- 関
- enantiomeric
English Journal
- Copper(I) Complexes of Pyridine-Bridged Phosphaalkene-Oxazoline Pincer Ligands.
- Serin SC1, Pick FS1, Dake GR1, Gates DP1.
- Inorganic chemistry.Inorg Chem.2016 Jul 5;55(13):6670-8. doi: 10.1021/acs.inorgchem.6b00917. Epub 2016 Jun 17.
- The synthesis of enantiomerically pure pyridine-bridged phosphaalkene-oxazolines ArP═C(Ph)(2,6-C5H3NOx) (1, Ar = Mes/Mes*, Ox = CNOCH(i-Pr)CH2/CNOCH(CH2Ph)CH2) is reported. This new ligand forms a κ(P), κ(2)(NN) dimeric complex with copper(I) (7) that dissociates into a cationic κ(3)(PNN) monom
- PMID 27315353
- First Atroposelective Total Synthesis of Enantiomerically Pure Ancistrocladidine and Ancistrotectorine.
- Bringmann G1, Manchala N2, Büttner T2, Hertlein-Amslinger B2, Seupel R2.
- Chemistry (Weinheim an der Bergstrasse, Germany).Chemistry.2016 Jul 4;22(28):9792-6. doi: 10.1002/chem.201600701. Epub 2016 Jun 6.
- The first regio- and stereoselective total synthesis of the axially chiral 7,3'-coupled naphthylisoquinoline alkaloids ancistrocladidine (1) and ancistrotectorine (2) has been described. Both possess a 7,3'-coupled axis, which before now, was difficult to attain synthetically. Moreover, target 2 has
- PMID 27273153
- Kinetic Resolution of Racemic and Branched Monosubstituted Allylic Acetates by a Ruthenium-Catalyzed Regioselective Allylic Etherification.
- Shinozawa T1, Terasaki S1, Mizuno S1, Kawatsura M1.
- The Journal of organic chemistry.J Org Chem.2016 Jul 1;81(13):5766-74. doi: 10.1021/acs.joc.6b00939. Epub 2016 Jun 20.
- We demonstrated the kinetic resolution of racemic and branched monosubstituted allylic acetates by a ruthenium-catalyzed regioselective allylic etherification. The reaction was effectively catalyzed by the chiral ruthenium catalyst, which was generated by [RuCl2(p-cymene)]2 and (S,S)-iPr-pybox and a
- PMID 27276556
Japanese Journal
- Combination of Novozym 435-catalyzed Enantioselective Hydrolysis and Amidation for the Preparation of Optically Active δ-Hexadecalactone
- Shimotori Yasutaka,Hoshi Masayuki,Miyakoshi Tetsuo
- Journal of Oleo Science 64(5), 561-575, 2015
- … A new enzymatic method for synthesis of enantiomerically enriched δ-hexadecalactone (3) based on the enzymatic kinetic resolution of N-methyl-5-acetoxyhexadecanamide (1) is described. …
- NAID 130005067210
- Asymmetric Synthesis of Ampelomin A and ent-Epiampelomin A
- Koyanagi Yuji,Hamada Toshiyuki,Iwagawa Tetsuo [他],Okamura Hiroaki
- Journal of Oleo Science 64(4), 449-454, 2015
- … The enantiomerically pure starting material was obtained by base-catalyzed asymmetric Diels–Alder reaction of 3-hydroxy-2-pyrone and chiral acrylate. …
- NAID 130005061329
- キラルカラムを用いたshikonin類の分析と、硬紫根、軟紫根におけるshikonin類の光学異性体比の特徴を利用した(R)-shikonin及び(S)-shikoninの効率的生産
- 松本 恵実,牧岡 富広,柳瀬 笑子,中塚 進一
- 日本食品化学学会誌 21(1), 65-71, 2014-04-25
- … We established an easy and efficient method for preparing enantiomerically pure (R)-shikonin and (S)-shikonin by removing low-enanntiopure acetylshikonin and β-hydroxyisovalerylshikonin from shikonins before the hydrolysis. …
- NAID 110009810367
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★リンクテーブル★
[★]
- 関
- chiral、chirality、enantiomer、enantiomerically、enantiomerism
[★]
- 英
- enantiomeric、enantiomerically
- 関
- エナンチオマー、鏡像異性