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出典(authority):フリー百科事典『ウィキペディア（Wikipedia）』「2017/05/27 00:55:19」(JST)
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The term supermolecule (or supramolecule) was introduced by Karl Lothar Wolf et al. (Übermoleküle) in 1937 to describe hydrogen-bonded acetic acid dimers.[1][2] The study of non-covalent association of complexes of molecules has since developed into the field of supramolecular chemistry. The term supermolecule is sometimes used to describe supramolecular assemblies, which are complexes of two or more molecules (often macromolecules) that are not covalently bonded.[3] [4] The term supermolecule is also used in biochemistry to describe complexes of biomolecules, such as peptides and oligonucleotides composed of multiple strands.[5]
See also
- Supramolecular chemistry
- Molecular self-assembly
- Supramolecular assembly
- Macromolecule
References
- ^ Wolf, K. L., Frahm, H. Harms, H. (1937). "The State of Arrangement of Molecules in Liquids". Z Phys. Chem., Abt. B, 36, 237–287.
- ^ Historical Remarks on Supramolecular Chemistry – PDF (16 pg. paper)
- ^ Supermolecule – thefreedictionary.com
- ^ Lehn, Jean-Marie (1995). Supramolecular Chemistry. VCH. ISBN 3-527-29311-6.
- ^ Lehninger, A. L. (1966). Naturwiss. 53, 57–63.
English Journal
- Affinity of Smectite and Divalent Metal Ions (Mg(2+), Ca (2+), Cu (2+)) with L-leucine: An Experimental and Theoretical Approach Relevant to Astrobiology.
- Pandey P1, Pant CK, Gururani K, Arora P, Pandey N, Bhatt P, Sharma Y, Negi JS, Mehata MS.
- Origins of life and evolution of the biosphere : the journal of the International Society for the Study of the Origin of Life.Orig Life Evol Biosph.2015 Dec;45(4):411-26. doi: 10.1007/s11084-015-9437-2. Epub 2015 May 8.
- Earth is the only known planet bestowed with life. Several attempts have been made to explore the pathways of the origin of life on planet Earth. The search for the chemistry which gave rise to life has given answers related to the formation of biomonomers, and their adsorption on solid surfaces has
- PMID 25952510
- The conformation effect of the diamine bridge on the stability of dinuclear platinum(II) complexes and their hydrolysis.
- Esteves LF1, Dos Santos HF1, Costa LA2.
- Journal of molecular graphics & modelling.J Mol Graph Model.2015 Sep;61:290-6. doi: 10.1016/j.jmgm.2015.08.006. Epub 2015 Aug 18.
- In this paper, the hydrolysis process of a bisplatinum complex containing the flexible chain 1,6-hexanediamine between the two metal centers was investigated through the use of density functional theory (DFT) with the analysis of the role of the spacing group arrangement on the values of free energy
- PMID 26318233
- Heat-set gels formed from easily accessible gelators of a succinamic acid derivative (SAD) and a primary alkyl amine (R-NH2).
- Zhong DC1, Liao LQ, Wang KJ, Liu HJ, Luo XZ.
- Soft matter.Soft Matter.2015 Aug 28;11(32):6386-92. doi: 10.1039/c5sm01305d. Epub 2015 Jun 29.
- Currently, the design and construction of an intelligent stimuli-responsive gel system is still a significant challenge. We present here a new gel system from which the formation of heat-set gels, conventional gels and irreversible heat-set gels can be achieved in aromatic solvents. This gel system
- PMID 26118365
Japanese Journal
- 超分子構造高分子によるインテリジェント機能の発現と生体材料応用 (特集 インテリジェント高分子(2))
- 高分子論文集 = Japanese journal of polymer science and technology 74(4), 239-249, 2017
- NAID 40021279856
- 超分子構造高分子によるインテリジェント機能の発現と生体材料応用
- Artificial DNA Base Pairing Mediated by Diverse Metal Ions
Related Links
- The term supermolecule or supramolecule, was introduced by K.L. Wolf ( Übermoleküle) in 1937 to describe hydrogen bonded acetic acid dimers. The study of non-covalent association of complexes of molecules has since developed into the ...
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