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| Plant oils |
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Olive oil
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A vegetable oil is a triglyceride extracted from a plant. Such oils have been part of human culture for millennia.[1] The term "vegetable oil" can be narrowly defined as referring only to plant oils that are liquid at room temperature,[2] or broadly defined without regard to a substance's state of matter at a given temperature.[3] For this reason, vegetable oils that are solid at room temperature are sometimes called vegetable fats. Vegetable oils are composed of triglycerides, as contrasted with waxes which lack glycerin in their structure. Although many plant parts may yield oil,[4] in commercial practice, oil is extracted primarily from seeds.
On food packaging, the term "vegetable oil" is often used in ingredients lists instead of specifying the exact plant being used.
Oils extracted from plants have been used since ancient times and in many cultures. As an example, in a 4,000-year-old kitchen unearthed in Indiana's Charlestown State Park, archaeologist Bob McCullough of Indiana University-Purdue University Fort Wayne found evidence that natives used large slabs of rock to crush hickory nuts, then boiled them in water to extract the oil.[5]
Many vegetable oils are consumed directly, or indirectly as ingredients in food – a role that they share with some animal fats, including butter and ghee. The oils serve a number of purposes in this role:
Secondly, oils can be heated and used to cook other foods. Oils suitable for this objective must have a high flash point. Such oils include the major cooking oils – soybean, canola, sunflower, safflower, peanut, cottonseed, etc. Tropical oils, such as coconut, palm, and rice bran oils, are particularly valued in Asian cultures for high-temperature cooking, because of their unusually high flash points.
Unsaturated vegetable oils can be transformed through partial or complete "hydrogenation" into oils of higher melting point. The hydrogenation process involves "sparging" the oil at high temperature and pressure with hydrogen in the presence of a catalyst, typically a powdered nickel compound. As each carbon–carbon double-bond is chemically reduced to a single bond, two hydrogen atoms each form single bonds with the two carbon atoms. The elimination of double bonds by adding hydrogen atoms is called saturation; as the degree of saturation increases, the oil progresses toward being fully hydrogenated. An oil may be hydrogenated to increase resistance to rancidity (oxidation) or to change its physical characteristics. As the degree of saturation increases, the oil's viscosity and melting point increase.
The use of hydrogenated oils in foods has never been completely satisfactory. Because the center arm of the triglyceride is shielded somewhat by the end fatty acids, most of the hydrogenation occurs on the end fatty acids, thus making the resulting fat more brittle[citation needed]. A margarine made from naturally more saturated oils will be more plastic (more "spreadable") than a margarine made from hydrogenated soy oil[citation needed]. While full hydrogenation produces largely saturated fatty acids, partial hydrogenation results in the transformation of unsaturated cis fatty acids to trans fatty acids in the oil mixture due to the heat used in hydrogenation. Partially hydrogenated oils and their trans fats have been linked to an increased risk of mortality from coronary heart disease (CHD).,[6] among other increased health risks.
In the US, the Standard of Identity for a product labeled as "vegetable oil margarine" specifies only canola, safflower, sunflower, corn, soybean, or peanut oil may be used.[7] Products not labeled "vegetable oil margarine" do not have that restriction.
Vegetable oils are used as an ingredient or component in many manufactured products.
Many vegetable oils are used to make soaps, skin products, candles, perfumes and other personal care and cosmetic products. Some oils are particularly suitable as drying oils, and are used in making paints and other wood treatment products. Dammar oil (a mixture of linseed oil and dammar resin), for example, is used almost exclusively in treating the hulls of wooden boats. Vegetable oils are increasingly being used in the electrical industry as insulators as vegetable oils are not toxic to the environment, biodegradable if spilled and have high flash and fire points. However, vegetable oils are less stable chemically, so they are generally used in systems where they are not exposed to oxygen, and they are more expensive than crude oil distillate. Synthetic tetraesters, which are similar to vegetable oils but with four fatty acid chains compared to the normal three found in a natural ester, are manufactured by Fischer esterification. Tetraesters generally have high stability to oxidation and have found use as engine lubricants. Vegetable oil is being used to produce biodegradable hydraulic fluid[8] and lubricant.[9]
One limiting factor in industrial uses of vegetable oils is that all such oils eventually chemically decompose, turning rancid. Oils that are more stable, such as ben oil or mineral oil, are preferred for some industrial uses.
Vegetable-based oils, like castor oil, have been used as medicine and as lubricants for a long time. Castor oil has numerous industrial uses, primarily due to the presence of hydroxyl groups on the fatty acid chains. Castor oil, and other vegetable oils which have been chemically modified to contain hydroxyl groups, are becoming increasingly important in the production of polyurethane plastic for many applications. These modified vegetable oils are known as natural oil polyols.
Vegetable oil is used in production of some pet foods. AAFCO defines vegetable oil, in this context, as the product of vegetable origin obtained by extracting the oil from seeds or fruits which are processed for edible purposes. In some poorer-grade pet foods, the oil is listed only as "vegetable oil", without specifying the particular oil.[10]
Vegetable oils are also used to make biodiesel, which can be used like conventional diesel. Some vegetable oil blends are used in unmodified vehicles but straight vegetable oil, also known as pure plant oil, needs specially prepared vehicles which have a method of heating the oil to reduce its viscosity. The use of vegetable oils as alternative energy is growing and the availability of biodiesel around the world is increasing.
The NNFCC estimate that the total net greenhouse gas savings when using vegetable oils in place of fossil fuel-based alternatives for fuel production, range from 18 to 100%.[11]
The production process of vegetable oil involves the removal of oil from plant components, typically seeds. This can be done via mechanical extraction using an oil mill or chemical extraction using a solvent. The extracted oil can then be purified and, if required, refined or chemically altered.
Oils can also be removed via mechanical extraction, termed "crushing" or "pressing." This method is typically used to produce the more traditional oils (e.g., olive, coconut etc.), and it is preferred by most "health-food" customers in the United States and in Europe.[citation needed] There are several different types of mechanical extraction.[12] Expeller-pressing extraction is common, though the screw press, ram press, and Ghani (powered mortar and pestle) are also used. Oilseed presses are commonly used in developing countries, among people for whom other extraction methods would be prohibitively expensive; the Ghani is primarily used in India.[13] The amount of oil extracted using these methods varies widely, as shown in the following table for extracting mowrah butter in India:[14]
| Method | Percentage extracted |
|---|---|
| Ghani[15] | 20–30% |
| Expellers | 34–37% |
| Solvent | 40–43% |
The processing vegetable oil in commercial applications is commonly done by chemical extraction, using solvent extracts, which produces higher yields and is quicker and less expensive. The most common solvent is petroleum-derived hexane. This technique is used for most of the "newer" industrial oils such as soybean and corn oils.
Supercritical carbon dioxide can be used as a non-toxic alternative to other solvents.[16]
Oils may be partially hydrogenated to produce various ingredient oils. Lightly hydrogenated oils have very similar physical characteristics to regular soy oil, but are more resistant to becoming rancid. Margarine oils need to be mostly solid at 32 °C (90 °F) so that the margarine does not melt in warm rooms, yet it needs to be completely liquid at 37 °C (98 °F), so that it doesn't leave a "lardy" taste in the mouth.
Hardening vegetable oil is done by raising a blend of vegetable oil and a catalyst in near-vacuum to very high temperatures, and introducing hydrogen. This causes the carbon atoms of the oil to break double-bonds with other carbons, each carbon forming a new single-bond with a hydrogen atom. Adding these hydrogen atoms to the oil makes it more solid, raises the smoke point, and makes the oil more stable.
Hydrogenated vegetable oils differ in two major ways from other oils which are equally saturated. During hydrogenation, it is easier for hydrogen to come into contact with the fatty acids on the end of the triglyceride, and less easy for them to come into contact with the center fatty acid. This makes the resulting fat more brittle than a tropical oil; soy margarines are less "spreadable"[compared to?]. The other difference is that trans fatty acids (often called trans fat) are formed in the hydrogenation reactor, and may amount to as much as 40 percent by weight of a partially hydrogenated oil. Hydrogenated oils, especially partially hydrogenated oils with their higher amounts of trans fatty acids are increasingly thought to be unhealthy.
In the processing of edible oils, the oil is heated under vacuum to near the smoke point, and water is introduced at the bottom of the oil. The water immediately is converted to steam, which bubbles through the oil, carrying with it any chemicals which are water-soluble. The steam sparging removes impurities that can impart unwanted flavors and odors to the oil.
The following triglyceride vegetable oils account for almost all worldwide production, by volume. All are used as both cooking oils and as SVO or to make biodiesel. According to the USDA, the total world consumption of major vegetable oils in 2007/08 was:[17]
| Oil source | World consumption (million metric tons) |
Notes |
|---|---|---|
| Palm | 41.31 | The most widely produced tropical oil, also used to make biofuel |
| Soybean | 41.28 | Accounts for about half of worldwide edible oil production |
| Rapeseed | 18.24 | One of the most widely used cooking oils, canola is a variety (cultivar) of rapeseed |
| Sunflower seed | 9.91 | A common cooking oil, also used to make biodiesel |
| Peanut | 4.82 | Mild-flavored cooking oil |
| Cottonseed | 4.99 | A major food oil, often used in industrial food processing |
| Palm kernel | 4.85 | From the seed of the African palm tree |
| Coconut | 3.48 | Used in soaps and cooking |
| Olive | 2.84 | Used in cooking, cosmetics, soaps and as a fuel for traditional oil lamps |
Note that these figures include industrial and animal feed use. The majority of European rapeseed oil production is used to produce biodiesel, or used directly as fuel in diesel cars which may require modification to heat the oil to reduce its higher viscosity. The suitability of the fuel should come as little surprise, as Rudolf Diesel originally designed his engine to run on peanut oil.
Other significant triglyceride oils include:
| Vegetable oils | ||||||||
|---|---|---|---|---|---|---|---|---|
| Type | Processing Treatment |
Saturated fatty acids[19] |
Mono- unsaturated |
Polyunsaturated fatty acids | Oleic acid (ω-9) |
Smoke point | ||
| Total poly[19] | linolenic acid (ω-3) |
Linoleic acid (ω-6) |
||||||
| Canola (rapeseed) | 7.365 | 63.276 | 28.142 | 10 | 10 | 400 °F (204 °C)[20] | ||
| Coconut | 91.00 | 6.000 | 3.000 | 2 | 6 | 350 °F (177 °C)[20] | ||
| Corn[21] | 12.948 | 27.576 | 54.677 | 1 | 58 | 28 | 450 °F (232 °C) | |
| Cottonseed | 25.900 | 17.800 | 51.900 | 1 | 54 | 19 | 420 °F (216 °C)[21] | |
| Flaxseed/Linseed (European)[22] | 7.5 | 15.5 | 79 | 64 | 15 | 11 | 225 °F (107 °C) | |
| Olive | 14.00 | 72.00 | 14.00 | 1.5 | 15 | 380 °F (193 °C)[20] | ||
| Palm | 49.300 | 37.000 | 9.300 | 10 | 40 | 455 °F (235 °C) | ||
| Peanut | 16.900 | 46.200 | 32.000 | 32 | 48 | 437 °F (225 °C)[21] | ||
| Safflower (>70% linoleic) | 8.00 | 15.00 | 75.00 | 410 °F (210 °C)[20] | ||||
| Safflower (high oleic) | 7.541 | 75.221 | 12.820 | 410 °F (210 °C)[20] | ||||
| Soybean | 15.650 | 22.783 | 57.740 | 7 | 50 | 24 | 460 °F (238 °C)[21] | |
| Sunflower (<60% linoleic) | 10.100 | 45.400 | 40.100 | 0.200 | 39.800 | 45.300 | 440 °F (227 °C)[21] | |
| Sunflower (>70% oleic) | 9.859 | 83.689 | 3.798 | 440 °F (227 °C)[21] | ||||
| Cottonseed (hydrogenated)[19] | Hydrogenated | 93.600 | 1.529 | .587 | .287 | |||
| Palm (hydrogenated) | Hydrogenated | 47.500 | 40.600 | 7.500 | ||||
| Soybean (hydrogenated)[19] | Hydrogenated | 21.100 | 73.700 | .400 | .096 | |||
| Values as percent (%) by weight of total fat. | ||||||||
While olive oil and other pressed oils have been around for millennia, Procter & Gamble researchers were innovators when they started selling cottonseed oil as a creamed shortening, in 1911. Ginning mills were happy to have someone haul away the cotton seeds. Procter & Gamble researchers learned how to extract the oil, refine it, partially hydrogenate it (causing it to be solid at room temperature and thus mimic natural lard), and can it under nitrogen gas. Compared to the rendered lard Procter & Gamble was already selling to consumers, Crisco was cheaper, easier to stir into a recipe, and could be stored at room temperature for two years without turning rancid. (Procter & Gamble sold their fats and oils brands – Jif and Crisco – to The J.M. Smucker Co. in 2002.)
Soybeans were an exciting new crop from China in the 1930s. Soy was protein-rich, and the medium viscosity oil was high in polyunsaturates. Henry Ford established a soybean research laboratory, developed soybean plastics and a soy-based synthetic wool, and built a car "almost entirely" out of soybeans.[24] Roger Drackett had a successful new product with Windex, but he invested heavily in soybean research, seeing it as a smart investment.[25] By the 1950s and 1960s, soybean oil had become the most popular vegetable oil in the US.
In the mid-1970s, Canadian researchers developed a low-erucic-acid rapeseed cultivar. Because the word "rape" was not considered optimal for marketing, they coined the name "canola" (from "Canada Oil low acid"). The U.S. Food and Drug Administration approved use of the canola name in January 1985,[26] and U.S. farmers started planting large areas that spring. Canola oil is lower in saturated fats, and higher in monounsaturates and is a better source of omega-3 fats than other popular oils. Canola is very thin (unlike corn oil) and flavorless (unlike olive oil), so it largely succeeds by displacing soy oil, just as soy oil largely succeeded by displacing cottonseed oil.
A large quantity of used vegetable oil is produced and recycled, mainly from industrial deep fryers in potato processing plants, snack food factories and fast food restaurants.
Recycled oil has numerous uses, including use as a direct fuel, as well as in the production of biodiesel, soap, animal feed, pet food, detergent, and cosmetics. It's traded as the commodity, yellow grease.
Since 2002, an increasing number of European Union countries have prohibited the inclusion of recycled vegetable oil from catering in animal feed. Used cooking oils from food manufacturing, however, as well as fresh or unused cooking oil, continue to be used in animal feed.[27]
Hydrogenated oils have been shown to cause what is commonly termed the "double deadly effect", raising the level of LDLs and decreasing the level of HDLs in the blood, increasing the risk of blood clotting inside blood vessels.[28]
A high consumption of oxidized polyunsaturated fatty acids (PUFAs), which are found in most types of vegetable oil (e.g. soybean oil, corn oil – the most consumed in USA, sunflower oil, etc.) may increase the likelihood that postmenopausal women will develop breast cancer.[29] A similar effect was observed on prostate cancer[30] and skin cancer[31] in mice.
Vegetables oils high in polyunsaturated fatty acids cause inflammation of the cells and may lead to a digestive disease and eventually cancer. The main reason is that the polyunsaturated fatty acids in vegetable oils autooxidize during food processing when exposed to oxygen or UV radiation; resulting in the autoproduction of inflammatory peroxides and hydroperoxides from polyunsaturated fatty acids.[32][33]
There is increasing concern[by whom?] that the product labeling that includes "vegetable fat" or "vegetable oil" in its list of ingredients masks the identity of the fats or oils present. This has been made more pressing as concerns have been raised over the social and environmental impact of palm oil in particular, especially given the predominance of palm oil.[34]
In Canada, palm oil is one of five vegetable oils, along with palm kernel oil, coconut oil, peanut oil and cocoa butter, which must be specifically named in the list of ingredients for a food product.[35] Also, oils in Canadian food products which have been modified or hydrogenated must contain the word "modified" or "hydrogenated" when listed as an ingredient.[36] A mix of oils other than the aforementioned exceptions may simply be listed as "vegetable oil" in Canada; however, if the food product is a cooking oil, salad oil or table oil, the type of oil must be specified and listing "vegetable oil" as an ingredient is not acceptable.[35]
From 13 December 2014 all food products produced in the European Union will be legally required to indicate the specific vegetable oil used in their manufacture, following the introduction of the Food Information to Consumers Regulation [37]
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| リンク元 | 「plant oil」 |
| 関連記事 | 「vegetable」 |