PrepTutorEJDIC

=Communist Party

English Journal

Study of the Reactivity of [Hydroxy(tosyloxy)iodo]benzene Toward Enol Esters to Access α-Tosyloxy Ketones.

Basdevant B1, Legault CY1.
The Journal of organic chemistry.J Org Chem.2015 Jul 2;80(13):6897-902. doi: 10.1021/acs.joc.5b00948. Epub 2015 Jun 22.
The reactivity of enol esters toward [hydroxy(tosyloxy)iodo]benzene (HTIB) was assessed. These substrates were found to be rapidly converted in high yields to their corresponding α-tosyloxy ketones. This transformation demonstrates that these substrates can act as ketone surrogates. The scope of th
PMID 26098233

Syntheses of Dihydroconduramines (±)-B-1, (±)-E-1, and (±)-F-1 via Diastereoselective Epoxidation of N-Protected 4-Aminocyclohex-2-en-1-ols.

Brennan MB1, Csatayová K1, Davies SG1, Fletcher AM1, Green WD1, Lee JA1, Roberts PM1, Russell AJ1, Thomson JE1.
The Journal of organic chemistry.J Org Chem.2015 Jul 2;80(13):6609-18. doi: 10.1021/acs.joc.5b00716. Epub 2015 Jun 15.
Diastereoselective syntheses of dihydroconduramines (±)-B-1, (±)-E-1, and (±)-F-1 have been achieved from N-protected 4-aminocyclohex-2-en-1-ols via two complementary procedures for epoxidation as the key step. Treatment of either trans- or cis-4-N-benzylaminocyclohex-2-en-1-ol with Cl3CCO2H and
PMID 25942585

Iodoarene-Catalyzed Stereospecific Intramolecular sp(3) C-H Amination: Reaction Development and Mechanistic Insights.

Zhu C1, Liang Y, Hong X, Sun H1, Sun WY1, Houk KN, Shi Z1.
Journal of the American Chemical Society.J Am Chem Soc.2015 Jun 24;137(24):7564-7. doi: 10.1021/jacs.5b03488. Epub 2015 Jun 11.
A new strategy is reported for intramolecular sp(3) C-H amination under mild reaction conditions using iodoarene as catalyst and m-CPBA as oxidant. This C-H functionalization involving iodine(III) reagents generated in situ occurs readily at sterically hindered tertiary C-H bonds. DFT (M06-2X) calcu
PMID 26035639

Japanese Journal

有機触媒による酸化的炭素-炭素二重結合切断反応

宮本和範,落合正仁
有機合成化学協会誌 68(3), 228-237, 2010-03-01
Oxidative cleavage of carbon–carbon double bonds to carbonyl compounds is an essential operation in organic synthesis. Ozonolysis is generally accepted as the standard method for this direct tra …
NAID 10026868188

ビタミン関係葉酸 (広範囲血液・尿化学検査免疫学的検査(第7版・2)その数値をどう読むか) -- (生化学的検査(2))

内山幸信
日本臨床 68(-) (970), 195-200, 2010-01
NAID 40016932817

Synthesis of nitrosoalkyl- and amino-substituted α,β-unsaturated ketones by cleavage of the N-O-bond of bicyclic Δ[4]-isoxazolines

Lager Markku,Dietrich Paul,Weinrich Dirk [他]
Heterocycles 74(-), 743-761, 2007-12
NAID 40015919625

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