(of physical systems) continuing in its present state of equilibrium unless sufficiently disturbed to pass to a more stable state of equilibrium
English Journal
Mechanism of CO Displacement from an Unusually Labile Rhenium Complex: An Experimental and Theoretical Investigation.
Muhammad S, Yempally V, Anas M, Moncho S, Kyran SJ, Brothers EN, Darensbourg DJ, Bengali AA.SourceDepartment of Chemistry, Texas A&M University at Qatar , Doha, Qatar.
Inorganic chemistry.Inorg Chem.2012 Nov 15. [Epub ahead of print]
The displacement of a CO ligand from an unusually labile rhenium carbonyl complex containing a bidentate carboxyaldehyde pyrrolyl ligand by PPh(3) and pyridine has been investigated. The reaction is found to proceed by an associative, preequilibrium mechanism. Theoretical calculations support the ex
Elucidating the mechanism of the halide-induced ligand rearrangement reaction.
Yoo H, Rosen MS, Brown AM, Wiester MJ, Stern CL, Mirkin CA.SourceDepartment of Chemistry and the International Institute for Nanotechnology, Northwestern University , 2145 Sheridan Road, Evanston, Illinois, 60208, United States.
Inorganic chemistry.Inorg Chem.2012 Nov 5;51(21):11986-95. doi: 10.1021/ic3018776. Epub 2012 Oct 22.
The formation of heteroligated Rh(I) complexes containing two different hemilabile phosphinoalkyl ligands, (κ(2)-Ph(2)PCH(2)CH(2)S-Aryl)(κ(1)-Ph(2)PCH(2)CH(2)O-C(6)H(5))RhCl, through a halide-induced ligand rearrangement (HILR) reaction has been studied mechanistically. The half-life of this rearr
HEMILABILE PHOSPHONA TE-PHOSPHANE-RH-CA TAL YSTS FOR HOMOGENEOUS AND HETEROGENEOUS CARBONYLA TION S. Bischoff *, A. Weigt. H. MieBner, B. Lucke 12489 Berlin-Adlershof, F.R.Germany