| Polycarbonate |
Repeating chemical structure unit of
Polycarbonate made from bisphenol A
|
| Physical Properties |
| Density (ρ) |
1.20–1.22 g/cm3 |
| Abbe number (V) |
34.0 |
| Refractive index (n) |
1.584–1.586 |
| Flammability |
V0-V2 |
| Limiting oxygen index |
25–27% |
| Water absorption – Equilibrium(ASTM) |
0.16–0.35% |
| Water absorption – over 24 hours |
0.1% |
| Radiation resistance |
Fair |
| Ultraviolet (1-380nm) resistance |
Fair |
| Mechanical Properties |
| Young's modulus (E) |
2.0–2.4 GPa |
| Tensile strength (σt) |
55–75 MPa |
| Compressive strength (σc) |
>80 MPa |
| Elongation (ε) @ break |
80–150% |
| Poisson's ratio (ν) |
0.37 |
| Hardness – Rockwell |
M70 |
| Izod impact strength |
600–850 J/m |
| Notch test |
20–35 kJ/m2 |
| Abrasive resistance – ASTM D1044 |
10–15 mg/1000 cycles |
| Coefficient of friction (μ) |
0.31 |
| Speed of sound |
2270 m/s |
| Thermal Properties |
| Melting temperature (Tm) |
155 °C |
| Glass transition temperature(Tg) |
147 °C |
| Heat deflection temperature – 10 kN (Vicat B)[citation needed] |
145 °C |
| Heat deflection temperature – 0.45 MPa |
140 °C |
| Heat deflection temperature – 1.8 MPa |
128–138 °C |
| Upper working temperature |
115–130 °C |
| Lower working temperature |
−40 °C[1] |
| Linear thermal expansion coefficient (α) |
65–70 × 10−6/K |
| Specific heat capacity (c) |
1.2–1.3 kJ/(kg·K) |
| Thermal conductivity (k) @ 23 °C |
0.19–0.22 W/(m·K) |
| Thermal diffusivity (a) @ 25 °C |
0.144 mm²/s [2] |
| Electrical Properties |
| Dielectric constant (εr) @ 1 MHz |
2.9 |
| Permittivity (ε) @ 1 MHz |
2.568 × 10−11 F/m |
| Relative permeability (μr) @ 1 MHz |
0.866(2) |
| Permeability (μ) @ 1 MHz |
1.089(2) μN/A2 |
| Dielectric strength |
15–67 kV/mm |
| Dissipation factor @ 1 MHz |
0.01 |
| Surface resistivity |
1015 Ω/sq |
| Volume resistivity (ρ) |
1012–1014 Ω·m |
| Near to Short-wave Infrared Transmittance Spectrum |
IR transmittance of polycarbonate. Also, polycarbonate is almost completely transparent throughout the entire visible region until 400 nm, blocking UV light.
|
| Chemical Resistance |
| Acids – concentrated |
Poor |
| Acids – dilute |
Good |
| Alcohols |
Good |
| Alkalis |
Good-Poor |
| Aromatic hydrocarbons |
Poor |
| Greases & Oils |
Good-fair |
| Halogenated Hydrocarbons |
Good-poor |
| Halogens |
Poor |
| Ketones |
Poor |
| Gas permeation @ 20 °C |
| Nitrogen |
10 – 25 cm3·mm/(m2·day·Bar) |
| Oxygen |
70 – 130 cm3·mm/(m2·day·Bar) |
| Carbon dioxide |
400 – 800 cm3·mm/(m2·day·Bar) |
| Water vapour |
1–2 gram·mm/(m2·day) @ 85%–0% RH gradient |
| Economic Properties |
| Price |
2.6 – 2.8 €/kg[3] |
Polycarbonates (PC), known by the trademarked names Lexan, Makrolon, Makroclear and others, are a particular group of thermoplastic polymers. They are easily worked, molded, and thermoformed. Because of these properties, polycarbonates find many applications. Polycarbonates do not have a unique resin identification code and are identified as Other, 7.
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Contents
- 1 Structure
- 2 Production
- 3 Properties and processing
- 4 Applications
- 4.1 Electronic components
- 4.2 Construction materials
- 4.3 Data storage
- 4.4 Automotive, aircraft, and security components
- 4.5 Niche applications
- 4.5.1 Medical applications
- 5 Manufacturers and brands
- 6 History
- 7 Potential hazards in food contact applications
- 8 See also
- 9 References
|
Structure [edit]
Polycarbonates received their name because they are polymers containing carbonate groups (–O–(C=O)–O–). Most polycarbonates of commercial interest are derived from rigid monomers. A balance of useful features including temperature resistance, impact resistance and optical properties position polycarbonates between commodity plastics and engineering plastics.
Production [edit]
The main polycarbonate material is produced by the reaction of bisphenol A (BPA) and phosgene COCl2. The overall reaction can be written as follows:
The first step of the synthesis involves treatment of bisphenol A with sodium hydroxide, which deprotonates the hydroxyl groups of the bisphenol A.[4]
- (HOC6H4)2CMe2 + 2 NaOH → (NaOC6H4)2CMe2 + 2 H2O
The diphenoxide ((NaOC6H4)2CMe2) reacts with phosgene to give a chloroformate, which subsequently is attacked by another phenoxide. The net reaction from the diphenoxide is:
- (NaOC6H4)2CMe2 + COCl2 → 1/n [OC(OC6H4)2CMe2]n + 2 NaCl
In this way, approximately one billion kilograms of polycarbonate is produced annually. Many other diols have been tested in place of bisphenol A, e.g. 1,1-bis(4-hydroxyphenyl)cyclohexane and dihydroxybenzophenone. The cyclohexane is used as a comonomer to suppress crystallisation tendency of the BPA-derived product. Tetrabromobisphenol A is used to enhance fire resistance. Tetramethylcyclobutanediol has been developed as a replacement for BPA.[4]
An alternative route to polycarbonates entails transesterification from BPA and diphenyl carbonate:
- (HOC6H4)2CMe2 + (C6H5O)2CO → 1/n [OC(OC6H4)2CMe2]n + 2 C6H5OH
The diphenyl carbonate was derived in part from carbon monoxide, this route being greener than the phosgene method.[4]
Properties and processing [edit]
Polycarbonate is a durable material. Although it has high impact-resistance, it has low scratch-resistance and so a hard coating is applied to polycarbonate eyewear lenses and polycarbonate exterior automotive components. The characteristics of polycarbonate are quite like those of polymethyl methacrylate (PMMA, acrylic), but polycarbonate is stronger and usable over a greater temperature range. Polycarbonate is highly transparent to visible light, with better light transmission than many kinds of glass.
Polycarbonate has a glass transition temperature of about 147 °C (297 °F),[5] so it softens gradually above this point and flows above about 155 °C (311 °F).[6] Tools must be held at high temperatures, generally above 80 °C (176 °F) to make strain- and stress-free products. Low molecular mass grades are easier to mold than higher grades, but their strength is lower as a result. The toughest grades have the highest molecular mass, but are much more difficult to process.
Unlike most thermoplastics, polycarbonate can undergo large plastic deformations without cracking or breaking. As a result, it can be processed and formed at room temperature using sheet metal techniques, such as bending on a brake. Even for sharp angle bends with a tight radius, heating may not be necessary. This makes it valuable in prototyping applications where transparent or electrically non-conductive parts are needed, which cannot be made from sheet metal. Note that PMMA/Plexiglas, which is similar in appearance to polycarbonate, is brittle and cannot be bent at room temperature.
Main transformation techniques for polycarbonate resins:
- extrusion into tubes, rods and other profiles including multiwall
- extrusion with cylinders (calenders) into sheets (0.5–20 mm (0.020–0.79 in)) and films (below 1 mm (0.039 in)), which can be used directly or manufactured into other shapes using thermoforming or secondary fabrication techniques, such as bending, drilling, routing, laser cutting etc.
- injection molding into ready articles
A bottle made from polycarbonate
Applications [edit]
Electronic components [edit]
Polycarbonate is mainly used for electronic applications that capitalize on its collective safety features. Being a good electrical insulator and having heat resistant and flame retardant properties, it is used in various products associated with electrical and telecommunications hardware. It can also serve as dielectric in high stability capacitors.[4] However, commercial manufacture of polycarbonate capacitors has mostly ceased following the decision of Bayer AG to discontinue production of capacitor-grade polycarbonate film at the end of 2000.[7]
Construction materials [edit]
Polycarbonate sheeting in a greenhouse
The second largest consumer of polycarbonates is the construction industry, e.g. for domelights, flat or curved glazing, and sound walls.
Data storage [edit]
A major application of polycarbonate is the production of Compact Discs, DVDs, and Blu-ray Discs. These discs are produced by injection molding polycarbonate into a mold cavity that has on one side a metal stamper containing a negative image of the disc data, while the other mold side is a mirrored surface. Typical products of sheet/film production include applications in advertisement (signs, displays, poster protection).[4]
Automotive, aircraft, and security components [edit]
In the automotive industry, injection-molded polycarbonate can produce very smooth surfaces that make it well-suited for direct (without the need for a basecoat) metalised parts such as decorative bezels and optical reflectors. Its uniform mold shrinkage results in parts with greater accuracy than those made of polypropylene. However, due to its susceptibility to environmental stress cracking, its use is limited to low-stress applications. It can be laminated to make bullet-proof "glass", although "bullet-resistant" is more accurate for the thinner windows, such as are used in bullet-resistant windows in automobiles. The thicker barriers of transparent plastic used in teller's windows and barriers in banks are also polycarbonate.
So-called "theft-proof" large plastic packaging for smaller items, which cannot be opened by hand, is uniformly made from polycarbonate.
The cockpit canopy of the F-22 Raptor jet fighter is made from a piece of high optical quality polycarbonate, and is the largest piece of its type formed in the world.[8][9]
South African security companies have launched the 'transparent burglar bar' under a variety of retail names, made from polycarbonate.[10]
Niche applications [edit]
Polycarbonate, being a versatile material with attractive processing and physical properties, has attracted myriad smaller applications. The use of injection molded drinking bottles, glasses and food containers is common, but the use of BPA in the manufacture of polycarbonate has stirred serious controversy (see Potential hazards in food contact applications), leading to development and use of "BPA-free" plastics in various formulations.
Laboratory safety goggles
Polycarbonate is commonly used in eye protection, as well as in other projectile-resistant viewing and lighting applications that would normally indicate the use of glass, but require much higher impact-resistance. Many kinds of lenses are manufactured from polycarbonate, including automotive headlamp lenses, lighting lenses, sunglass/eyeglass lenses, swimming and SCUBA goggles, and safety glasses/goggles/visors including visors in sporting helmets/masks and police riot gear. Windscreens in small motorized vehicles are commonly made of polycarbonate, such as for motorcycles, ATVs, golf carts, and small planes and helicopters.
The light weight of polycarbonate as opposed to glass has led to development of electronic display screens that replace glass with polycarbonate, for use in mobile and portable devices. Such displays include newer e-ink and some LCD screens, though CRT, plasma screen and other LCD technologies generally still require glass for its higher melting temperature and its ability to be etched in finer detail.
As more and more governments are restricting the use of glass in pubs and clubs[11] due to the increased incidence of glassings, polycarbonate glasses[12] are becoming popular for serving alcohol because of their strength, durability, and glass-like feel.
Other miscellaneous items include durable, lightweight luggage, MP3/digital audio player cases, ocarinas, computer cases, riot shields, instrument panels, tealight candle containers and blender jars. Many toys and hobby items are made from polycarbonate parts, e.g. fins, gyro mounts, and flybar locks for use with radio-controlled helicopters.[13]
For use in applications exposed to weathering or UV-radiation, a special surface treatment is needed. This either can be a coating (e.g. for improved abrasion resistance), or a coextrusion for enhanced weathering resistance.
Polycarbonate is also used as a printing substrate for nameplate and other forms of industrial grade under printed products. The polycarbonate provides a barrier to wear, the elements, and fading.
Medical applications [edit]
Many polycarbonate grades are used in medical applications and comply with both ISO 10993-1 and USP Class VI standards (occasionally referred to as PC-ISO). Class VI is the most stringent of the six USP ratings. These grades can be sterilized using steam at 120 °C, gamma radiation, or by the ethylene oxide (EtO) method.[14] However, scientific research indicates possible problems with biocompatibility. Dow Chemical strictly limits all its plastics with regard to medical applications.[15][16]
Manufacturers and brands [edit]
| Manufacturer |
Brand |
|
Manufacturer |
Brand |
| Sabic |
LEXAN® |
Bayer |
MAKROLON® |
| Teijin |
PANLITE® |
Styron |
CALIBRE® |
| Mitsubishi |
IUPILON® |
Idemitsu |
TARFLON® |
| Chi Mei |
WONDERLITE® |
Honam |
HOPELEX® |
| Cheil |
INFINO® |
LG |
LUPOY® |
| Samyang |
TRIREX® |
Kazanorgsintez |
MAPKA® |
| PCCI (KZPC) |
|
Unigel |
DURALON® |
History [edit]
The polycarbonate derived from BPA was discovered at Bayer by Dr. Herman Schnell in 1953 and soon at General Electric by Daniel Fox. It was first introduced to the market in 1958 by Bayer Mobay, and General Electric.[4]
Potential hazards in food contact applications [edit]
Main articles: Bisphenol A and Endocrine disruptor
The use of polycarbonate containers for the purpose of food storage is controversial. The basis of this controversy is their hydrolysis (degradation by water, often referred to as leaching) occurring at high temperature, releases bisphenol A:
- 1/n [OC(OC6H4)2CMe2]n + H2O → (HOC6H4)2CMe2 + CO2
More than 100 studies have explored the bioactivity of bisphenol A derived from polycarbonates. Bisphenol A appeared to be released from polycarbonate animal cages into water at room temperature and it may have been responsible for enlargement of the reproductive organs of female mice.[17] However, the animal cages used in the research were fabricated from industrial grade polycarbonate, rather than FDA food grade polycarbonate.
An analysis of the literature on bisphenol A leachate low-dose effects by vom Saal and Hughes published in August 2005 seems to have found a suggestive correlation between the source of funding and the conclusion drawn. Industry funded studies tend to find no significant effects whereas government funded studies tend to find significant effects.[18]
Sodium hypochlorite bleach and other alkali cleaners catalyze the release of the bisphenol A from polycarbonate containers.[19][20] A chemical compatibility chart shows that polycarbonate is incompatible with ammonia and acetone because it dissolves in their presence.[21] Alcohol is one recommended organic solvent for cleaning grease and oils from polycarbonate.
See also [edit]
- Bioplastic
- CR-39
- Organic electronics
- Vapor polishing
References [edit]
- ^ M. Parvin and J. G. Williams (1975). "The effect of temperature on the fracture of polycarbonate". Journal of Materials Science 10 (11): 1883. doi:10.1007/BF00754478.
- ^ J. Blumm, A. Lindemann (2003/2007). "Characterization of the thermophysical properties of molten polymers and liquids using the flash technique". High Temperatures-High Pressures. 35/36 (6): 627. doi:10.1068/htjr144.
- ^ CES Edupack 2010, Polycarbonate (PC) specs sheet
- ^ a b c d e f Volker Serini "Polycarbonates" in Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim, 2000. doi:10.1002/14356007.a21_207
- ^ Answers to Common Questions about Bayer Polycarbonate Resins
- ^ City Plastics Polycarbonate
- ^ Film Capacitors
- ^ Egress technicians keep raptor pilots covered. Pacaf.af.mil. Retrieved on 2011-02-26.
- ^ F-22 Cockpit. Globalsecurity.org (2008-01-21). Retrieved on 2011-02-26.
- ^ [1]. Retrieved on 2012-06-28.
- ^ http://www.olgr.nsw.gov.au/alcohol_restrictions_for_violent_venues.asp, http://www.olgr.qld.gov.au/industry/liquor_compliance/glass_bans/index.shtml
- ^ http://polysafe.com.au/
- ^ Hobby Applications of Polycarbonate
- ^ Medical Applications of Polycarbonate
- ^ "Dow Plastics Medical Application Policy".
- ^ "Makrolon Polycarbonate Biocompatibility Grades".
- ^ Howdeshell, KL; Peterman PH, Judy BM, Taylor JA, Orazio CE, Ruhlen RL, Vom Saal FS, Welshons WV (2003). "Bisphenol A is released from used polycarbonate animal cages into water at room temperature". Environmental Health Perspectives 111 (9): 1180–7. doi:10.1289/ehp.5993. PMC 1241572. PMID 12842771. Retrieved 2006-06-07.
- ^ vom Saal FS, Hughes C (2005). "An extensive new literature concerning low-dose effects of bisphenol A shows the need for a new risk assessment". Environ. Health Perspect. 113 (8): 926–33. doi:10.1289/ehp.7713. PMC 1280330. PMID 16079060.
- ^ Hunt, PA; Kara E. Koehler, Martha Susiarjo, Craig A. Hodges, Arlene Ilagan, Robert C. Voigt, Sally Thomas, Brian F. Thomas and Terry J. Hassold (2003). "Bisphenol A Exposure Causes Meiotic Aneuploidy in the Female Mouse". Current Biology 13 (7): 546–553. doi:10.1016/S0960-9822(03)00189-1. PMID 12676084.
- ^ Koehler, KE; Robert C. Voigt, Sally Thomas, Bruce Lamb, Cheryl Urban, Terry Hassold, and Patricia A. Hunt (2003). "When disaster strikes: rethinking caging materials". Lab Animal 32 (4): 24–27. doi:10.1038/laban0403-24. PMID 19753748.
- ^ Premium Twinwall and Triplewall Polycarbonate Sheet by Verolite
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Plastics
|
|
- Acrylonitrile butadiene styrene (ABS)
- Cross-linked polyethylene (PEX, XLPE)
- Ethylene vinyl acetate (EVA)
- Poly(methyl methacrylate) (PMMA)
- Polyacrylic acid (PAA)
- Polyamide (PA)
- Polybutylene (PB)
- Polybutylene terephthalate (PBT)
- Polycarbonate (PC)
- Polyester (PEs)
- Polyethylene (PE)
- Polyethylene terephthalate (PET, PETE)
- Polyimide (PI)
- Polylactic acid (PLA)
- Polyoxymethylene (POM)
- Polyphenyl ether (PPE)
- Polypropylene (PP)
- Polystyrene (PS)
- Polysulfone (PES)
- Polytetrafluoroethylene (PTFE)
- Polyurethane (PU)
- Polyvinyl chloride (PVC)
- Polyvinylidene chloride (PVDC)
- Styrene maleic anhydride (SMA)
- Styrene-acrylonitrile (SAN)
|
|
|
Health issues of plastics and Polyhalogenated compounds (PHCs)
|
|
| Plasticizers: Phthalates |
- DIBP
- DBP
- BBP (BBzP)
- DIHP
- DEHP (DOP)
- DIDP
- DINP
|
|
| Miscellaneous plasticizers |
- Organophosphates
- Adipates (DEHA
- DOA)
|
|
| Monomers |
- Bisphenol A (BPA, in Polycarbonates)
- Vinyl chloride (in PVC)
|
|
| Miscellaneous additives incl. PHCs |
- PBDEs
- PCBs
- Organotins
- PFCs
|
|
| Health issues |
- Teratogen
- Carcinogen
- Endocrine disruptor
- Diabetes
- Obesity
|
|
| Miscellanea |
- PVC
- Plastic recycling
- Plastic bottle
- Vinyl chloride
- Dioxins
- Polystyrene
- Foam food container
- PTFE (Teflon)
- California Proposition 65
- List of environmental health hazards
- Persistent organic pollutant
- European REACH regulation
- Japan Toxic Substances Law
- Toxic Substances Control Act
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