WordNet

a tortuous and twisted shape or position; "they built a tree house in the tortuosities of its boughs"; "the acrobat performed incredible contortions" (同)tortuousness, torsion, contortion, crookedness
a sharp bend in a line produced when a line having a loop is pulled tight (同)twist, twirl
a difficulty or flaw in a plan or operation; "there are still a few kinks to iron out"
a person with unusual sexual tastes
an eccentric idea

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(糸・綱などの)もつれ,ねじれ / (首や背の筋肉の)痛み,こり / 《話》(機械・計画などの)欠陥,不備(flaw) / 《話》つむじ曲がり;むら気,気まぐれ / …‘を'よじる,もつれさす / よじれる,もつれる

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出典(authority):フリー百科事典『ウィキペディア（Wikipedia）』「2015/03/17 20:37:57」(JST)

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A tortuous river (meander of Nowitna River, Alaska)

Tortuosity is a property of curve being tortuous (twisted; having many turns). There have been several attempts to quantify this property. Tortuosity is commonly used to describe diffusion in porous media,^[1] such as soils and snow.^[2]

Tortuosity in 2-D

Subjective estimation (sometimes aided by optometric grading scales^[3]) is often used.

The simplest mathematical method to estimate tortuosity is the arc-chord ratio: the ratio of the length of the curve (L) to the distance between the ends of it (C):

Arc-chord ratio equals 1 for a straight line and is infinite for a circle.

Another method, proposed in 1999,^[4] is to estimate the tortuosity as integral of square (or module) of curvature. Dividing the result by length of curve or chord has also been tried.

In 2002 several Italian scientists^[5] proposed one more method. At first, the curve is divided into several (N) parts with constant sign of curvature (using hysteresis to decrease sensitivity to noise). Then the arc-chord ratio for each part is found and the tortuosity is estimated by:

In this case tortuosity of both straight line and circle is estimated to be 0.

In 1993^[6] Swiss mathematician Martin Mächler proposed an analogy: it’s relatively easy to drive a bicycle or a car in a trajectory with a constant curvature (an arc of a circle), but it’s much harder to drive where curvature changes. This would imply that roughness (or tortuosity) could be measured by relative change of curvature. In this case the proposed "local" measure was derivative of logarithm of curvature:

However, in this case tortuosity of a straight line is left undefined.

In 2005 it was proposed to measure tortuosity by an integral of square of derivative of curvature, divided by the length of a curve:^[7]

In this case tortuosity of both straight line and circle is estimated to be 0.

In most of these methods digital filters and approximation by splines can be used to decrease sensitivity to noise.

Tortuosity in 3-D

Tortuosity calculation from an x-ray tomography reconstruction of a porous sandstone (the pores are shown):^[8] the color represents the shortest distance within the pore space from the left limit of the image to any point in the pores. Comparing this distance to the straight-line distance shows that the tortuosity is about 1.5 for this sample.

Usually subjective estimation is used. However, several ways to adapt methods estimating tortuosity in 2-D have also been tried. The methods include arc-chord ratio, arc-chord ratio divided by number of inflection points and integral of square of curvature, divided by length of the curve (curvature is estimated assuming that small segments of curve are planar).^[9] Another method used for quantifying tortuosity in 3D has been applied in 3D reconstructions of solid oxide fuel cell cathodes where the Euclidean distance sums of the centroids of a pore were divided by the length of the pore.^[10]

Applications of tortuosity

Tortuosity of blood vessels (for example, retinal and cerebral blood vessels) is known to be used as a medical sign.

In mathematics, cubic splines minimize the functional, equivalent to integral of square of curvature (approximating the curvature as the second derivative).

In many engineering domains dealing with mass transfer in porous materials, such as hydrogeology or heterogeneous catalysis, the tortuosity refers to the ratio of the diffusivity in the free space to the diffusivity in the porous medium^[11] (analogous to arc-chord ratio of path). Strictly speaking, however, the effective diffusivity is proportional to the reciprocal of the square of the geometrical tortuosity^[12]

In acoustics and following initial works by Maurice Anthony Biot in 1956, the tortuosity is used to describe sound propagation in fluid-saturated porous media. In such media, when frequency of the sound wave is high enough, the effect of viscous drag force between the solid and the fluid can be ignored. In this case, velocity of sound propagation in the fluid in the pores is non-dispersive and compared with the value of the velocity of sound in the free fluid is reduced by a ratio equal to the square root of the tortuosity. This has been used for a number of applications including the study of materials for acoustic isolation, and for oil prospection using acoustics means.

In analytical chemistry applied to polymers and sometimes small molecules tortuosity is applied in Gel permeation chromatography (GPC) also known as Size Exclusion Chromatography (SEC). As with any chromatography it is used to separate mixtures. In the case of GPC the separation is based on molecular size and it works by the use of stationary media with appropriately dimensioned pores. The separation occurs because larger molecules take a shorter, less tortuous path and elute more quickly and smaller molecules can pass into the pores and take a longer, more tortuous path and elute later.

In pharmaceutical sciences, tortuosity is used in relation to diffusion-controlled release from solid dosage forms. Insoluble matrix formers, such as ethyl cellulose, certain vinyl polymers, starch acetate and others control the permeation of the drug from the preparation and into the surrounding liquid. The rate of mass transfer per area unit is, among other factors, related to the shape of polymeric chains within the dosage form. Higher tortuosity or curviness retards mass transfer as it acts obstructively on the drug particles within the formulation.

HVAC makes extensive use of tortuosity in evaporator and condenser coils for heat exchangers, whereas Ultra-high vacuum makes use of the inverse of tortuosity, which is conductivity, with short, straight, voluminous paths.

References

^ Epstein, N. (1989), On tortuosity and the tortuosity factor in flow and diffusion through porous media, Chem. Eng. Sci., 44(3), 777– 779. [1]
^ Kaempfer, T. U., M. Schneebeli, and S. A. Sokratov (2005), A microstructural approach to model heat transfer in snow, Geophys. Res. Lett., 32, L21503,[2]
^ Richard M. Pearson. Optometric Grading Scales for use in everyday practice. Optometry Today, Vol. 43, No. 20, 2003, ISSN 0268-5485 [3]
^ William E. Hart, Michael Goldbaum, Brad Cote, Paul Kube, Mark R. Nelson. Automated measurement of retinal vascular tortuosity. International Journal of Medical Informatics, Vol. 53, No. 2-3, p. 239-252, 1999 [4]
^ Enrico Grisan, Marco Foracchia, Alfredo Ruggeri. A novel method for automatic evaluation of retinal vessel tortuosity. Proceedings of the 25th Annual International Conference of the IEEE EMBS, Cancun, Mexico, 2003 [5]
^ M. Mächler, Very smooth nonparametric curve estimation by penalizing change of curvature, Technical Report 71, ETH Zurich, May 1993 [6]
^ Patasius, M.; Marozas, V.; Lukosevicius, A.; Jegelevicius, D.. Evaluation of tortuosity of eye blood vessels using the integral of square of derivative of curvature // EMBEC'05: proceedings of the 3rd IFMBE European Medical and Biological Engineering Conference, November 20–25, 2005, Prague. - ISSN 1727-1983. - Prague. - 2005, Vol. 11, p. [1-4]
^ Gommes, C.J., Bons, A.-J., Blacher, S. Dunsmuir, J. and Tsou, A. (2009) Practical methods for measuring the tortuosity of porous materials from binary or gray-tone tomographic reconstructions. American Institute of Chemical Engineering Journal, 55, 2000-2012 [7]
^ E. Bullitt, G. Gerig, S. M. Pizer, Weili Lin, S. R. Aylward. Measuring tortuosity of the intracerebral vasculature from MRA images. IEEE Transactions on Medical Imaging, Volume 22, Issue 9, Sept. 2003, p. 1163 - 1171 [8]
^ Gostovic, D., et al., Three-dimensional reconstruction of porous LSCF cathodes. Electrochemical and Solid State Letters, 2007. 10(12): p. B214-B217. [9]
^ Watanabe, Y. and Nakashima, Y. (2001) Two-dimensional random walk program for the calculation of the tortuosity of porous media. Journal of Groundwater Hydrology, 43, 13-22 [10]
^ Gommes, C.J., Bons, A.-J., Blacher, S. Dunsmuir, J. and Tsou, A. (2009) Practical methods for measuring the tortuosity of porous materials from binary or gray-tone tomographic reconstructions. American Institute of Chemical Engineering Journal, 55, 2000-2012 [11]

UpToDate Contents

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English Journal

Polybutylene succinate adipate/starch blends: a morphological study for the design of controlled release films.

Khalil F1, Galland S1, Cottaz A1, Joly C2, Degraeve P1.
Carbohydrate polymers.Carbohydr Polym.2014 Aug 8;108:272-80. doi: 10.1016/j.carbpol.2014.02.062. Epub 2014 Feb 28.
Films made of plasticized starch (PLS)/poly(butylene succinate co-butylene adipate) (PBSA) blends were prepared by thermomechanical processing varying the PBSA proportions in blends to obtain biphasic materials with distinct morphologies. These morphologies were characterized by selective extraction
PMID 24751274

Imaging findings in a distinct lethal inherited arteriopathy syndrome associated with a novel mutation in the FBLN4 gene.

Rajeshkannan R1, Kulkarni C, Kappanayil M, Nampoothiri S, Malfait F, De Paepe A, Moorthy S.
European radiology.Eur Radiol.2014 Aug;24(8):1742-8. doi: 10.1007/s00330-014-3205-y. Epub 2014 May 17.
OBJECTIVES: We present the imaging findings of a newly identified lethal arteriopathy associated with a novel mutation in the gene encoding fibulin-4, occurring in a distinct community from southern India.MATERIAL AND METHODS: A total of 31 children from a distinct population subgroup who presented
PMID 24838734

The effect of polymer properties on direct compression and drug release from water-insoluble controlled release matrix tablets.

Grund J1, Koerber M2, Walther M1, Bodmeier R1.
International journal of pharmaceutics.Int J Pharm.2014 Jul 20;469(1):94-101. doi: 10.1016/j.ijpharm.2014.04.033. Epub 2014 Apr 16.
The objective of this study was to identify and evaluate key polymer properties affecting direct compression and drug release from water-insoluble matrices. Commonly used polymers, such as Kollidon(®) SR, Eudragit(®) RS and ethyl cellulose, were characterized, formulated into tablets and compared
PMID 24746409

Japanese Journal

A fractal model for characterizing fluid flow in fractured rock masses based on randomly distributed rock fracture networks

Liu Richeng,Jiang Yujing,Li Bo,Wang Xiaoshan
Computers and Geotechnics 65, 45-55, 2015-04
… The fractal dimension DT is utilized to represent the tortuosity of the fluid flow, and another fractal dimension Df is utilized to represent the geometric distribution of fractures in the networks. … The results indicate that the equivalent permeability of a fracture network can be significantly influenced by the tortuosity of the fluid flow, the aperture of the fractures and a random number used to generate the fractal length distribution of the fractures in the network. …
NAID 120005602590

Basilar Artery Angulation in Association with Aging and Pontine Lacunar Infarction: A Multicenter Observational Study

Jeong Seul-Ki,Lee Ju-Hee,Nam Do-Hyun,Kim Joon-Tae,Ha Yeon Soo,Oh Sun-Young,Park Se-Hyoung,Lee Sang Hyuk,Hur Nahmkeon,Kwak Hyo-Sung,Chung Gyung-Ho
Journal of Atherosclerosis and Thrombosis 22(5), 509-517, 2015
… The angles and triangular areas were summated into angulation indexes and used to quantify the degree of BA tortuosity.Results: The BA showed a more acute angle at the angulation point in the elderly patients than in the healthy subjects. …
NAID 130005071042

Influence of the Interfacial Transition Zone and Interconnection on Chloride Migration of Portland Cement Mortar

Wu Kai,Xu Linglin,Schutter Geert De,Shi Huisheng,Ye Guang
Journal of Advanced Concrete Technology 13(3), 169-177, 2015
… The ITZ effect would dominate the blocking aggregate, densification and tortuosity of bulk paste when aggregate volume content exceeded 0.35. …
NAID 130004940170

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