硝酸ペルオキシアセチル
Wikipedia preview
出典(authority):フリー百科事典『ウィキペディア(Wikipedia)』「2014/09/26 19:52:38」(JST)
[Wiki en表示]
|
This article needs additional citations for verification. Please help improve this article by adding citations to reliable sources. Unsourced material may be challenged and removed. (December 2010) |
Peroxyacetyl nitrate |
|
|
|
Systematic name
ethanoic nitric peroxyanhydride
|
Other names
PAN
peroxyacetyl nitrate
α-oxoethylperoxylnitrate
|
Identifiers |
CAS number |
2278-22-0 Y |
PubChem |
16782 |
ChemSpider |
15907 |
EC number |
218-905-6 |
Jmol-3D images |
Image 1 |
|
-
InChI=1S/C2H3NO5/c1-2(4)7-8-3(5)6/h1H3
Key: VGQXTTSVLMQFHM-UHFFFAOYSA-N
InChI=1/C2H3NO5/c1-2(4)7-8-3(5)6/h1H3
Key: VGQXTTSVLMQFHM-UHFFFAOYAL
|
Properties |
Molecular formula |
C2H3NO5 |
Molar mass |
121.05 g mol−1 |
Solubility in water |
1.46 × 10 5 mg l−1 at 298 K |
log P |
−0.19 |
Vapor pressure |
29.2 mmHg at 298 K |
kH |
0.000278 m³ atm mol−1 at 298 K |
Atmospheric OH rate constant |
10−13 cm³ molecule−1 s−1 at 298 K |
Except where noted otherwise, data are given for materials in their standard state (at 25 °C (77 °F), 100 kPa) |
Y (verify) (what is: Y/N?) |
Infobox references |
|
|
Peroxyacetyl nitrate is a peroxyacyl nitrate. It is a secondary pollutant present in photochemical smog. It is thermally unstable and decomposes into peroxyethanoyl radicals and nitrogen dioxide gas. It is a lachrymatory substance.
Peroxyacetyl nitrate, or PAN, is an oxidant more stable than ozone. Hence, it is better capable of long-range transport than ozone. It serves as a carrier for oxides of nitrogen (NOx) into rural regions and causes ozone formation in the global troposphere.
The formation of PAN on a secondary scale becomes an issue when ethanol is used as an automotive fuel. Acetaldehyde emissions increase, which subsequently react in the atmosphere to form smog. Whereas ethanol policies solve domestic oil supply problems, they drastically exacerbate air quality conditions.[citation needed]
External links
- NIST WebBook page for peroxyacetyl nitrate
English Journal
- Athletic performance and urban air pollution.
- Shephard RJ.AbstractAir pollution may affect athletic performance. In Los Angeles, contaminants include carbon monoxide, ozone, peroxyacetylnitrate (PAN) and nitrogen oxides, whereas in older European cities, such as Sarajevo, "reducing smog" of sulfur dioxide is the main hazard. The carbon monoxide and ozone levels expected in Los Angeles this summer could affect the athletes' performance in endurance events at the Olympic Games. Carbon monoxide may also impair psychomotor abilities, and PAN causes visual disturbances. The only likely physiologic consequence from reducing smog is an increase in the workload of the respiratory system and thus a decrease in endurance performance. While carbon monoxide has been blamed for myocardial infarctions, nitrogen oxides for pulmonary edema and sulfur dioxide for deaths due to respiratory failure, the only illnesses that are likely to be more frequent than usual among young athletes exposed to high levels of these pollutants are upper respiratory tract infections. Therapeutic tactics include the avoidance of pollution, the administration of oxygen, vitamin C and vitamin E, and general reassurance.
- Canadian Medical Association journal.Can Med Assoc J.1984 Jul 15;131(2):105-9.
- Air pollution may affect athletic performance. In Los Angeles, contaminants include carbon monoxide, ozone, peroxyacetylnitrate (PAN) and nitrogen oxides, whereas in older European cities, such as Sarajevo, "reducing smog" of sulfur dioxide is the main hazard. The carbon monoxide and ozone levels ex
- PMID 6744156
Related Links
- Peroxyacetyl nitrate is a peroxyacyl nitrate. It is a secondary pollutant present in photochemical smog. It is thermally unstable and decomposes into peroxyethanoyl radical and nitrogen dioxide gas. It is a lachrymatory substance. ...
Related Pictures
★リンクテーブル★
[★]
- 英
- photochemical oxidant, Ox
- 関
- オキシダント、光化学スモッグ
定義
- 光化学反応によって生成するオキシダント(酸化性物質)の総称
光化学オキシダントの生成
光化学オキシダント生成に影響を与える要素
- 一次汚染物質の濃度
- 紫外線の強さ ← オゾン層の破壊により地表に到達する紫外線量が増える
光化学オキシダントの生体への影響
参考
- http://ja.wikipedia.org/wiki/%E5%85%89%E5%8C%96%E5%AD%A6%E3%82%AA%E3%82%AD%E3%82%B7%E3%83%80%E3%83%B3%E3%83%88
[★]
[★]
- 英
- peroxyacetylnitrate PAN
- 関
- 光化学スモッグ、二次汚染物質
参考
[★]
- 関
- 光化学オキシダント