ピクリン酸、(化合物)クリン酸塩
- 関
- picric acid
Wikipedia preview
出典(authority):フリー百科事典『ウィキペディア(Wikipedia)』「2015/11/04 23:15:07」(JST)
[Wiki en表示]
A picrate is a salt or an ester of picric acid (a 2,4,6-trinitrophenol). But it could also be an additional compound which picric acid forms with many aromatic hydrocarbons, aromatic amines, aliphatic amines, alkalines, and other compounds.[1] These additional compounds are also called picrates even though they are not a salt of picric acid.
The picrate ion has yellow color. Many picrates are explosives, for example ammonium picrate (known as Dunnite). Some are used as primary explosives, namely lead picrate or potassium picrate which find their use as primers for cartridge ammunition.
Ferrous picrate is used in some applications as a diesel fuel additive to achieve better mileage.
Sodium picrate is used as an etchant in metallography to differ preeutectoid ferrite in hypoeutectoid steel from preeutectoid cementite in hypereutectoid steel by etching cementite to a dark colour, whereas not attacking ferrite and thus it remains reflective.
Picrates of some metals tend to be significantly more sensitive to impact, friction and shock than picric acid itself. As a result, storage of picric acid (or mixtures containing it) in metal containers is strongly discouraged due to the high risk of accidental explosion.
References
- ^ Smith, M. B.; March, J. (2007). March's Advanced Organic Chemistry (6th ed.). John Wiley & Sons. p. 118. ISBN 978-0-471-72091-1.
UpToDate Contents
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English Journal
- Tetracoordinate Imidazole-Based Boron Complexes for the Selective Detection of Picric Acid.
- Dhanunjayarao K1, Mukundam V1, Venkatasubbaiah K1.
- Inorganic chemistry.Inorg Chem.2016 Oct 11. [Epub ahead of print]
- N,N-Dimethylamine and N,N-diphenylamine-decorated highly fluorescent imidazole borates have been synthesized and investigated as new fluorophores for the selective detection of trinitrophenol/picric acid (PA). Structural studies of a probe 1 and PA (1·PA) complex revealed that the adduct formed by
- PMID 27726346
- Distribution and Adsorption of Ionic Species into a Liposome Membrane and Their Dependence upon the Species and Concentration of a Coexisting Counterion.
- Murakami K1, Hori K1, Maeda K1, Fukuyama M1, Yoshida Y1.
- Langmuir : the ACS journal of surfaces and colloids.Langmuir.2016 Oct 10. [Epub ahead of print]
- The distribution of ions into a bilayer lipid membrane (BLM) and their adsorption on the BLM are investigated by extracting a hydrophobic cation, rhodamine 6G (R6G+), into a liposome through the dialysis membrane method. R6G+ distribution mainly depends upon the concentration of the coexisting anion
- PMID 27687781
- A Multiresponsive Regenerable Europium-Organic Framework Luminescent Sensor for Fe3+, CrVI anions and Picric Acid.
- Liu W1, Huang X2, Xu C3, Chen C4, Yang L5, Dou W6, Chen W7, Yang H8, Liu W9.
- Chemistry (Weinheim an der Bergstrasse, Germany).Chemistry.2016 Oct 6. doi: 10.1002/chem.201603607. [Epub ahead of print]
- A novel luminescence microporous lanthanide metal-organic framework (Ln-MOF) based on urea containing ligand was successfully assembled. The structural analyses indicate that the framework exhibited two types of 1D channels and with N-H urea bonds projecting into pores. The luminescence studies reve
- PMID 27709697
Japanese Journal
- Extraction Properties of p-Methyloxacalix[3]arene Methyl Ether for Alkali Metal Ions
- KANAYA Naoki,MATSUHASHI Shumpei,KATSUTA Shoichi
- Solvent Extraction Research and Development, Japan 22(1), 17-24, 2015
- … From extraction equilibrium analysis, MOC3A-Me (L) was found to extract each alkali metal picrate (M+A−) by the reaction M+w + Lo + A−w⇄ ML+A−o, where subscripts 'o' and 'w' denote the organic and aqueous phases, respectively. …
- NAID 130005071505
- Rapid and Precise Coulometric Determination and Separation of Redox Inert Ions Based on Electrolysis for Ion Transfer at the Aqueous Organic Solution Interface
- Kihara Sorin,Kasuno Megumi
- Analytical sciences : the international journal of the Japan Society for Analytical Chemistry 27(1), 1-11, 2011-01-10
- … The coulometric determination can be performed with an efficiency of more than 99% and a precision of better than 0.2% based on the ion transfer under an optimum condition, even if the ion is redox inert such as Na+, K+, Mg2+, Ca2+, ClO4−, picrate or alkylsulfonates. …
- NAID 10027739379
- Ion-pair Formation between Cd(II), Na(I), and Ag(I) Complex Ions with 18-Crown-6 Ether Derivatives and Various Pairing Anions in Water: an Understanding of the Ion-pair Formation Based on the HSAB Principle
- KUDO Yoshihiro,KOIDE Tsukasa,ZHAO Yujie,KATSUTA Shoichi,TAKEDA Yasuyuki
- Analytical Sciences 27(12), 1207, 2011
- … Using the log KCdLX0 values of CdLCl+, CdLBr+, CdLPic+, and CdLSO4, then CdL2+ and picrate ion (Pic−) in water have been classified with the hard and soft acids and bases principle, where the values were available in the literature, except for CdLBr+. …
- NAID 130004827074
Related Links
- 世界大百科事典 第2版 - picrateの用語解説 - また有機塩基とは付加化合物の塩を,芳香族炭化水素とは分子化合物をつくる。これらの塩をピクラートpicrateと総称する。ピクリン酸はフェノールのスルホン化とそれに続く脱スルホン酸 ...
- Picrate definition, a salt or ester of picric acid. See more. Dictionary.com Word of the Day Translate Games Blog Thesaurus.com Apps Favorites Log Out Log In follow Dictionary.com Dictionary.com Thesaurus.com My Account ...
★リンクテーブル★
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- 英
- picric acid、picrate
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- ピクリン酸塩
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- 英
- picrate
- 関
- ピクリン酸
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ピクリン酸
- 関
- picrate