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出典(authority):フリー百科事典『ウィキペディア（Wikipedia）』「2016/06/06 15:47:55」(JST)
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P-toluenesulfonylhydrazide (1) and 1,3,5-triisopropylbenzenesulfonylhydrazide (2)
Hydrazides in organic chemistry are a class of organic compounds sharing a common functional group characterized by a nitrogen to nitrogen covalent bond with 4 substituents with at least one of them being an acyl group.[1] The general structure for a hydrazide is E(=O)-NR-NR2, where the R's are frequently hydrogens.[1] Hydrazides can be further classified by atom attached to the oxygen: carbohydrazides (R-C(=O)-NH-NH2), sulfonohydrazides (R-S(=O)2-NH-NH2), and phosphonic dihydrazides (R-P(=O)(-NH-NH2)2.[1] The related hydrazines do not carry an acyl group.[2] Some important members of this class are sulfonylhydrazides such as p-toluenesulfonylhydrazide which are useful reagents in organic chemistry such as in the Shapiro reaction. This reagent can be prepared by reaction of tosyl chloride with hydrazine.[3]
References
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Wikimedia Commons has media related to Hydrazides. |
- ^ a b c IUPAC, Compendium of Chemical Terminology, 2nd ed. (the "Gold Book") (1997). Online corrected version: (2006–) "Hydrazides".
- ^ IUPAC, Compendium of Chemical Terminology, 2nd ed. (the "Gold Book") (1997). Online corrected version: (2006–) "Hydrazines".
- ^ Lester Friedman; Robert L. Litle; Walter R. Reichle (1960). "p-toluenesulfonylhydrazide". Org. Synth. 40: 93. ; Coll. Vol. 5, p. 1055
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Hydrazines
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- 4-PTSC
- Acylhydrazine
- ADH
- Adjudin
- Agaritine
- Benmoxin
- Cadralazine
- Carbazide
- Carbidopa
- Carbohydrazide
- Daminozide
- Dihydralazine
- DNPH
- Endralazine
- Gyromitrin
- HBT
- Hydralazine
- Hydrazide
- Hydrazine
- Hydrazone
- Iproclozide
- Iproniazid
- Isocarboxazid
- Isoniazid
- Mebanazine
- Metfendrazine
- MMH
- Nialamide
- Octamoxin
- PEH
- Phenelzine
- Pheniprazine
- Phenoxypropazine
- Phenylhydrazine
- Pildralazine
- Pimagedine
- Pivalylbenzhydrazine
- Procarbazine
- Safrazine
- Semicarbazide
- Semicarbazone
- SDMH
- Tetrafluorohydrazine
- UDMH
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UpToDate Contents
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English Journal
- Immobilization of chondroitin sulfate to lipid membranes and its interactions with ECM proteins.
- Altgärde N, Becher J, Möller S, Weber FE, Schnabelrauch M, Svedhem S.SourceDepartment of Applied Physics, Chalmers University of Technology, 412 96 Göteborg, Sweden. Electronic address: noomi.altgarde@chalmers.se.
- Journal of colloid and interface science.J Colloid Interface Sci.2013 Jan 15;390(1):258-66. doi: 10.1016/j.jcis.2012.07.063. Epub 2012 Aug 7.
- Glycosaminoglycans (GAGs) in the extracellular matrix (ECM) have multiple functions in tissues including providing support, mediating cell division and differentiation, and taking part in important interactions with proteins, e.g. growth factors. Studying GAG related interactions is inherently diffi
- PMID 23026301
- Noninvasive Determination of 2-[18F]-Fluoroisonicotinic Acid Hydrazide Pharmacokinetics by Positron Emission Tomography in Mycobacterium tuberculosis-Infected Mice.
- Weinstein EA, Liu L, Ordonez AA, Wang H, Hooker JM, Tonge PJ, Jain SK.SourceCenter for Infection and Inflammation Imaging.
- Antimicrobial agents and chemotherapy.Antimicrob Agents Chemother.2012 Dec;56(12):6284-90. doi: 10.1128/AAC.01644-12. Epub 2012 Sep 24.
- Tuberculosis (TB) is a global pandemic requiring sustained therapy to facilitate curing and to prevent the emergence of drug resistance. There are few adequate tools to evaluate drug dynamics within infected tissues in vivo. In this report, we evaluated a fluorinated analog of isoniazid (INH), 2-[(1
- PMID 23006755
Japanese Journal
- A cross-linked polymer possessing a high density of hydrazide groups : high-throughput glycan purification and labeling for high-performance liquid chromatography analysis
- Abe Midori,Shimaoka Hideyuki,Fukushima Masao [他],NISHIMURA Shin-Ichiro
- Polymer journal 44(3), 269-277, 2012-03-15
- NAID 10030169203
- 体内でのフィルム形成 : 腹膜癒着防止膜と薬物送達膜
- 伊藤 大知,鈴木 幸光
- 膜 36(2), 63-70, 2011-03-01
- … We have designed and synthesized injectable hydrogels that are formed by mixing hydrazide-modified hyaluronic acid (HA) with aldehyde-modified versions of cellulose derivatives such as carboxymethylcellulose (CMC), hydroxypropylmethyl cellulose (HPMC), and methyl cellulose (MC). …
- NAID 10029601681
- Novel synthesis of 2-alkoxy(aralkoxy)-5-chloro〔1,2,4〕triazolo〔1,5-a〕quinazolines and their derivatives
- Al-Salahi Rashad,Geffken Detlef
- Heterocycles 81(8), 1843-1859, 2010-08-01
- NAID 40017214025
Related Links
- Hydrazides are a class of organic compounds characterized by a nitrogen-nitrogen covalent bond with four substituents with at least one of them being an acyl group. The development of new hydrazide derivatives is inspired by the ...
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