アミドクロライド水銀
WordNet
- of or containing mercury (同)mercurous
PrepTutorEJDIC
- (特に)第二水銀の(を含んだ)
Wikipedia preview
出典(authority):フリー百科事典『ウィキペディア(Wikipedia)』「2016/09/16 22:09:33」(JST)
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Mercuric amidochloride
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Names |
IUPAC name
mercuric azanide chloride
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Other names
mercuric amidochloride
mercury(II) amide chloride
mercury(II) amidochloride
ammoniated mercury
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Identifiers |
CAS Number
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10124-48-8 Y |
ChemSpider |
21106343 Y |
Jmol 3D model |
Interactive image |
PubChem |
3032553 |
UNII |
JD546Z56F0 N |
InChI
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InChI=1S/ClH.Hg.H2N/h1H;;1H2/q;+2;-1/p-1 Y
Key: WRWRKDRWMURIBI-UHFFFAOYSA-M Y
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InChI=1/ClH.Hg.H2N/h1H;;1H2/q;+2;-1/p-1/rClH2HgN/c1-2-3/h3H2
Key: WRWRKDRWMURIBI-CUFRCDTJAQ
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Properties |
Chemical formula
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ClH2HgN |
Molar mass |
252.065 g/mol |
Density |
5.56 g/cm3 |
Pharmacology |
ATC code
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D08AK01 (WHO) |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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N verify (what is YN ?) |
Infobox references |
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Mercuric amidochloride is an inorganic compound with the formula HgNH2Cl. It consists of a zig-zag 1-dimensional polymer (HgNH2)n with chloride counterions.[1][2] It arises from the reaction of ammonia and mercuric chloride. Addition of base converts it into "Millon's base," which has the formula [Hg2N]OH(H2O)x. A variety of related amido and nitrido materials with chloride, bromide, and hydroxide are known.[3]
Before the toxicity of mercury was appreciated, mercuric amidochloride, known as "ammoniated mercury", was used as a topical antiseptic and disinfectant.[4][5]
Eli Lilly & Company - Ointment No. 8 - Ammoniated Mercury 10%
See also
- Merbromin, also known as "Mercurochrome", another antiseptic mercury compound
- Thiomersal, another antiseptic mercury compound
References
- ^ Wells, A.F. (1984). Structural Inorganic Chemistry. Oxford: Clarendon Press. ISBN 0-19-855370-6. [page needed]
- ^ Lipscomb, W. N. (1951). "The structure of mercuric amidochloride, HgNH2Cl". Acta Crystallographica. 4 (3): 266–8. doi:10.1107/S0365110X51000866.
- ^ Holleman, A. F.; Wiberg, E. (2001). Inorganic Chemistry. San Diego: Academic Press. ISBN 0-12-352651-5. [page needed]
- ^ Aberer W, Gerstner G, Pehamberger H (September 1990). "Ammoniated mercury ointment: outdated but still in use". Contact Dermatitis. 23 (3): 168–71. doi:10.1111/j.1600-0536.1990.tb04778.x. PMID 2149317.
- ^ http://www.huidziekten.nl/allergie/stoffen/mercury-ammonium-chloride.htm[full citation needed]
Mercury compounds
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Mercury(I) |
- HgH
- Hg2H2
- Hg2Br2
- Hg2Cl2
- Hg2F2
- Hg2I2
- Hg2(NO3)2
- Hg2O
- Hg2CO3
- Hg2SO4
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Mercury(II) |
- HgH2
- HgNH2Cl
- HgSe
- HgS
- HgTe
- Hg(O2CCH3)2
- HgBr2
- HgCl2
- Hg(CN)2
- HgF2
- Hg(OH)2
- HgI2
- Hg(NO3)2
- HgO
- HgSO4
- Hg(SCN)2
- Hg(CNO)2
- Hg3N2
- Hg(Si(CH3)3)2
- K2HgI4
Organomercury
compounds
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- Hg(CH3)2
- Hg(C2H5)2
- Hg(C6H5)2
- HgC6H5CH3CO2
- HgC6H5OB(OH)2
- HgClC6H4CO2H
- HgOHCH2CHOCH3CH2(NHCO)2C2H4CO2H
- HgOHCH2CHOCH3CH2NHCOC6H4OCH2CO2H
- Na2HgOHC6HOBrC6H2OBrOCHC6H4CO2
- HgOC6H2CH3NO2
- NaHgC2H5SC6H4CO2
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Mercury(IV) |
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Amalgams |
- Na(Hg)
- Al(Hg)
- K(Hg)
- Au(Hg)
- Tl(Hg)
- Sn(Hg)
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Mercury cations |
- Hg2+
- Hg4+
- Hg22+
- Hg32+
- Hg42+
- Hg34+
- HgCH3+
- HgC2H5+
- HgC6H5+
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UpToDate Contents
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English Journal
- A novel optical DNA biosensor for detection of trace amounts of mercuric ions using gold nanoparticles introduced onto modified glass surface.
- Mashhadizadeh MH1, Talemi RP2.
- Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy.Spectrochim Acta A Mol Biomol Spectrosc.2014 Nov 11;132:403-9. doi: 10.1016/j.saa.2014.04.146. Epub 2014 May 16.
- In this work we report a DNA spectrophotometric biosensor for detection of Hg(2+) ions in which a pair of oligonucleotides with four thymine-thymine (T-T) mismatched bases was immobilized onto modified glass surface. Firstly, glass surface modified with 3-(mercaptopropyl) trimethoxysilane (MSPT) and
- PMID 24887502
- Electronic structure calculations of mercury mobilization from mineral phases and photocatalytic removal from water and the atmosphere.
- Da Pieve F1, Stankowski M2, Hogan C3.
- The Science of the total environment.Sci Total Environ.2014 Sep 15;493:596-605. doi: 10.1016/j.scitotenv.2014.06.012. Epub 2014 Jun 28.
- Mercury is a hazardous environmental pollutant mobilized from natural sources, and anthropogenically contaminated and disturbed areas. Current methods to assess mobility and environmental impact are mainly based on field measurements, soil monitoring, and kinetic modelling. In order to understand in
- PMID 24982025
- Irreversible inhibitory kinetics of mercuric ion on N-acetyl-β-d-glucosaminidase from Nile tilapia (Oreochromis niloticus).
- Zhang WN1, Chen QX2, Lin XY1, Huang XH3, Huang YF4.
- Aquatic toxicology (Amsterdam, Netherlands).Aquat Toxicol.2014 Sep;154:163-7. doi: 10.1016/j.aquatox.2014.05.018. Epub 2014 May 22.
- N-acetyl-β-d-glucosaminidase (EC 3.2.1.52, NAGase), hydrolyzes dimers or trimers of N-acetyl-β-d-glucosamine (NAG) into monomers and is shown to be important for the reproduction of male animals. NAGase is purified from the spermary of Nile tilapia, and its enzyme activity can be strongly inhibite
- PMID 24907676
Related Links
- Editor-In-Chief: C. Michael Gibson, M.S., M.D. Overview Mercuric amidochloride is an inorganic compound with the formula HgNH 2 Cl. It consists of a zig-zag 1-dimensional polymer (HgNH 2) n with chloride counterions. It arises ...
- Quote: Mercuric amidochloride is an inorganic compound with the formula HgNH2Cl. It consists of a zig-zag 1-dimensional polymer (HgNH2)n with chloride counterions. It arises from the reaction of ammonia and mercuric chloride.
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★リンクテーブル★
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- 英
- mercuric amidochloride
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- 関
- Hg、mercurial、mercury