- 関
- isophthalate
WordNet
- street name for lysergic acid diethylamide (同)back breaker, battery-acid, dose, dot, Elvis, loony toons, Lucy in the sky with diamonds, pane, superman, window pane, Zen
- any of various water-soluble compounds having a sour taste and capable of turning litmus red and reacting with a base to form a salt
- having the characteristics of an acid; "an acid reaction"
PrepTutorEJDIC
- 酸性の / 酸味のある,すっぱい(sour) / (言葉・態度などが)厳しい,しんらつな / 酸 / すっぱいもの / 《俗》=LSD
Wikipedia preview
出典(authority):フリー百科事典『ウィキペディア(Wikipedia)』「2015/05/13 19:23:36」(JST)
[Wiki en表示]
Isophthalic acid
|
|
Names |
Other names
Benzene-1,3-dicarboxylic acid
meta-Phthalic acid
|
Identifiers |
CAS Registry Number
|
121-91-5 Y |
ChEBI |
CHEBI:30802 Y |
ChemSpider |
8182 Y |
InChI
-
InChI=1S/C8H6O4/c9-7(10)5-2-1-3-6(4-5)8(11)12/h1-4H,(H,9,10)(H,11,12) Y
Key: QQVIHTHCMHWDBS-UHFFFAOYSA-N Y
-
InChI=1/C8H6O4/c9-7(10)5-2-1-3-6(4-5)8(11)12/h1-4H,(H,9,10)(H,11,12)
Key: QQVIHTHCMHWDBS-UHFFFAOYAY
|
Jmol-3D images |
Image |
PubChem |
8496 |
|
Properties |
Chemical formula
|
C6H4(COOH)2 |
Molar mass |
166.14 g/mol |
Appearance |
White crystalline solid |
Density |
1.526 g/cm3, Solid |
Solubility in water
|
Insoluble in water |
Acidity (pKa) |
3.46, 4.46[1] |
Hazards |
EU classification |
not listed |
Related compounds |
Related carboxylic acids
|
Benzoic acid
Phthalic acid (ortho)
Terephthalic acid (para)
Trimesic acid (benzene-1,3,5-tricarboxyllic acid) |
Except where noted otherwise, data is given for materials in their standard state (at 25 °C (77 °F), 100 kPa)
|
Y verify (what is: Y/N?) |
Infobox references |
|
|
Isophthalic acid is an organic compound with the formula C6H4(CO2H)2. This colourless solid is an isomer of phthalic acid and terephthalic acid. These aromatic dicarboxylic acids are used as precursors (in form of acyl chlorides) to commercially important polymers, e.g. the fire-resistant material Nomex. Mixed with terephthalic acid, isophthalic acid is used in the production of resins for drink bottles. The high-performance polymer polybenzimidazole is produced from isophthalic acid.[2]
Preparation
Isophthalic acid is produced on the billion kilogram per year scale by oxidizing meta-xylene using oxygen.[2] The process employs a cobalt-manganese catalyst. In the laboratory, chromic acid can be used as the oxidant. It also arises by fusing potassium meta-sulphobenzoate, or meta-brombenzoate with potassium formate (terephthalic acid is also formed in the last case).
The barium salt (as its hexahydrate) is very soluble (a distinction between phthalic and terephthalic acids). Uvitic acid, 5-methylisophthalic acid, is obtained by oxidizing mesitylene or by condensing pyroracemic acid with baryta water.
References
- ^ Brown, H.C., et al., in Baude, E.A. and Nachod, F.C., Determination of Organic Structures by Physical Methods, Academic Press, New York, 1955.
- ^ a b Richard J. Sheehan "Terephthalic Acid, Dimethyl Terephthalate, and Isophthalic Acid" in Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim, 2005.doi:10.1002/14356007.a26_193
External links
- International Chemical Safety Card 0500
UpToDate Contents
全文を閲覧するには購読必要です。 To read the full text you will need to subscribe.
English Journal
- From Zn(II)-Carboxylate to Double-Walled Zn(II)-Carboxylato Phosphate MOF: Change in the Framework Topology, Capture and Conversion of CO2, and Catalysis of Strecker Reaction.
- Gupta M1, De D1, Tomar K1, Bharadwaj PK1.
- Inorganic chemistry.Inorg Chem.2017 Dec 4;56(23):14605-14611. doi: 10.1021/acs.inorgchem.7b02443. Epub 2017 Nov 13.
- PMID 29131604
- Diverse Structures based on Heptanuclear Co Cluster from 0D to 3D Metal Organic Framework: Magnetism and Application in Batteries.
- Qin B1, Huang K1, Zhang Y1, Zhou L1, Cui Z1, Zhang K1, Zhang X1, Zhang J2.
- Chemistry (Weinheim an der Bergstrasse, Germany).Chemistry.2017 Nov 26. doi: 10.1002/chem.201705023. [Epub ahead of print]
- PMID 29178323
- A Flexible Diacetylene-Based Mixed-Linker MOF with Two Low-Temperature Phase Transitions and Colossal Positive and Negative Thermal Expansions.
- Dutremez SG1, Duarte Rodrigues A, Fahsi K, Dumail X, Masquelez N, van der Lee A, Mallet-Ladeira S, Sibille R, Filhol JS.
- Chemistry (Weinheim an der Bergstrasse, Germany).Chemistry.2017 Nov 8. doi: 10.1002/chem.201703711. [Epub ahead of print]
- PMID 29115702
Japanese Journal
- Synthesis of Polysubstituted Benzenes from 2-Pyrone-4,6-dicarboxylic Acid
- Okura Keisho,Tamura Ryuichi,Shigehara Kiyotaka,Masai Eiji,Nakamura Masaya,Otsuka Yuichiro,Katayama Yoshihiro,Nakao Yoshiaki
- Chemistry Letters 43(8), 1349-1351, 2014
- … Cycloaddition reactions of a lignin-derived pyrone derivative, 2-pyrone-4,6-dicarboxylic acid, and its dimethyl ester with alkenyl acetates and alkynes under thermal conditions proceed with decarboxylation to give isophthalic acids and various mono- and disubstituted isophthalates. …
- NAID 130004427141
- A leukotriene C₄ synthase inhibitor with the backbone of 5-(5-methylene-4-oxo-4,5-dihydrothiazol-2-ylamino) isophthalic acid
- Ago Hideo,Okimoto Noriaki,Kanaoka Yoshihide [他]
- The journal of biochemistry 153(5), 421-429, 2013-05
- NAID 40019646791
- Formation of organically modified octacalcium phosphate in solutions containing various amounts of benzenedicarboxylic acids
- YOKOI Taishi,KAMITAKAHARA Masanobu,KAWASHITA Masakazu,OHTSUKI Chikara
- Journal of the Ceramic Society of Japan 121(1410), 219-225, 2013
- … We investigated formation of OCP with incorporated dicarboxylate ions, namely octacalcium phosphate carboxylate (OCPC), under synthetic conditions with various concentrations of benzenedicarboxylic acids (BDCAs) such as 1,2-benzenedicarboxylic acid (1,2BDCA, phthalic acid), 1,3-benzenedicarboxylic acid (1,3BDCA, isophthalic acid), and 1,4-benzenedicarboxylic acid (1,4BDCA, terephthalic acid). …
- NAID 130004950812
Related Links
- [Isophthalic Acid] [121-91-5] | 価格や在庫、物性値などの詳細情報ページです。 ... ・川口の在庫は即日,つくばの在庫は2〜3日以内の出荷となります。・詳細につきましては,お手数ですが営業部までお問い合わせください。
- Isophthalic acid (IPA) is a non-toxic organic compound with the formula C 6 H 4 (CO 2 H) 2. This colorless solid is an isomer of phthalic acid and terephthalic acid. These aromatic dicarboxylic acids are used as precursors (in the form ...
★リンクテーブル★
[★]
- 関
- isophthalic acid
[★]
- 英
- isophthalic acid、isophthalate
- 関
- イソフタル酸塩