- 関
- half-cell
WordNet
- partially or to the extent of a half; "he was half hidden by the bushes"
- one of two divisions into which some games or performances are divided: the two divisions are separated by an interval
- (of siblings) related through one parent only; "a half brother"; "half sister"
- consisting of one of two equivalent parts in value or quantity; "a half chicken"; "lasted a half hour"
- partial; "gave me a half smile"; "he did only a half job"
- small room in which a monk or nun lives (同)cubicle
- a device that delivers an electric current as the result of a chemical reaction (同)electric cell
- a room where a prisoner is kept (同)jail cell, prison cell
- (biology) the basic structural and functional unit of all organisms; they may exist as independent units of life (as in monads) or may form colonies or tissues as in higher plants and animals
- any small compartment; "the cells of a honeycomb"
- a small unit serving as part of or as the nucleus of a larger political movement (同)cadre
PrepTutorEJDIC
- 〈C〉〈U〉『半分』,2分の1;約半分 / 〈U〉《時刻を表す数詞と共に用いて》『半』,30分 / 〈C〉《おもに英》(2学期制の学校での)前(後)期 / 〈C〉(競技などの)前(後)半;(野球で1イニングの)表(裏) / 〈C〉=halfback / 『半分の』 / 不十分な,中途はんぱな / 『半ば』,半分[だけ] / 半時間だけ,30分だけ / 不完全に / かなり,ほとんど
- (刑務所の)『独房』;(修道院の)小さい独居室 / (ミツバチの)みつ房,巣穴 / 小さい部屋 / 『細胞』 / 電池 / 花粉室 / (共産党などの)細胞
- おや,はああ,ああ(驚き・喜び・疑い・ためらいなどを表す声)
- hectare; hectares
Wikipedia preview
出典(authority):フリー百科事典『ウィキペディア(Wikipedia)』「2014/06/28 03:05:15」(JST)
[Wiki en表示]
A half-cell is a structure that contains a conductive electrode and a surrounding conductive electrolyte separated by a naturally occurring Helmholtz double layer. Chemical reactions within this layer momentarily pump electric charges between the electrode and the electrolyte, resulting in a potential difference between the electrode and the electrolyte. The typical anode reaction involves a metal atom in the electrode dissolved and transported as a positive ion across the double layer, causing the electrolyte to acquire a net positive charge while the electrode acquires a net negative charge. The growing potential difference creates an intense electric field within the double layer, and the potential rises in value until the field halts the net charge-pumping reactions. This self-limiting action occurs almost instantly in an isolated half-cell; in applications two dissimilar half-cells are appropriately connected to constitute a Galvanic cell.
A standard half-cell, used in electrochemistry, consists of a metal electrode in a 1 molar (1 mol/L) aqueous solution of the metal's salt, at 298 kelvin (25 °C).[1] The electrochemical series, which consists of standard electrode potentials and is closely related to the reactivity series, was generated by measuring the difference in potential between the metal half-cell in a circuit with a standard hydrogen half-cell, connected by a salt bridge.
The standard hydrogen half-cell:
- 2H+(aq) + 2e- → H2(g)
The half-cells of a Daniell cell:
- Original equation
- Zn + Cu2+ → Zn2+ + Cu
- Half-cell (anode) of Zn
- Zn → Zn2+ + 2e−
- Half-cell (cathode) of Cu
- Cu2+ + 2e− → Cu
References
- ^ Andrews, Donald H.; Richard J. Kokes (1962). "Electrochemistry". Fundamental Chemistry. New York: John Wiley & Sons, Inc. p. 482.
Articles related to electrolysis / Standard electrode potential
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Electrolytic processes |
- Betts electrolytic process
- Castner process
- Castner–Kellner process
- Chloralkali process
- Downs cell
- Electrolysis of water
- Electrowinning
- Hall–Héroult process
- Hofmann voltameter
- Kolbe electrolysis
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Materials produced by electrolysis |
- Aluminium (extraction)
- Calcium metal
- Chlorine
- Copper
- Electrolysed water
- Fluorine
- Hydrogen
- Lithium metal
- Magnesium metal
- Potassium metal
- Sodium metal
- Sodium hydroxide
- Zinc
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See also |
- Electrochemistry
- Gas cracker
- Standard electrode potential (data page)
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Galvanic cells
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Types |
- Voltaic pile
- Battery
- Flow battery
- Trough battery
- Concentration cell
- Fuel cell
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Primary cell
(non-rechargable)
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- Alkaline
- Aluminium–air
- Bunsen
- Chromic acid
- Clark
- Daniell
- Dry
- Edison-Lalande
- Grove
- Leclanché
- Lithium
- Mercury
- Nickel oxyhydroxide
- Silicon–air
- Silver oxide
- Weston
- Zamboni
- Zinc–air
- Zinc–carbon
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Secondary cell
(rechargeable)
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- Automotive
- Lead–acid
- Lithium–air
- Lithium–ion
- Lithium polymer
- Lithium iron phosphate
- Lithium–sulfur
- Lithium titanate
- Nanowire
- Nickel–cadmium
- Nickel–hydrogen
- Nickel–iron
- Nickel–lithium
- Nickel–metal hydride
- Nickel–zinc
- Polysulfide bromide
- Potassium-ion
- Rechargeable alkaline
- Sodium-ion
- Sodium–sulfur
- Vanadium redox
- Zinc–bromine
- Zinc–cerium
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Cell parts |
- Anode
- Binder
- Catalyst
- Cathode
- Electrolyte
- Half-cell
- Ions
- Salt bridge
- Semipermeable membrane
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UpToDate Contents
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English Journal
- Sputum analysis: Non-invasive early lung cancer detection.
- D'Urso V, Doneddu V, Marchesi I, Collodoro A, Pirina P, Giordano A, Bagella L.SourceINT-CROM, Pascale Foundation National Cancer Institute, Cancer Research Center, Mercogliano, Italy.
- Journal of cellular physiology.J Cell Physiol.2013 May;228(5):945-51. doi: 10.1002/jcp.24263.
- Lung cancer is the leading cause of cancer-related deaths over the world, characterized by a very high mortality rate. Molecular technique development tries to focus on early detection of cancers by studying molecular alterations that characterize cancer cells. Worldwide lung cancer research has foc
- PMID 23086732
- Ultra-sensitive conductometric detection of heavy metals based on inhibition of alkaline phosphatase activity from Arthrospira platensis.
- Tekaya N, Saiapina O, Ben Ouada H, Lagarde F, Ben Ouada H, Jaffrezic-Renault N.SourceUniversity Lyon, Institut des Sciences Analytiques, CNRS/ENS/UCBL UMR 5280, Villeurbanne, France. tekayanadeje@yahoo.fr
- Bioelectrochemistry (Amsterdam, Netherlands).Bioelectrochemistry.2013 Apr;90:24-9. doi: 10.1016/j.bioelechem.2012.10.001. Epub 2012 Nov 7.
- This study is based on the conductometric measurement of alkaline phosphatase activity (APA) from the cyanobacterium, Arthrospira platensis, called Spirulina. Cyanobacterium cells were directly immobilized, by physical adsorption, on the ceramic part of gold interdigitated transducers. This activity
- PMID 23174485
- Intracellular delivery and antitumor effects of pH-sensitive liposomes based on zwitterionic oligopeptide lipids.
- Mo R, Sun Q, Li N, Zhang C.SourceCenter of Drug Discovery, State Key Laboratory of Natural Medicines, China Pharmaceutical University, Nanjing 210009, PR China.
- Biomaterials.Biomaterials.2013 Apr;34(11):2773-86. doi: 10.1016/j.biomaterials.2013.01.030. Epub 2013 Jan 23.
- pH-sensitive liposomes (HHG2C(18)-L and PEGHG2C(18)-L) based on zwitterionic oligopeptide lipids as anticancer drug carriers were developed and evaluated for effective intracellular delivery and enhanced antitumor activity. The amino acid-based lipids, 1,5-dioctadecyl-l-glutamyl 2-histidyl-hexahydro
- PMID 23352118
Japanese Journal
- 関口 善吉,滝沢 明利,竹島 徹平 [他]
- 泌尿器科紀要 58(9), 481-485, 2012-09
- … Histological examination revealed the presence of clear cell-type, G3, pT3b renal cell carcinoma. … We administered half of the previous dose of sunitinib 2 weeks after cessation of sunitinib therapy for complete resolution of the lung metastases. …
- NAID 40019429492
- Innovative antimicrobial coating of titanium implants with iodine
- Tsuchiya Hiroyuki,Shirai Toshiharu,Nishida Hideji,Murakami Hideki,Kabata Tamon,Yamamoto Norio,Watanabe Koji,Nakase Junsuke
- Journal of Orthopaedic Science 17(5), 595-604, 2012-09
- … White blood cell (WBCs) and C-reactive protein (CRP) levels were measured pre- and postoperatively in all patients. … The chronological changes of the iodine amount were evaluated using half pins removed after completion of external fixation. …
- NAID 120004966630
- Enhancement of Cycling Performance by Li2O--Sn Anode for All-Solid-State Batteries
- Jee Seung Hyun,Lee Seok Hee,Kim Dong-Joo,Kwak Ji-Yeon,Nam Sang-Cheol,Yoon Young Soo
- Jpn J Appl Phys 51(8), 085803-085803-7, 2012-08-25
- … A solid-state half-cell structure with a Sn--Li2O composite (SLC) anode/LiPON/Li was prepared to improve upon the cycling stability at the second discharging cycle of the non-Li anode thin films for all-solid-state batteries. … Based on the cycling behaviors of the all-solid half cell with SLC and pure Sn thin film electrodes at first and second discharging cycles, cycling stability at the initial charging--discharging cycle of the all-solid-state battery system was improved. …
- NAID 150000103787
Related Links
- Half-cell definition, a single electrode, generally a metal, immersed in a container filled with an electrolyte, and having a specific electrical potential for a given combination of electrode and electrolyte. See more. Dictionary.com ...
- Half-Cell definition, as used in chemistry, chemical engineering, and physics. ... Related Articles Salt Bridge Definition Concentration Cell Definition How Electrochemical Cells Work How to Identify the Anode and Cathode of a ...
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- halves
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細胞