English Journal

Oxidovanadium Catechol Complexes: Radical versus Non-Radical States and Redox Series.

Kundu S, Maity S, Weyhermüller T, Ghosh P.SourceDepartment of Chemistry, R. K. Mission Residential College , Narendrapur, Kolkata-103, India.
Inorganic chemistry.Inorg Chem.2013 Jun 20. [Epub ahead of print]
A new family of oxidovanadium complexes, [(L1R)(VO)(LR')] (R = H, R' = H, 1; R = H, R' = -CMe3, 2; R = H, R' = Me, 3; R = -CMe3, R' = H, 4 and R = -CMe3, R' = -CMe3, 5), incorporating tridentate L1RH ligands (L1RH = 2,4-di-R-6-{(2-(pyridin-2-yl)hydrazono)methyl}phenol) and substituted catechols (LR'
PMID 23786369

Baranac-Stojanović M, Stojanović M.SourceFaculty of Chemistry, University of Belgrade, Studentski trg 12-16, PO Box 158 and Center for Chemistry ICTM, PO Box 473, 11000 Belgrade, Serbia. mbaranac@chem.bg.ac.rs
Chemistry (Weinheim an der Bergstrasse, Germany).Chemistry.2013 Mar 25;19(13):4249-54. doi: 10.1002/chem.201204267. Epub 2013 Feb 11.
Anisotropic effects are broadly used in NMR spectroscopy for structure elucidation. With the development of computational methods it has become possible to quantify the effects and obtain further insight into their origin. Some classical interpretations have been questioned. Herein, we show that the
PMID 23400889

Charge-pairing interactions control the conformational setpoint and motions of the FMN domain in neuronal nitric oxide synthase.

Haque MM, Bayachou M, Fadlalla MA, Durra D, Stuehr DJ.SourceDepartment of Pathobiology, Lerner Research Institute, The Cleveland Clinic, Cleveland, OH 44195, USA.
The Biochemical journal.Biochem J.2013 Mar 15;450(3):607-17. doi: 10.1042/BJ20121488.
The NOS (nitric oxide synthase; EC 1.14.13.39) enzymes contain a C-terminal flavoprotein domain [NOSred (reductase domain of NOS)] that binds FAD and FMN, and an N-terminal oxygenase domain that binds haem. Evidence suggests that the FMN-binding domain undergoes large conformational motions to shutt
PMID 23289611

Japanese Journal

NMR and DFT Study on Onium Ions Derived from Substituted Fluoranthenes and Benzo[k]fluoranthenes

Okazaki Takao,Adachi Taisuke,Kitagawa Toshikazu
Bulletin of the Chemical Society of Japan 86(4), 464-471, 2013
… The most deshielded 13C peaks in fluoranthene frames were observed at 155.7 and 148.7 ppm for 4H+, 154.4 ppm for 5H+, 159.1 and 139.6 ppm for 7H+, and 139.7 ppm for 8H+. …
NAID 130004153200

Steric and Electronic Effects of Substituents on Planar Nickel(II) Complexes: Synthesis, NMR Spectral and Single Crystal X-ray Structural Studies on Nickel(II) Dithiocarbamates with NiS2PN, NiS2PC, and NiS2P2 Chromophores

Arul Prakasam Balasubramaniam,Ramalingam Kuppukkannu,Bocelli Gabriele,Cantoni Andrea
Bulletin of the Chemical Society of Japan 79(1), 113-117, 2006
… In the cyclohexyl ring, the α-CH carbon is deshielded to a greater extent on complexation. …
NAID 130004152000

山本出 [他],藪田五郎,冨澤元博,斉藤隆行,宮本徹,利部伸三
日本農薬学会誌 20(1), 33-40, 1995-02-20
[^3H]α-ブンガロトキシン, [^3H]ニコチンをプローブとしニコチン性アセチルコリン受容体(nAChR)の認識部位へのニコチノイド, ネオニコチノイド, 関連化合物の結合性をみた結果, 昆虫nAChRでは3-ピリジルメチルアミノ部分をもつこと, 脊椎動物nAChRではイオン化度の高いことが必要であった.[^3H]フェンサイクリジンを用いTorpedoのnAChRのイオンチャンネル開口への効果 …
NAID 110001712788