WordNet
- street name for lysergic acid diethylamide (同)back breaker, battery-acid, dose, dot, Elvis, loony toons, Lucy in the sky with diamonds, pane, superman, window pane, Zen
- any of various water-soluble compounds having a sour taste and capable of turning litmus red and reacting with a base to form a salt
- having the characteristics of an acid; "an acid reaction"
PrepTutorEJDIC
- 酸性の / 酸味のある,すっぱい(sour) / (言葉・態度などが)厳しい,しんらつな / 酸 / すっぱいもの / 《俗》=LSD
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出典(authority):フリー百科事典『ウィキペディア(Wikipedia)』「2015/08/10 17:14:33」(JST)
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Myristic acid[1]
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Names |
IUPAC name
Tetradecanoic acid
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Other names
C14:0 (Lipid numbers)
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Identifiers |
CAS Registry Number
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544-63-8 Y |
ChEBI |
CHEBI:28875 N |
ChEMBL |
ChEMBL111077 N |
ChemSpider |
10539 N |
EC number |
208-875-2 |
InChI
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InChI=1S/C14H28O2/c1-2-3-4-5-6-7-8-9-10-11-12-13-14(15)16/h2-13H2,1H3,(H,15,16) N
Key: TUNFSRHWOTWDNC-UHFFFAOYSA-N N
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InChI=1/C14H28O2/c1-2-3-4-5-6-7-8-9-10-11-12-13-14(15)16/h2-13H2,1H3,(H,15,16)
Key: TUNFSRHWOTWDNC-UHFFFAOYAZ
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IUPHAR/BPS
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2806 |
Jmol-3D images |
Image |
PubChem |
11005 |
RTECS number |
QH4375000 |
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UNII |
0I3V7S25AW N |
Properties |
Chemical formula
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C14H28O2 |
Molar mass |
228.38 g·mol−1 |
Density |
1.03 g/cm3 (−3 °C)[2]
0.99 g/cm3 (24 °C)[3]
0.8622 g/cm3 (54 °C)[4] |
Melting point |
54.4 °C (129.9 °F; 327.5 K) [9] |
Boiling point |
326.2 °C (619.2 °F; 599.3 K) at 760 mmHg
250 °C (482 °F; 523 K)
at 100 mmHg[4]
218.3 °C (424.9 °F; 491.4 K)
at 32 mmHg[3] |
Solubility in water
|
13 mg/L (0 °C)
20 mg/L (20 °C)
24 mg/L (30 °C)
33 mg/L (60 °C)[5] |
Solubility |
Soluble in alcohol, acetates, C6H6, haloalkanes, phenyls, nitros[5] |
Solubility in acetone |
2.75 g/100 g (0 °C)
15.9 g/100 g (20 °C)
42.5 g/100 g (30 °C)
149 g/100 g (40 °C)[5] |
Solubility in benzene |
6.95 g/100 g (10 °C)
29.2 g/100 g (20 °C)
87.4 g/100 g (30 °C)
1.29 kg/100 g (50 °C)[5] |
Solubility in methanol |
2.8 g/100 g (0 °C)
17.3 g/100 g (20 °C)
75 g/100 g (30 °C)
2.67 kg/100 g (50 °C)[5] |
Solubility in ethyl acetate |
3.4 g/100 g (0 °C)
15.3 g/100 g (20 °C)
44.7 g/100 g (30 °C)
1.35 kg/100 g (40 °C)[5] |
Solubility in toluene |
0.6 g/100 g (−10 °C)
3.2 g/100 g (0 °C)
30.4 g/100 g (20 °C)
1.35 kg/100 g (50 °C)[5] |
log P |
6.1[4] |
Vapor pressure |
0.01 kPa (118 °C)
0.27 kPa (160 °C)[6]
1 kPa (186 °C)[4] |
Thermal conductivity |
0.159 W/m·K (70 °C)
0.151 W/m·K (100 °C)
0.138 W/m·K (160 °C)[7] |
Refractive index (nD)
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1.4723 (70 °C)[4] |
Viscosity |
7.2161 cP (60 °C)
3.2173 cP (100 °C)
0.8525 cP (200 °C)
0.3164 cP (300 °C)[8] |
Structure |
Crystal structure
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Monoclinic (−3 °C)[2] |
Space group
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P21/c[2] |
Lattice constant
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a = 31.559 Å, b = 4.9652 Å, c = 9.426 Å[2]
α = 90°, β = 94.432°, γ = 90°
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Thermochemistry |
Specific
heat capacity (C)
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432.01 J/mol·K[4][6] |
Std enthalpy of
formation (ΔfHo298)
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−833.5 kJ/mol[4][6] |
Std enthalpy of
combustion (ΔcHo298)
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8675.9 kJ/mol[6] |
Hazards |
GHS pictograms |
[10] |
GHS signal word |
Warning |
GHS hazard statements
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H315[10] |
EU classification |
Xi |
R-phrases |
R36/37/38 |
NFPA 704 |
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Flash point |
> 110 °C (230 °F; 383 K) [11] |
Lethal dose or concentration (LD, LC): |
LD50 (Median dose)
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>10 g/kg (rats, oral)[11] |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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N verify (what is: Y/N?) |
Infobox references |
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Myristic acid, also called tetradecanoic acid, is a common saturated fatty acid with the molecular formula CH3(CH2)12COOH. A myristate is a salt or ester of myristic acid. Myristic acid is named after the nutmeg Myristica fragrans.
Contents
- 1 Occurrence
- 2 Uses
- 3 References
- 4 External links
Occurrence
Myristica fragrans fruit contains myristic acid
Nutmeg butter has 75% trimyristin, the triglyceride of myristic acid. Besides nutmeg, myristic acid is also found in palm kernel oil, coconut oil, butter fat and is a minor component of many other animal fats.[9] It is also found in spermaceti, the crystallized fraction of oil from the sperm whale.
Uses
Myristic acid is commonly added co-translationally to the penultimate, nitrogen-terminus, glycine in receptor-associated kinases to confer the membrane localisation of the enzyme.[citation needed] The myristic acid has a sufficiently high hydrophobicity to become incorporated into the fatty acyl core of the phospholipid bilayer of the plasma membrane of the eukaryotic cell. In this way, myristic acid acts as a lipid anchor in biomembranes.[citation needed]
The ester isopropyl myristate is used in cosmetic and topical medicinal preparations where good absorption through the skin is desired[citation needed].
Reduction of myristic acid yields myristyl aldehyde and myristyl alcohol.
References
- ^ Merck Index, 11th Edition, 6246
- ^ a b c d Bond, Andrew D. (2003). "On the crystal structures and melting point alternation of the n-alkyl carboxylic acids" (PDF). http://www.rsc.org. Royal Society of Chemistry. Retrieved 2014-06-17.
- ^ a b G., Chuah T.; D., Rozanna; A., Salmiah; Y., Thomas Choong S.; M., Sa'ari (2006). "Fatty Acids used as Phase Change Materials (PCMs) for Thermal Energy Storage in Building Material Applications" (PDF). University Putra Malaysia. Retrieved 2014-06-17.
- ^ a b c d e f g Lide, David R., ed. (2009). CRC Handbook of Chemistry and Physics (90th ed.). Boca Raton, Florida: CRC Press. ISBN 978-1-4200-9084-0.
- ^ a b c d e f g Seidell, Atherton; Linke, William F. (1940). Solubilities of Inorganic and Organic Compounds (3rd ed.). New York: D. Van Nostrand Company. pp. 762–763.
- ^ a b c d Tetradecanoic acid in Linstrom, P.J.; Mallard, W.G. (eds.) NIST Chemistry WebBook, NIST Standard Reference Database Number 69. National Institute of Standards and Technology, Gaithersburg MD. http://webbook.nist.gov (retrieved 2014-06-17)
- ^ Vargaftik, Natan B. et al. (1993). Handbook of Thermal Conductivity of Liquids and Gases (illustrated ed.). CRC Press. p. 305. ISBN 0-8493-9345-0.
- ^ Yaws, Carl L. (2009). Transport Properties of Chemicals and Hydrocarbons. New York: William Andrew Inc. p. 177. ISBN 978-0-8155-2039-9.
- ^ a b "Lexicon of lipid nutrition (IUPAC Technical Report)". Pure and Applied Chemistry 73 (4): 685–744. 2001. doi:10.1351/pac200173040685.
- ^ a b Sigma-Aldrich Co., Myristic acid. Retrieved on 2014-06-17.
- ^ a b c "MYRISTIC ACID". https://www.chemicalland21.com. AroKor Holdings Inc. Retrieved 2014-06-17.
External links
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Wikimedia Commons has media related to Myristic acid. |
Lipids: fatty acids
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Saturated |
- Acetic (C2)
- Propionic (C3)
- Butyric (C4)
- Valeric (C5)
- Caproic (C6)
- Enanthic (C7)
- Caprylic (C8)
- Pelargonic (C9)
- Capric (C10)
- Undecylic (C11)
- Lauric (C12)
- Tridecylic (C13)
- Myristic (C14)
- Pentadecanoic (C15)
- Palmitic (C16)
- Margaric (C17)
- Stearic (C18)
- Nonadecylic (C19)
- Arachidic (C20)
- Heneicosylic (C21)
- Behenic (C22)
- Tricosylic (C23)
- Lignoceric (C24)
- Pentacosylic (C25)
- Cerotic (C26)
- Heptacosylic (C27)
- Montanic (C28)
- Nonacosylic (C29)
- Melissic (C30)
- Hentriacontylic (C31)
- Lacceroic (C32)
- Psyllic (C33)
- Geddic (C34)
- Ceroplastic (C35)
- Hexatriacontylic (C36)
- Heptatriacontanoic (C37)
- Octatriacontanoic (C38)
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ω−3 Unsaturated |
- α-Linolenic (18:3)
- Stearidonic (18:4)
- Eicosapentaenoic (20:5)
- Docosahexaenoic (22:6)
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ω−6 Unsaturated |
- Linoleic (18:2)
- γ-Linolenic (18:3)
- Dihomo-γ-linolenic (20:3)
- Arachidonic (20:4)
- Adrenic (22:4)
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ω-7 Unsaturated |
- Palmitoleic (16:1)
- Vaccenic (18:1)
- Paullinic (20:1)
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ω−9 Unsaturated |
- Oleic (18:1)
- Elaidic (trans-18:1)
- Gondoic (20:1)
- Erucic (22:1)
- Nervonic (24:1)
- Mead (20:3)
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Index of biochemical families
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Carbohydrates |
- Alcohols
- Glycoproteins
- Glycosides
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Lipids |
- Eicosanoids
- Fatty acids
- Glycerides
- Phospholipids
- Sphingolipids
- Steroids
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Nucleic acids |
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Proteins |
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Other |
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UpToDate Contents
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English Journal
- Structural elucidation of olive pomace fed sea bass (Dicentrarchus labrax) polar lipids with cardioprotective activities.
- Nasopoulou C, Smith T, Detopoulou M, Tsikrika C, Papaharisis L, Barkas D, Zabetakis I.SourceLaboratory of Food Chemistry, Faculty of Chemistry, National and Kapodistrian University of Athens, Athens 15771, Greece.
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- The purpose of this study was to structurally characterise the polar lipids of sea bass (Dicentrarchus labrax), fed with an experimental diet containing olive pomace (OP), that exhibit cardioprotective activities. OP has been added to conventional fish oil (FO) feed at 4% and this was the OP diet, h
- PMID 24128590
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- Meng X, Xu G, Zhou QL, Wu JP, Yang LR.SourceInstitute of Biological Engineering, Department of Chemical and Biological Engineering, Zhejiang University, 310027 Hangzhou, China.
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Japanese Journal
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Related Links
- Tetradecanoic acid | C14H28O2 | CID 11005 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more. NIH ...
- Myristic Acid, Reagent MY110 - Spectrum Chemical 544-63-8 MY110 | 544-63-8 | CH3(CH2)12COOH MYRISTIC ACID, REAGENT, also known as tetradecanoic acid, acts as a lipid anchor in biomembranes. The Reagent grade ...
Related Pictures
★リンクテーブル★
[★]
ミリスチン酸、ミリスチン酸エステル
- 関
- myristic acid