- 関
- trigonal
WordNet
- (physical chemistry) a sample of matter in which substances in different phases are in equilibrium; "in a static system oil cannot be replaced by water on a surface"; "a system generating hydrogen peroxide"
- instrumentality that combines interrelated interacting artifacts designed to work as a coherent entity; "he bought a new stereo system"; "the system consists of a motor and a small computer"
- a group of independent but interrelated elements comprising a unified whole; "a vast system of production and distribution and consumption keep the country going" (同)scheme
- a complex of methods or rules governing behavior; "they have to operate under a system they oppose"; "that language has a complex system for indicating gender" (同)system of rules
- a group of physiologically or anatomically related organs or parts; "the body has a system of organs for digestion"
- a procedure or process for obtaining an objective; "they had to devise a system that did not depend on cooperation"
- the living body considered as made up of interdependent components forming a unified whole; "exercise helped him get the alcohol out of his system"
- a triangular lyre of ancient Greece and Rome
PrepTutorEJDIC
- 〈C〉(関連した部分から成る)『体系』,系統,組織[網],装置 / 〈C〉(教育・政治などの)『制度』,機構;《the~》体制 / 〈C〉(思想・学問などの)『体系』,学説 / 〈C〉(…の)『方法』,方式,やり方《+of doing》 / 〈U〉正しい方針(筋道,順序) / 〈U〉《the~》(身体の)組織,系統 / 〈U〉《the~,one's~》身体,全身
Wikipedia preview
出典(authority):フリー百科事典『ウィキペディア(Wikipedia)』「2015/12/10 18:33:09」(JST)
[Wiki en表示]
Example trigonal crystals (quartz) |
Example trigonal rhombohedral crystals (dolomite) |
Hexagonal lattice cell |
Hexagonal rhombohedral unit cell |
In crystallography, the trigonal crystal system is one of the seven crystal systems. Sometimes the term rhombohedral lattice system is used as an exact synonym, whereas it is a subset. Crystals in the rhombohedral lattice system are always in the trigonal crystal system, but some crystals such as quartz are in the trigonal crystal system but not in the rhombohedral lattice system. The rhombohedral lattice system consists of the rhombohedral lattice, while the trigonal crystal system consists of the five point groups of the seven space groups with a rhombohedral lattice. There are 25 space groups whose point groups are one of the five in the trigonal crystal system, consisting of the seven space groups associated with the rhombohedral lattice system together with 18 of the 45 space groups associated with the hexagonal lattice system.
The trigonal point group describes the symmetry of an object produced by stretching a cube along the body diagonal. The resultant rhombohedral (or trigonal) Bravais lattice is generated by three primitive vectors of equal length that make equal angles with one another.[1]
"Rhombohedral crystal system" is an ambiguous term that confuses the trigonal crystal system with the rhombohedral lattice system and may mean either of them (or even the hexagonal crystal family).
In the classification into 6 crystal families, the trigonal crystal system is combined with the hexagonal crystal system and grouped into a larger hexagonal family.[2]
Contents
- 1 Rhombohedral lattice system
- 2 Crystal classes
- 3 See also
- 4 References
- 5 External links
Rhombohedral lattice system
There are two descriptions (settings) of the rhombohedral lattice system.
- Hexagonal axes. The unit cell is a = b ≠ c; α = β = 90°, γ = 120°. Two additional lattice points occupy space diagonal of the unit cell and have coordinates 2/3 1/3 1/3 and 1/3 2/3 2/3. Hence, there are totally 3 lattice points per unit cell.
- Rhombohedral axes. The unit cell is a rhombohedron (which gives the name for rhombohedral lattice system). This is a primitive unit cell (no additional lattice points inside unit cell) with parameters a = b = c; α = β = γ ≠ 90°.
In practice, the hexagonal description is more commonly used because it is easier to deal with coordinate system with two 90° angles. However, the rhombohedral axes are often shown in textbooks because this cell reveals 3m symmetry of crystal lattice. The relation between two settings is given below.
The rhombohedral lattice system is combined with the hexagonal lattice system and grouped into a larger hexagonal family. These lattice systems belong to hexagonal family because the same (hexagonal) unit cell can be used for both of them.
Crystal classes
The trigonal crystal system is the only crystal system whose point groups have more than one lattice system associated with their space groups: the hexagonal and rhombohedral lattices both appear.
The 5 point groups in this crystal system are listed below, with their international number and notation, their space groups in name and example crystals. (All these point groups are also associated with some space groups not in the rhombohedral lattice system.)[3][2][4]
# |
Point group |
Examples |
Space group |
Class |
Intl |
Schoen. |
Orb. |
Cox. |
143-146 |
Pyramidal
rhombohedral tetartohedral |
3 |
C3 |
33 |
[3]+ |
carlinite, jarosite |
P3, P31, P32
R3 |
147-148 |
Rhombohedral
rhombohedral tetartohedral |
3 |
S6 |
3× |
[2+,6+] |
dolomite, ilmenite |
P3
R3 |
149-155 |
trapezohedral |
32 |
D3 |
223 |
[2,3]+ |
abhurite, quartz, cinnabar |
P312, P321, P3112, P3121, P3212, P3221
R32 |
156-161 |
Ditrigonal Pyramidal
rhombohedral hemimorphic |
3m |
C3v |
*33 |
[3] |
schorl, cerite, tourmaline, alunite, lithium tantalate |
P3m1, P31m, P3c1, P31c
R3m, R3c |
162-167 |
Hexagonal Scalenohedral
rhombohedral holohedral |
3m |
D3d |
2*3 |
[2+,6] |
antimony, hematite, corundum, calcite |
P31m, P31c, P3m1, P3c1
R3m, R3c |
See also
References
- ^ Ashcroft, Neil W.; Mermin, N. David, 1976, "Solid State Physics," 1st ed., p. 119 ISBN 0-03-083993-9
- ^ a b Hurlbut, Cornelius S.; Klein, Cornelis, 1985, Manual of Mineralogy, 20th ed., pp. 78–89 ISBN 0-471-80580-7
- ^ Frederick H. Pough, Roger Tory Peterson (1998). A Field Guide to Rocks and Minerals. Houghton Mifflin Harcourt. p. 62. ISBN 0-395-91096-X.
- ^ Crystallography and Minerals Arranged by Crystal Form, Webmineral
External links
The 7 crystal systems
|
|
- triclinic
- monoclinic
- orthorhombic
- tetragonal
- trigonal
- hexagonal
- cubic (isometric)
|
|
UpToDate Contents
全文を閲覧するには購読必要です。 To read the full text you will need to subscribe.
English Journal
- Self-Assembly of C Symmetric Rigid Macrolactams into Very Polar and Porous Trigonal Crystals.
- Marmin T, Dory YL.
- Chemistry (Weinheim an der Bergstrasse, Germany). 2019 May;25(27)6707-6711.
- Cyclohexane and cyclotri-β-alanyl have been used as scaffolds for the design of new C -symmetric rings incorporating conjugated alkenes and dienes. All three C -symmetric lactams share the same triangular shape and their crystal system is trigonal. They all belong to the R3 space group, R3m, R3 and
- PMID 30913318
- Scalable Geometrically Designed Protein Cages Assembled via Genetically Encoded Split Inteins.
- Wright JN, Wong WL, Harvey JA, Garnett JA, Itzhaki LS, Main ERG.
- Structure (London, England : 1993). 2019 May;27(5)776-784.e4.
- Engineering proteins to assemble into user-defined structures is key in their development for biotechnological applications. However, designing generic rather than bespoke solutions is challenging. Here we describe an expandable recombinant assembly system that produces scalable protein cages via sp
- PMID 30879889
- A Revised Structure Model for the UCl Structure Type, Novel Modifications of UCl and UBr , and a Comment on the Modifications of Protactinium Pentabromides.
- Deubner HL, Rudel SS, Sachs M, Pietzonka C, Karttunen AJ, Ivlev SI, Müller M, Conrad M, Müller U, Kraus F.
- Chemistry (Weinheim an der Bergstrasse, Germany). 2019 May;25(25)6402-6411.
- The redetermination of the crystal structure of trigonal UCl , which is the eponym for the UCl structure type, showed that certain atomic coordinates had been incorrectly reported. This led to noticeably different U-Cl distances within the octahedral UCl molecule (2.41 and 2.51 Å). Within the rev
- PMID 30865329
Japanese Journal
- Uniaxial-Pressure Effects on Spin-Driven Lattice Distortions in Geometrically Frustrated Magnets CuFe₁₋xGa[x]O₂ (x=0, 0.035)
- NAKAJIMA Taro,IGUCHI Yusuke,TAMATSUKURI Hiromu [他],Mitsuda Setsuo,Yamasaki Yuichi,Nakao Hironori,Terada Noriki
- J Phys Soc Jpn 82(11), 114711-114711-7, 2013-11-15
- … The triangular lattice antiferromagnet CuFeO<inf>2</inf>(CFO) is a spin--lattice coupled system, whose magnetic phase transitions are accompanied by crystal lattice distortions to relieve the geometrical spin frustration. … We have also found that CFO exhibits a pronounced lattice instability in the vicinity of the phase transition from the paramagnetic phase with a trigonal structure to an incommensurate magnetic phase with a monoclinic structure. …
- NAID 40019871754
- Quasi-Topological Insulator and Trigonal Warping in Gated Bilayer Silicene
- EZAWA Motohiko
- J Phys Soc Jpn 81(10), 104713-104713-8, 2012-10-15
- … Bilayer silicene has richer physical properties than bilayer graphene due to its buckled structure together with its trigonal symmetric structure. … The trigonal symmetry originates in a particular way of hopping between two silicenes. … Furthermore we find that there are several critical electric fields where the gap closes due to the trigonal warping effect in bilayer silicene. …
- NAID 150000103537
- Crystal Structures and 3d Electron Configurations for the Li[x]V₂(PO₄)₃ Insertion Electrode System with a Semi-Double-Electron Reaction
- ONODA Masashige,HIROSE Hajime
- J Phys Soc Jpn 81(9), 094801-094801-9, 2012-09-15
- … The crystal structures and electronic properties of the LixV2(PO4)3 or LixV2P3O12 insertion electrode system that exhibits a semi-double-electron reaction are explored through measurements of x-ray four-circle diffraction and magnetization. … The electron configurations of V ions for 0.9 \leq x \leq 3 are considered in the framework of intermediate pseudo-trigonal crystal field approach. …
- NAID 150000103221
Related Links
- Trigonal system, a structural category of crystalline solids sometimes considered as a subdivision of the hexagonal system. The unit cell has a single line called an axis of three-fold symmetry about which the cell can be rotated by ...
- ブリタニカ国際大百科事典 小項目事典 - 三方晶系の用語解説 - 結晶系の1つ。六方晶系に含められることがある。菱面体晶系とも呼ばれる。結晶軸の1つ ( c 軸) が3回の回転軸または回反軸であり,他の2つの結晶軸は c 軸に垂直で互いに ...
- Trigonal system definition is - a crystal system that is characterized by three equal and equally inclined axes and that is commonly held to be a division of the hexagonal system.
Related Pictures
★リンクテーブル★
[★]
- 英
- trigonal system、trigonal
- 関
- 三方晶、三方平面
[★]
- 関
- method、series、strain
[★]
- 関
- trigonal system