出典(authority):フリー百科事典『ウィキペディア(Wikipedia)』「2013/02/26 16:12:45」(JST)
Lye is a collective term referring to a strong alkali which is highly soluble in water to produce caustic basic solutions. It is commonly the alternative name of sodium hydroxide (NaOH) or historically potassium hydroxide (KOH).
Today, lye is commercially manufactured using a membrane cell method and widely available as flakes, pellets, microbeads, coarse powder or even a saturated solution for many uses, including clandestine production of the drug methamphetamine, soap making, biodiesel production, household uses, and food preparation.
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Here are some prominent examples of the uses of lye:
Lye is used to cure many types of food, such as lutefisk, green olives, canned mandarin oranges, hominy, lye rolls, century eggs, and pretzels. It is also used as a tenderizer in the crust of baked Cantonese moon cakes, and in lye-water "zongzi" (glutenous rice dumplings wrapped in bamboo leaves), in chewy southern Chinese noodles popular in Hong Kong and southern China, and in Japanese ramen. In the United States, food-grade lye must meet the requirements outlined in the Food Chemicals Codex (FCC),[1] as prescribed by the U.S. Food and Drug Administration (FDA).[2] Lower grades of lye are commonly used as drain openers and oven cleaners and should not be used for food preparation.[2]
Both sodium hydroxide and potassium hydroxide are used in soap making. Sodium hydroxide is often used to make solid soap while potassium hydroxide is used to make liquid soap.[3] Soaps made of potassium hydroxide are softer and can more easily be dissolved in water than sodium hydroxide soaps.[4]
When used in making soap, sodium hydroxide cannot be substituted for potassium hydroxide and vice versa because soap making recipes will have different quantity requirements for these two chemicals depending on the kind of soap being manufactured. In addition, the quantities required for soap saponification differ when using caustic soda and hydrated potash.[5]
Lye is also valued for its cleaning effect. It is commonly the major constituent in oven cleaners and drain openers due to its capability of dissolving grease. It decomposes greases via alkaline ester hydrolysis to yield water soluble products which can be easily removed.
In common with other corrosives, the major concern is its effects on living tissue, including skin, flesh and cornea. Its solutions are capable of causing chemical burns, permanent injuries or scarring and blindness upon contact. Lye may be harmful or even fatal if swallowed. Its ingestion can cause esophageal stricture. Moreover, solvation of dry solid lye is highly exothermic, and the resulting heat may cause additional burns or ignite flammables.
The reaction between sodium hydroxide and a few metals is also hazardous. Aluminium reacts with lye to produce hydrogen gases. Since hydrogen is flammable, mixing a large quantity of lye (e.g. sodium hydroxide) and aluminium in a closed container is dangerous - especially when the system is at a high temperature, which speeds up the reaction. In addition to aluminium, lye may also react with magnesium, galvanized zinc, tin, chromium, brass, and bronze to produce hydrogen gas.
Personal protective equipment including safety glasses, chemical-resistant gloves, and adequate ventilation are required for the safe handling of lye. When in proximity to lye that is dissolving in an open container of water, the use of a vapor-resistant face mask is recommended. Be aware that adding too much lye to water too quickly can cause the solution to boil and gush.[6]
Lye is a deliquescent and has a strong affinity for air moisture. Lye will deliquesce or dissolve when exposed to open air, absorbing a relatively large amount of water vapour. Accordingly, it should be stored in air-tight plastic containers. Glass is not a good material to be used for storage as lye is mildly corrosive to it. Similar to the case of other corrosives, the containers should be labeled to indicate the potential danger of the contents and stored away from children, pets, heat, and moisture.[6]
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