, making pots and other cast iron goods. Foundry work was a minor branch of the industry, but Darby's son built a new furnace at nearby Horsehay, and began to supply the owners of finery forges with coke pig iron for the production of bar iron. Coke pig iron was by this time cheaper to produce than charcoal pig iron. The use of a coal-derived fuel in the iron industry was a key factor in the British Industrial Revolution.[41][42][43] Darby's original blast furnace has been archaeologically excavated and can be seen in situ at Coalbrookdale, part of the Ironbridge Gorge Museums. Cast iron from the furnace was used to make girders for the world's first iron bridge in 1779. The Iron Bridge crosses the River Severn at Coalbrookdale and remains in use for pedestrians.
Hot Blast was the single most important advance in fuel efficiency of the blast furnace and was one of the most important technologies developed during the Industrial Revolution.[44][45] Hot blast was patented by James Beaumont Neilson at Wilsontown Ironworks in Scotland in 1828. Within a few years of the introduction, hot blast was developed to the point where fuel consumption was cut by one-third using coke or two-thirds using coal, while furnace capacity was also significantly increased. Within a few decades, the practice was to have a "stove" as large as the furnace next to it into which the waste gas (containing CO) from the furnace was directed and burnt. The resultant heat was used to preheat the air blown into the furnace.[46]
Hot blast enabled the use of raw anthracite coal, which was difficult to light, to the blast furnace. Anthracite was first tried successfully by George Crane at Ynyscedwyn ironworks in south Wales in 1837.[47] It was taken up in America by the Lehigh Crane Iron Company at Catasauqua, Pennsylvania, in 1839.
The blast furnace remains an important part of modern iron production. Modern furnaces are highly efficient, including Cowper stoves to pre-heat the blast air and employ recovery systems to extract the heat from the hot gases exiting the furnace. Competition in industry drives higher production rates. The largest blast furnaces have a volume around 5,580 m3 (197,000 cu ft)[48] and can produce around 80,000 tonnes (79,000 long tons; 88,000 short tons) of iron per week.[needs update]
This is a great increase from the typical 18th-century furnaces, which averaged about 360 tonnes (350 long tons; 400 short tons) per year. Variations of the blast furnace, such as the Swedish electric blast furnace, have been developed in countries which have no native coal resources.
Blast furnaces are currently rarely used in copper smelting, but modern lead smelting blast furnaces are much shorter than iron blast furnaces and are rectangular in shape.[49] The overall shaft height is around 5 to 6 m.[50] Modern lead blast furnaces are constructed using water-cooled steel or copper jackets for the walls, and have no refractory linings in the side walls.[49] The base of the furnace is a hearth of refractory material (bricks or castable refractory).[49] Lead blast furnaces are often open-topped rather than having the charging bell used in iron blast furnaces.[51]
The blast furnace used at the Nyrstar Port Pirie lead smelter differs from most other lead blast furnaces in that it has a double row of tuyeres rather than the single row normally used.[50] The lower shaft of the furnace has a chair shape with the lower part of the shaft being narrower than the upper.[50] The lower row of tuyeres being located in the narrow part of the shaft.[50] This allows the upper part of the shaft to be wider than the standard.[50]
The blast furnaces used in the Imperial Smelting Process ("ISP") were developed from the standard lead blast furnace, but are fully sealed.[52] This is because the zinc produced by these furnaces is recovered as metal from the vapor phase, and the presence of oxygen in the off-gas would result in the formation of zinc oxide.[52]
Blast furnaces used in the ISP have a more intense operation than standard lead blast furnaces, with higher air blast rates per m2 of hearth area and a higher coke consumption.[52]
Zinc production with the ISP is more expensive than with electrolytic zinc plants, so several smelters operating this technology have closed in recent years.[53] However, ISP furnaces have the advantage of being able to treat zinc concentrates containing higher levels of lead than can electrolytic zinc plants.[52]
Blast furnace placed in an installation
Blast furnace diagram
Modern furnaces are equipped with an array of supporting facilities to increase efficiency, such as ore storage yards where barges are unloaded. The raw materials are transferred to the stockhouse complex by ore bridges, or rail hoppers and ore transfer cars. Rail-mounted scale cars or computer controlled weight hoppers weigh out the various raw materials to yield the desired hot metal and slag chemistry. The raw materials are brought to the top of the blast furnace via a skip car powered by winches or conveyor belts.[54]
There are different ways in which the raw materials are charged into the blast furnace. Some blast furnaces use a "double bell" system where two "bells" are used to control the entry of raw material into the blast furnace. The purpose of the two bells is to minimize the loss of hot gases in the blast furnace. First, the raw materials are emptied into the upper or small bell which then opens to empty the charge into the large bell. The small bell then closes, to seal the blast furnace, while the large bell rotates to provide specific distribution of materials before dispensing the charge into the blast furnace.[55][56] A more recent design is to use a "bell-less" system. These systems use multiple hoppers to contain each raw material, which is then discharged into the blast furnace through valves.[55] These valves are more accurate at controlling how much of each constituent is added, as compared to the skip or conveyor system, thereby increasing the efficiency of the furnace. Some of these bell-less systems also implement a discharge chute in the throat of the furnace (as with the Paul Wurth top) in order to precisely control where the charge is placed.[57]
The iron making blast furnace itself is built in the form of a tall structure, lined with refractory brick, and profiled to allow for expansion of the charged materials as they heat during their descent, and subsequent reduction in size as melting starts to occur. Coke, limestone flux, and iron ore (iron oxide) are charged into the top of the furnace in a precise filling order which helps control gas flow and the chemical reactions inside the furnace. Four "uptakes" allow the hot, dirty gas high in carbon monoxide content to exit the furnace throat, while "bleeder valves" protect the top of the furnace from sudden gas pressure surges. The coarse particles in the exhaust gas settle in the "dust catcher" and are dumped into a railroad car or truck for disposal, while the gas itself flows through a venturi scrubber and/or electrostatic precipitators and a gas cooler to reduce the temperature of the cleaned gas.[54]
The "casthouse" at the bottom half of the furnace contains the bustle pipe, water cooled copper tuyeres and the equipment for casting the liquid iron and slag. Once a "taphole" is drilled through the refractory clay plug, liquid iron and slag flow down a trough through a "skimmer" opening, separating the iron and slag. Modern, larger blast furnaces may have as many as four tapholes and two casthouses.[54] Once the pig iron and slag has been tapped, the taphole is again plugged with refractory clay.
The tuyeres are used to implement a hot blast, which is used to increase the efficiency of the blast furnace. The hot blast is directed into the furnace through water-cooled copper nozzles called tuyeres near the base. The hot blast temperature can be from 900 °C to 1300 °C (1600 °F to 2300 °F) depending on the stove design and condition. The temperatures they deal with may be 2000 °C to 2300 °C (3600 °F to 4200 °F). Oil, tar, natural gas, powdered coal and oxygen can also be injected into the furnace at tuyere level to combine with the coke to release additional energy and increase the percentage of reducing gases present which is necessary to increase productivity.[54]
Blast furnaces operate on the principle of chemical reduction whereby carbon monoxide, having a stronger affinity for the oxygen in iron ore than iron does, reduces the iron to its elemental form. Blast furnaces differ from bloomeries and reverberatory furnaces in that in a blast furnace, flue gas is in direct contact with the ore and iron, allowing carbon monoxide to diffuse into the ore and reduce the iron oxide to elemental iron mixed with carbon. The blast furnaces operates as a countercurrent exchange process whereas a bloomery does not. Another difference is that bloomeries operate as a batch process while blast furnaces operate continuously for long periods because they are difficult to start up and shut down. (See: Continuous production) Also, the carbon in pig iron lowers the melting point below that of steel or pure iron; in contrast, iron does not melt in a bloomery.
Carbon monoxide also reduces silica which has to be removed from the pig iron. The silica is reacted with calcium oxide (burned limestone) and forms a slag which floats to the surface of the molten pig iron. The direct contact of flue gas with the iron causes contamination with sulfur if it is present in the fuel. Historically, to prevent contamination from sulfur, the best quality iron was produced with charcoal.
The downward moving column of ore, flux, coke or charcoal and reaction products must be porous enough for the flue gas to pass through. This requires the coke or charcoal to be in large enough particles to be permeable, meaning there cannot be an excess of fine particles. Therefore, the coke must be strong enough so it will not be crushed by the weight of the material above it. Besides physical strength of the coke, it must also be low in sulfur, phosphorus, and ash. This necessitates the use of metallurgical coal, which is a premium grade due to its relative scarcity.
The main chemical reaction producing the molten iron is:
This reaction might be divided into multiple steps, with the first being that preheated blast air blown into the furnace reacts with the carbon in the form of coke to produce carbon monoxide and heat:
The hot carbon monoxide is the reducing agent for the iron ore and reacts with the iron oxide to produce molten iron and carbon dioxide. Depending on the temperature in the different parts of the furnace (warmest at the bottom) the iron is reduced in several steps. At the top, where the temperature usually is in the range between 200 °C and 700 °C, the iron oxide is partially reduced to iron(II,III) oxide, Fe3O4.
At temperatures around 850 °C, further down in the furnace, the iron(II,III) is reduced further to iron(II) oxide:
Hot carbon dioxide, unreacted carbon monoxide, and nitrogen from the air pass up through the furnace as fresh feed material travels down into the reaction zone. As the material travels downward, the counter-current gases both preheat the feed charge and decompose the limestone to calcium oxide and carbon dioxide:
The calcium oxide formed by decomposition reacts with various acidic impurities in the iron (notably silica), to form a fayalitic slag which is essentially calcium silicate, CaSiO3:[58]
As the iron(II) oxide moves down to the area with higher temperatures, ranging up to 1200 °C degrees, it is reduced further to iron metal:
The carbon dioxide formed in this process is re-reduced to carbon monoxide by the coke:
The temperature-dependent equilibrium controlling the gas atmosphere in the furnace is called the Boudouard reaction:
The "pig iron" produced by the blast furnace has a relatively high carbon content of around 4–5%, making it very brittle, and of limited immediate commercial use. Some pig iron is used to make cast iron. The majority of pig iron produced by blast furnaces undergoes further processing to reduce the carbon content and produce various grades of steel used for construction materials, automobiles, ships and machinery.
Although the efficiency of blast furnaces is constantly evolving, the chemical process inside the blast furnace remains the same. According to the American Iron and Steel Institute: "Blast furnaces will survive into the next millennium because the larger, efficient furnaces can produce hot metal at costs competitive with other iron making technologies."[54] One of the biggest drawbacks of the blast furnaces is the inevitable carbon dioxide production as iron is reduced from iron oxides by carbon and as of 2016, there is no economical substitute – steelmaking is one of the largest industrial contributors of the CO2 emissions in the world (see greenhouse gases).
The challenge set by the greenhouse gas emissions of the blast furnace is being addressed in an ongoing European Program called ULCOS (Ultra Low CO2 Steelmaking).[61] Several new process routes have been proposed and investigated in depth to cut specific emissions (CO2 per ton of steel) by at least 50%. Some rely on the capture and further storage (CCS) of CO2, while others choose decarbonizing iron and steel production, by turning to hydrogen, electricity and biomass.[62] In the nearer term, a technology that incorporates CCS into the blast furnace process itself and is called the Top-Gas Recycling Blast Furnace is under development, with a scale-up to a commercial size blast furnace under way. The technology should be fully demonstrated by the end of the 2010s, in line with the timeline set, for example, by the EU to cut emissions significantly. Broad deployment could take place from 2020 on.[citation needed]
Stone wool or rock wool is a spun mineral fibre used as an insulation product and in hydroponics. It is manufactured in a blast furnace fed with diabase rock which contains very low levels of metal oxides. The resultant slag is drawn off and spun to form the rock wool product.[63] Very small amounts of metals are also produced which are an unwanted by-product and run to waste.
For a long time, it was normal procedure for a decommissioned blast furnace to be demolished and either be replaced with a newer, improved one, or to have the entire site demolished to make room for follow-up use of the area. In recent decades, several countries have realized the value of blast furnaces as a part of their industrial history. Rather than being demolished, abandoned steel mills were turned into museums or integrated into multi-purpose parks. The largest number of preserved historic blast furnaces exists in Germany; other such sites exist in Spain, France, the Czech Republic, Japan, Luxembourg, Poland, Romania, Mexico, Russia and the United States.
...earliest blast furnace discovered in China from about the first century AD
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