- 関
- volatile、volatilization
WordNet
- make volatile; cause to pass off in a vapor (同)volatilise
- tending to vary often or widely; "volatile stocks"; "volatile emotions"
- a volatile substance; a substance that changes readily from solid or liquid to a vapor; "it was heated to evaporate the volatiles"
- evaporating readily at normal temperatures and pressures; "volatile oils"; "volatile solvents"
PrepTutorEJDIC
- (液体が)揮発性の,揮発しやすい / (人・性格が)変わりやすい,気まぐれの / 不安定な;爆発しやすい / 怒りやすい,短気な
Wikipedia preview
出典(authority):フリー百科事典『ウィキペディア(Wikipedia)』「2015/11/09 09:56:38」(JST)
[Wiki en表示]
In chemistry and physics, volatility is the tendency of a substance to vaporize. Volatility is directly related to a substance's vapor pressure. At a given temperature, a substance with higher vapor pressure vaporizes more readily than a substance with a lower vapor pressure.[1][2][3][4]
The term is primarily written to be applied to liquids; however, it may be used to describe the process of sublimation which is associated with solid substances, such as dry ice (solid carbon dioxide) and ammonium chloride, which can change directly from the solid state to a vapor without becoming liquid.
A typical vapor pressure chart for various liquids
Contents
- 1 Relations between vapor pressure, temperature, and boiling point
- 2 See also
- 3 References
- 4 External links
Relations between vapor pressure, temperature, and boiling point
Main article: Vapor pressure
The vapor pressure of a substance is the pressure at which its gas phase is in equilibrium with its condensed phases (liquid or solid). It is a measure of the tendency of molecules and atoms to escape from a liquid or a solid. A liquid's atmospheric pressure boiling point corresponds to the temperature at which its vapor pressure is equal to the surrounding atmospheric pressure and it is often called the normal boiling point.
The higher the vapor pressure of a liquid at a given temperature, the higher the volatility and the lower the normal boiling point of the liquid. The vapor pressure chart (right hand side) displays the vapor pressures dependency for a variety of liquids as a function of temperature.[5]
For example, at any given temperature, methyl chloride has the highest vapor pressure of any of the liquids in the chart. It also has the lowest normal boiling point (−24.2 °C), which is where the vapor pressure curve of methyl chloride (the blue line) intersects the horizontal pressure line of one atmosphere (atm) of absolute vapor pressure.
See also
- Clausius–Clapeyron relation
- Distillation
- Fractional distillation
- Partial pressure
- Raoult's law
- Relative volatility
- Vapor–liquid equilibrium
- Volatile organic compound
References
- ^ Gases and Vapor (University of Kentucky website)
- ^ Definition of Terms (University of Victoria website)
- ^ James G. Speight (2006). The Chemistry and Technology of Petroleum (4th Edition ed.). CRC Press. ISBN 978-0-8493-9067-8.
- ^ Kister, Henry Z. (1992-02-01). Distillation Design (1st Edition ed.). McGraw-hill. ISBN 978-0-07-034909-4.
- ^ Perry, R.H. and Green, D.W. (Editors); Don W. Green; James O. Maloney (1997). Perry's Chemical Engineers' Handbook (7th Edition ed.). McGraw-Hill. ISBN 978-0-07-049841-9.
External links
- Volatility from ilpi.com
- Definition of volatile from Wiktionary
States of matter
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State |
- Solid
- Liquid
- Gas / Vapor
- Plasma
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|
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Low energy |
- Bose–Einstein condensate
- Fermionic condensate
- Degenerate matter
- Quantum Hall
- Rydberg matter
- Strange matter
- Superfluid
- Supersolid
- Photonic matter
|
|
High energy |
- QCD matter
- Lattice QCD
- Quark–gluon plasma
- Supercritical fluid
|
|
Other states |
- Colloid
- Glass
- Liquid crystal
- Quantum spin liquid
- Magnetically ordered
- Antiferromagnet
- Ferrimagnet
- Ferromagnet
- String-net liquid
- Superglass
|
|
Transitions |
- Boiling
- Boiling point
- Condensation
- Critical line
- Critical point
- Crystallization
- Deposition
- Evaporation
- Flash evaporation
- Freezing
- Chemical ionization
- Ionization
- Lambda point
- Melting
- Melting point
- Recombination
- Regelation
- Saturated fluid
- Sublimation
- Supercooling
- Triple point
- Vaporization
- Vitrification
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|
Quantities |
- Enthalpy of fusion
- Enthalpy of sublimation
- Enthalpy of vaporization
- Latent heat
- Latent internal energy
- Trouton's ratio
- Volatility
|
|
Concepts |
- Binodal
- Compressed fluid
- Cooling curve
- Equation of state
- Leidenfrost effect
- macroscopic quantum phenomena
- Mpemba effect
- Order and disorder (physics)
- Spinodal
- Superconductivity
- Superheated vapor
- Superheating
- Thermo-dielectric effect
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Lists |
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English Journal
- Influence of chlorine, sulfur and phosphorus on the volatilization behavior of heavy metals during sewage sludge thermal treatment.
- Luan J, Li R, Zhang Z, Li Y, Zhao Y.SourceLiaoning Key Laboratory of Clean Energy, School of Energy & Environmental Engineering, Shenyang Aerospace University, Shenyang, China.
- Waste management & research : the journal of the International Solid Wastes and Public Cleansing Association, ISWA.Waste Manag Res.2013 Jul 5. [Epub ahead of print]
- Chlorine, sulfur and phosphorus were selected as element donators to investigate their effect on the volatilization behavior of heavy metals in sludge sewage incineration. Principal component analysis indicated that the promotive effect on the volatilization of heavy metals was followed by chlorine,
- PMID 23831774
- Degradation of the persistent organic pollutant [(14)c]heptachlor in Japanese field soils.
- Hayashi O, Kameshiro M, Satoh K.SourceChemistry Division, The Institute of Environmental Toxicology.
- Bioscience, biotechnology, and biochemistry.Biosci Biotechnol Biochem.2013 Jun 23;77(6):1240-4. Epub 2013 Jun 7.
- The fate of [(14)C]heptachlor in Saitama soil and the degradation of [(14)C]heptachlor in four Japanese field soils over 112 d after application were investigated. Heptachlor was degraded mainly to cis-heptachlor epoxide by a biotic process and to 1-hydroxychlordene by an abiotic process in the fiel
- PMID 23748788
- Isolation and characterization of bacteria from mercury contaminated sites in Rio Grande do Sul, Brazil, and assessment of methylmercury removal capability of a Pseudomonas putida V1 strain.
- Cabral L, Giovanella P, Gianello C, Bento FM, Andreazza R, Camargo FA.SourceDepartment of Soil Science, Federal University of Rio Grande do Sul, UFRGS, Avenida Bento Gonçalves, 7712, Porto Alegre, RS 91540-000, Brazil. lucelia.cabral@hotmail.com
- Biodegradation.Biodegradation.2013 Jun;24(3):319-31. doi: 10.1007/s10532-012-9588-z. Epub 2012 Sep 16.
- Methylmercury (MeHg) is one of the most dangerous heavy metal for living organisms that may be found in environment. Given the crescent industrialization of Brazil and considering that mercury is a residue of several industrial processes, there is an increasing need to encounter and develop remediat
- PMID 22983740
Japanese Journal
- Morphology Evolution and Phase Interactions of Fe-containing Si3N4 in Vacuum High-temperature Environment
- Investigation on Morphology Evolution and Phase Interactions of Fe-containing Si<sub>3</sub>N<sub>4</sub> in Vacuum High-temperature Environment
- Double Cold Trap Method to Determine the Concentrations of Volatile Organic Compounds in Human Expired Gas
Related Links
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