ブロムフェノールブルー、ブロモフェノールブルー
- 関
- BPB、bromophenol blue
WordNet
- used to signify the Union forces in the American Civil War (who wore blue uniforms); "a ragged blue line"
- blue color or pigment; resembling the color of the clear sky in the daytime; "he had eyes of bright blue" (同)blueness
- any of numerous small butterflies of the family Lycaenidae
- blue clothing; "she was wearing blue"
- any organization or party whose uniforms or badges are blue; "the Union army was a vast blue"
- of the color intermediate between green and violet; having a color similar to that of a clear unclouded sky; "Octobers bright blue weather"- Helen Hunt Jackson; "a blue flame"; "blue haze of tobacco smoke" (同)bluish, blueish
- causing dejection; "a blue day"; "the dark days of the war"; "a week of rainy depressing weather"; "a disconsolate winter landscape"; "the first dismal dispiriting days of November"; "a dark gloomy day"; "grim rainy weather" (同)dark, dingy, disconsolate, dismal, gloomy, grim, sorry, drab, drear, dreary
- suggestive of sexual impropriety; "a blue movie"; "blue jokes"; "he skips asterisks and gives you the gamy details"; "a juicy scandal"; "a naughty wink"; "naughty words"; "racy anecdotes"; "a risque story"; "spicy gossip" (同)gamy, gamey, juicy, naughty, racy, risque, spicy
- morally rigorous and strict; "the puritan work ethic"; "puritanic distaste for alcohol"; "she was anything but puritanical in her behavior" (同)puritanic, puritanical
- turn blue
- a state of depression; "he had a bad case of the blues" (同)blue devils, megrims, vapors, vapours
- a type of folksong that originated among Black Americans at the beginning of the 20th century; has a melancholy sound from repeated use of blue notes
- a process that makes something blue (or bluish) (同)blueing
- used to whiten laundry or hair or give it a bluish tinge (同)blueing, blue
PrepTutorEJDIC
- 『青い』,あい色の / 青黒い / 《話》陰気な,憂うつな / 〈U〉『青色』,あい色;青色の着物 / 〈U〉〈C〉青色絵の具,あい色染料 / 《the~》《詩》青空,青い海 / 《the blues》《話》気のふさぎ,うれいの色 / 《the blues》《ときに単数扱い》(ジャズ音楽の)ブルース / …'を'青色にする
- = bluing
Wikipedia preview
出典(authority):フリー百科事典『ウィキペディア(Wikipedia)』「2017/12/27 10:06:50」(JST)
[Wiki en表示]
Bromophenol blue
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Names |
IUPAC name
4,4′-(1,1-dioxido-3H-2,1-benzoxathiole-3,3-diyl)bis(2,6-dibromophenol)
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Identifiers |
CAS Number
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3D model (JSmol)
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ChEBI |
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ChemSpider |
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ECHA InfoCard |
100.003.715 |
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InChI
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InChI=1S/C19H10Br4O5S/c20-12-5-9(6-13(21)17(12)24)19(10-7-14(22)18(25)15(23)8-10)11-3-1-2-4-16(11)29(26,27)28-19/h1-8,24-25H Y
Key: UDSAIICHUKSCKT-UHFFFAOYSA-N Y
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InChI=1/C19H10Br4O5S/c20-12-5-9(6-13(21)17(12)24)19(10-7-14(22)18(25)15(23)8-10)11-3-1-2-4-16(11)29(26,27)28-19/h1-8,24-25H
Key: UDSAIICHUKSCKT-UHFFFAOYAE
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SMILES
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Brc1cc(cc(Br)c1O)C3(OS(=O)(=O)c2ccccc23)c4cc(Br)c(O)c(Br)c4
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Properties |
Chemical formula
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C19H10Br4O5S |
Molar mass |
669.96 g·mol−1 |
Odor |
odorless |
Density |
2.2 g/mL[1] |
Melting point |
273 °C (523 °F; 546 K) |
Boiling point |
279 °C (534 °F; 552 K) |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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N verify (what is YN ?) |
Infobox references |
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Bromophenol blue (3′,3″,5′,5″-tetrabromophenolsulfonphthalein, BPB,[2] albutest[3]) is used as a pH indicator, a color marker, and a dye. It can be prepared by slowly adding excess bromine to a hot solution of phenolsulfonphthalein in glacial acetic acid.[4]
Contents
- 1 Acid–base indicator
- 2 Color marker
- 3 Dye
- 4 External links
- 5 References
Acid–base indicator
Bromophenol blue (pH indicator) |
below pH 3.0 |
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above pH 4.6 |
3.0 |
⇌ |
4.6 |
As an acid–base indicator, its useful range lies between pH 3.0 and 4.6. It changes from yellow at pH 3.0 to blue at pH 4.6; this reaction is reversible.[5] Bromophenol blue is structurally related to phenolphthalein (a popular indicator).
Color marker
Bromophenol blue is also used as a color marker to monitor the process of agarose gel electrophoresis and polyacrylamide gel electrophoresis. Since bromophenol blue carries a slight negative charge at moderate pH, it will migrate in the same direction as DNA or protein in a gel; the rate at which it migrates varies according to gel density and buffer composition, but in a typical 1% agarose gel in a 1X TAE buffer or TBE buffer, bromophenol blue migrates at the same rate as a DNA fragment of about 300 base pairs, in 2% agarose as 150 bp. Xylene cyanol and orange G may also be used for this purpose.[6]
Dye
Bromophenol blue is also used as a dye. At neutral pH, the dye absorbs red light most strongly and transmits blue light. Solutions of the dye, therefore, are blue. At low pH, the dye absorbs ultraviolet and blue light most strongly and appears yellow in solution. In solution at pH 3.6 (in the middle of the transition range of this pH indicator) obtained by dissolution in water without any pH adjustment, bromophenol blue has a characteristic green red color, where the apparent color shifts depending on the concentration and/or path length through which the solution is observed. This phenomenon is called dichromatic color.[7] Bromophenol blue is the substance with the highest known value of Kreft's dichromaticity index.[8] This means it has the largest change in color hue, when the thickness or concentration of observed sample increases or decreases.
External links
- Bromophenol blue at OpenWetWare
References
- ^ Santa Cruz Biotechnology, Inc. Bromophenol Blue (CAS 115-39-9) Properties. https://www.scbt.com/scbt/product/bromophenol-blue-115-39-9
- ^ Reaxys. Bromophenol blue (115-39-9) Chemical Names and Synonyms.
- ^ PubChem Compound. Bromphenol Blue - Compound Summary. https://pubchem.ncbi.nlm.nih.gov/summary/summary.cgi?cid=8272&loc=ec_rcs
- ^ PubChem Compound. Bromphenol Blue - Use and Manufacturing. https://pubchem.ncbi.nlm.nih.gov/summary/summary.cgi?cid=8272&loc=ec_rcs
- ^ http://www.sigmaaldrich.com/Graphics/COfAInfo/SigmaSAPQM/SPEC/B0/B0126/B0126-BULK________SIAL_____.pdf
- ^ "Agarose gel electrophoresis (basic method)". Retrieved 2008-04-07.
- ^ Kreft S, Kreft M (2007). "Physicochemical and physiological basis of dichromatic colour". Naturwissenschaften. 94 (11): 935–9. Bibcode:2007NW.....94..935K. doi:10.1007/s00114-007-0272-9. PMID 17534588.
- ^ Kreft S, Kreft M. (2009). "Quantification of dichromatism: a characteristic of color in transparent materials". Journal of the Optical Society of America A. 26 (7): 1576–1581. Bibcode:2009JOSAA..26.1576K. doi:10.1364/JOSAA.26.001576. PMID 19568292.
UpToDate Contents
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Japanese Journal
- 抗菌剤とポバールの表面処理によるレーヨンの生分解の抑制
- 新田見 匡,村田 良太,中村 健二,松本 幹治,中村 一穂
- 土木学会論文集G(環境) 67(1), 39-46, 2011
- 生分解性高分子材料であるレーヨンの表面に,抗菌処理剤DC5700とポバール(PVA)をコーティングして,環境中におけるレーヨンの生分解を抑制する研究を行った.活性汚泥中,バーク堆肥中において,DC5700のコーティングの有無によるレーヨンの分解期間を比較したところ,含水率が56 wt%以下の条件ではコーティングをしたレーヨンの分解期間が顕著に長くなることを確認した.また含水率が40 wt%以下の …
- NAID 130004560191
- Absorption characteristics of compounds with different molecular weights after application to the unilateral kidney surface in rats
- Nishida Koyo,Tomiyama Naoki,Mukai Takahiro,Nakashima Mikiro,Sasaki Hitoshi,Nakamura Junzo
- European Journal of Pharmaceutics and Biopharmaceutics 58(3), 705-711, 2004-11
- … Furthermore, we examined the importance of molecular weight on the absorption from the kidney surface using fluorescein isothiocyanate-dextrans (FDs) with molecular weights of 4400 (FD-4), 11,000 (FD-10), 40,500 (FD-40) or 69,000 (FD-70), including the organic anions bromphenol blue and bromosulfonphthalein. …
- NAID 120000918282
- 掌せき多汗症に対するボツリヌス菌毒素を用いた治療経験
- 村上 義之,高梨 真教,湧川 基史
- 西日本皮膚科 65(6), 599-604, 2003
- 近年,多汗症の治療にボツリヌス菌毒素製剤が使用され,他の保存的治療や外科的治療に代わる簡便で,安全かつ有効な治療であることが報告されてきている。ボツリヌス菌毒素製剤の表情皺への投与に比べると,多汗症での注入法·注入量の基準は未だ確立されているとは言い難い。今回我々は4例の掌蹠多汗症患者に対してDysport<SUP>®</SUP>を用いて,その注入法や注入量を検討した。先ず …
- NAID 130004474967
Related Links
- Synonym: 3′,3′′,5′,5′′-Tetrabromophenolsulfonephthalein, Bromophenol Blue (BPB), Bromphenol Blue Sultone Form SDS Similar Products CAS Number 115-39-9 Empirical Formula (Hill Notation) C 19 H 10 Br 4 O 5 S 669.96 ...
- Bromophenol Blue 販売元 和光純薬工業(株) 販売元コード 021-02911,029-02912 製造元 製造元コード CAS.NO 115-39-9 分子式 C19H10Br4O5S 分子量 669.96 保存条件 室温 適用法規 危険有害性 等級 試薬特級 JIS Special Grade ...
★リンクテーブル★
[★]
- 英
- bromphenol blue, BPB
- 同
- ブロモフェノールブルー bromophenol blue 、3,3',5,5'-テトラブロモフェノールスルホンフタレイン 3,3',5,5'-tetrabromophenol sulfonphthalein
- 関
- 指示薬、アルブミン
[★]
- 英
- bromophenol blue、bromphenol blue、BPB
- 関
- ブロムフェノールブルー
[★]
- 関
- bromophenol blue、bromphenol blue
[★]
ブロモフェノールブルー
- 関
- BPB、bromphenol blue
[★]
- 関
- cyan
[★]