関: stereocontrolled

English Journal

Biocatalysis for desymmetrization and resolution of stereocenters beyond the reactive center: How far is far enough?

Cunha RL1, Ferreira EA2, Oliveira CS1, Omori ÁT3.
Biotechnology advances.Biotechnol Adv.2015 Sep-Oct;33(5):614-23. doi: 10.1016/j.biotechadv.2014.12.009. Epub 2015 Jan 2.
The kinetic resolution of racemates and desymmetrization are the most common approaches to the preparation of enantiomerically enriched compounds. These procedures allow the access of high valuable, chiral building blocks for many purposes in academic or industrial R&D endeavors. Nevertheless, t
PMID 25560930

Synergistic Stereocontrol in the Enantioselective Ruthenium-Catalyzed Sulfoxidation of Spirodithiolane-Indolones.

Zhong F1, Pöthig A1, Bach T2.
Chemistry (Weinheim an der Bergstrasse, Germany).Chemistry.2015 Jul 13;21(29):10310-3. doi: 10.1002/chem.201501780. Epub 2015 Jun 10.
A chiral ruthenium catalyst was developed for the enantioselective sulfoxidation of the title compounds. The catalyst combines two elements of chirality, a chiral pybox ligand and a chiral bicylic lactam unit, to which the ligand is attached. The latter unit was shown to improve significantly the pe
PMID 26095750

An Ultimate Stereocontrol in Asymmetric Synthesis of Optically Pure Fully Aromatic Helicenes.

Šámal M1, Chercheja S1, Rybáček J1, Vacek Chocholoušová J1, Vacek J1, Bednárová L1, Šaman D1, Stará IG1, Starý I1.
Journal of the American Chemical Society.J Am Chem Soc.2015 Jul 8;137(26):8469-74. doi: 10.1021/jacs.5b02794. Epub 2015 May 18.
The role of the helicity of small molecules in enantioselective catalysis, molecular recognition, self-assembly, material science, biology, and nanoscience is much less understood than that of point-, axial-, or planar-chiral molecules. To uncover the envisaged potential of helically chiral polyarom
PMID 25928194

Japanese Journal

Multiple Absolute Stereocontrol in Pd-Catalyzed [3+2] Cycloaddition of Oxazolidinones and Trisubstituted Alkenes Using Chiral Ammonium–Phosphine Hybrid Ligands

Bulletin of the Chemical Society of Japan advpub(0), 2016
NAID 130005131580

ドミノ型ラジカル閉環反応の開発研究

有機合成化学協会誌 73(9), 895-901, 2015
NAID 130005104060

分子内<i>C</i>-グリコシル化反応を利用したPolygalolide Aの全合成

有機合成化学協会誌 73(6), 607-615, 2015
NAID 130005088786

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