ファラデー定数、Faraday定数
WordNet
- steadfast in purpose or devotion or affection; "a man constant in adherence to his ideals"; "a constant lover"; "constant as the northern star"
- a number representing a quantity assumed to have a fixed value in a specified mathematical context; "the velocity of light is a constant"
- a quantity that does not vary (同)constant quantity, invariable
- the English physicist and chemist who discovered electromagnetic induction (1791-1867) (同)Michael Faraday
PrepTutorEJDIC
- 『不変の』,一定の / 『絶え間のない』,不断の,繰り返される / 《文》〈人が〉心変わりしない;(…に対して)誠実な,貞節な《+『to』+『名』》 / (数学で)常数;(化学・物理分析などにおける)定量
- ファラデー(電気分解に用いられる電気量の単位)
Wikipedia preview
出典(authority):フリー百科事典『ウィキペディア(Wikipedia)』「2014/05/05 18:59:50」(JST)
[Wiki en表示]
In physics and chemistry, the Faraday constant (named after Michael Faraday) is the magnitude of electric charge per mole of electrons.[1] It has the currently accepted value
- 9.64853399(24) x 104 C mol-1.
The constant F has a simple relation to two other physical constants:
where
- e ≈ 1.6021766×10−19 C;[2]
- NA ≈ 6.022141×1023 mol−1.[3]
NA is the Avogadro constant (the ratio of the number of particles N to the amount of substance n - a unit mole), and e is the elementary charge or the magnitude of the charge of an electron. This relation is true because the amount of charge of a mole of electrons is equal to the amount of charge in one electron multiplied by the number of electrons in a mole.
One common use of the faraday constant is Electrolysis. One can divide the amount of charge in coulombs by the Faraday constant in order to find the amount (in moles) of the element that has been Oxidized.
The value of F was first determined by weighing the amount of silver deposited in an electrochemical reaction in which a measured current was passed for a measured time, and using Faraday's law of electrolysis.[4] Research is continuing into more accurate ways of determining the interrelated constants F, NA, and e.
Contents
- 1 Other Common Units of Faraday's Constant
- 2 Faraday unit of charge
- 3 Popular media
- 4 See also
- 5 References
Other Common Units of Faraday's Constant
- 96,485 J (96.485 kJ) per volt gram equivalent
- 23.061 kcal per volt gram equivalent
- 26.801 A·h/mol
Faraday unit of charge
Related to Faraday's constant is the "faraday", a unit of electrical charge. It is much less common than the coulomb, but sometimes used in electrochemistry.[5] One faraday of charge is the magnitude of the charge of one mole of electrons, i.e. 96485.3365(21) C.[6]
Expressed in faradays, the Faraday constant F equals "1 faraday of charge per mole".
This faraday unit is not to be confused with the farad, an unrelated unit of capacitance (1 farad= 1 coulomb/1 volt).
Popular media
The Simpsons episode "Dark Knight Court" (RABF10) has Mr. Burns asking Comic Book Guy how much he wants for his entire comic book inventory. He says "the speed of light expressed as dollars" and Mr. Burns says to Smithers, "give him Faraday's Constant." The check is written for $96,485.34.
See also
- Faraday cage
- Faraday efficiency
- Faraday's law of electrolysis
- Faraday's law of Electromagnetic induction
References
- ^ The term "magnitude" is used in the sense of "absolute value": The charge of an electron is negative, but F is always defined to be positive.
- ^ "CODATA Value: elementary charge". The NIST Reference on Constants, Units, and Uncertainty. US National Institute of Standards and Technology. June 2011. Retrieved 2011-06-23.
- ^ "CODATA Value: Avogadro constant". The NIST Reference on Constants, Units, and Uncertainty. US National Institute of Standards and Technology. June 2011. Retrieved 2011-06-23.
- ^ NIST Introduction to physical constants
- ^ Foundations Of Physics, Volume 2, by R. S. Gambhir, p51
- ^ "CODATA Value: Faraday constant". The NIST Reference on Constants, Units, and Uncertainty. US National Institute of Standards and Technology. June 2011. Retrieved 2011-06-23.
UpToDate Contents
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English Journal
- Electrochemical stability of Sm0.5Sr0.5CoO3-δ-infiltrated YSZ for solid oxide fuel cells/electrolysis cells.
- Fan H1, Han M.
- Faraday discussions.Faraday Discuss.2015 Jul 27. [Epub ahead of print]
- Composite SSC (Sm0.5Sr0.5CoO3-δ)-YSZ (yttria stabilized zirconia) oxygen electrodes were prepared by an infiltration process. X-ray diffraction (XRD) analysis and scanning electron microscopy (SEM) of the composite electrodes showed the formation of SSC perovskite and a well-connected network of SS
- PMID 26212177
- Timescales of N-H bond dissociation in pyrrole: a nonadiabatic dynamics study.
- Sapunar M1, Ponzi A, Chaiwongwattana S, Mališ M, Prlj A, Decleva P, Došlić N.
- Physical chemistry chemical physics : PCCP.Phys Chem Chem Phys.2015 Jul 15;17(29):19012-20. doi: 10.1039/c5cp02100f.
- The excitation wavelength dependent photodynamics of pyrrole are investigated by nonadiabatic trajectory-surface-hopping dynamics simulations based on time dependent density functional theory (TDDFT) and the algebraic diagrammatic construction method to the second order (ADC(2)). The ADC(2) results
- PMID 26129838
- Bluetooth Communication Interface for EEG Signal Recording in Hyperbaric Chambers.
- Pastena L, Formaggio E, Faralli F, Melucci M, Rossi M, Gagliardi R, Ricciardi L, Storti SF.
- IEEE transactions on neural systems and rehabilitation engineering : a publication of the IEEE Engineering in Medicine and Biology Society.IEEE Trans Neural Syst Rehabil Eng.2015 Jul;23(4):538-47. doi: 10.1109/TNSRE.2015.2391672. Epub 2015 Jan 16.
- Recording biological signals inside a hyperbaric chamber poses technical challenges (the steel walls enclosing it greatly attenuate or completely block the signals as in a Faraday cage), practical (lengthy cables creating eddy currents), and safety (sparks hazard from power supply to the electronic
- PMID 25608308
Japanese Journal
- チオ尿素を含む溶液中における銅めっきの電気化学インピーダンスで観察される負性抵抗の解釈
- , , [他], ,
- Electrochemistry 83(3), 142-149, 2015
- … The Nyquist plot of impedance spectrum in the presence of the thiourea described the capacitive loop, which was related to the time constant of the charge transfer resistance and the electric double layer capacitance, in the high frequency range and a part of the large locus crossing the imaginary axis in the low frequency range. … In order to clarify the negative resistance, the theoretical equations of the Faraday impedance were derived. …
- NAID 130004787087
- Theory of Light Scattering in Axion Electrodynamics
- OCHIAI Tetsuyuki
- J Phys Soc Jpn 81(9), 094401-094401-8, 2012-09-15
- … Taking account of the axion term in the Maxwell Lagrangian, we present a rigorous theory of light scattering in piecewise-constant axion fields. … We demonstrate enhanced Faraday rotation, parity-violating light scattering, and strong perturbation of dipole radiation. …
- NAID 40019415505
- MOD法によるガラス基板上へのBi3Fe5O12薄膜の作製と評価
- 池原 成拓,和田 翔,小林 司 [他],後藤 聡希,吉田 和彦,石橋 隆幸,西 敬生
- Journal of the Magnetics Society of Japan 36(3), 169-172, 2012
- … The Faraday rotation of the BIG/Bi-YIG films was 13.55 deg/μm at a wavelength of 525 nm, and a maximum figure of merit of the BIG/Bi-YIG films was obtained at 528 nm. … In addition, the well-matched lattice constant of BIG with the relationship between the lattice constant and the Bi-substitution rate was shown by successful crystallization of BIG. …
- NAID 130002112341
Related Links
- faraday /far·a·day/ (F) (far´ah-da) the electric charge carried by one mole of electrons or one equivalent weight of ions, equal to 9.649 × 104coulombs. far·a·day (făr′ə-dā′) n. The electric charge required to deposit or liberate 1 gram ...
- What is the Faraday constant? This definition explains what Faraday's constant is, how it is used for calculations and whol Michael Faraday was. ... software-defined networking (SDN) Software-defined networking (SDN) is an ...
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