amination

• アミノ化

関

aminate

WordNet

1. (law) the initial questioning of a witness by the party that called the witness

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出典(authority):フリー百科事典『ウィキペディア（Wikipedia）』「2016/04/22 14:48:45」(JST)

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Not to be confused with animation.

Amination is the process by which an amine group is introduced into an organic molecule. This type of reaction is important because organonitrogen compounds are pervasive.

Amination reactions

Enzymes that catalyse this reaction are termed aminases. Amination can occur in a number of ways including reaction with ammonia or another amine such as an alkylation, reductive amination and the Mannich reaction. For example, -COOH --> -CONH₂.

Many alkyl amines are produced industrially by the amination of alcohols using ammonia in the presence of acid catalysts.

In electrophilic amination, the amine as the nucleophile react with another the organic compound as the electrophile. This sense of reactivity may be reversed for some electron-deficient amines, including oxaziridines, hydroxylamines, oximes, and other N–O substrates. When the amine is used as an electrophile, the reaction is called electrophilic amination. Electron-rich organic substrates that may be used as nucleophiles for this process include carbanions and enolates.

In hydroamination, amines add to alkenes.

See also

• Alkylation, the addition of an alkyl group
• Acylation, the addition of an acyl group (-COCH₃)
• Deamination

References

UpToDate Contents

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• 1. B群レンサ球菌感染症予防のための予防接種 vaccines for the prevention of group b streptococcal disease

English Journal

• Deciphering the origin of cooperative catalysis by dirhodium acetate and chiral spiro phosphoric acid in an asymmetric amination reaction.

• Kisan HK1, Sunoj RB.
• Chemical communications (Cambridge, England).Chem Commun (Camb).2014 Dec 4;50(93):14639-42. doi: 10.1039/c4cc05202a. Epub 2014 Oct 14.
• The mechanism of asymmetric amination of diazo-acetate by tert-butyl carbamate catalyzed by dirhodium tetra(trifluoro)acetate and chiral SPINOL-phosphoric acid is examined using DFT (M06 and B3LYP) computations. A cooperative participation of both catalysts is noticed in the stereo-controlling trans
• PMID 25313895

• Biosensor for selective detection of E. coli in spinach using the strong affinity of derivatized mannose with fimbrial lectin.

• Yazgan I1, Noah NM1, Toure O1, Zhang S1, Sadik OA2.
• Biosensors & bioelectronics.Biosens Bioelectron.2014 Nov 15;61:266-73. doi: 10.1016/j.bios.2014.05.008. Epub 2014 May 21.
• Escherichia coli (E. coli) contamination in foods and water resources represents a major threat for human health and the environment. This work exploits the strong affinity of mannose-containing oligosaccharides with the fimbrial lectin of E. coli to design novel biosensors. Modified carbohydrate li
• PMID 24906084

• Genetic Examination and Mass Balance Analysis of Pyruvate/Amino Acid Oxidation Pathways in the Hyperthermophilic Archaeon Thermococcus kodakarensis.

• Nohara K1, Orita I1, Nakamura S1, Imanaka T2, Fukui T3.
• Journal of bacteriology.J Bacteriol.2014 Nov 15;196(22):3831-9. doi: 10.1128/JB.02021-14. Epub 2014 Aug 25.
• The present study investigated the simultaneous oxidation of pyruvate and amino acids during H2-evolving growth of the hyperthermophilic archaeon Thermococcus kodakarensis. The comparison of mass balance between a cytosolic hydrogenase (HYH)-deficient strain (the ΔhyhBGSL strain) and the parent str
• PMID 25157082

Japanese Journal

• SYNTHESIS OF 8-AMINO-(DIHYDROFURAN-FUSED PERHYDROPHENANTHRENE) VIA COPPER-MEDIATED AMINATION REACTION (Dedicated to Professor Victor Snieckus on the occasion of his 77th birthday)

• Sugimoto Kenji,Tamura Kosuke,Toyooka Naoki [他]
• Heterocycles : an international journal for reviews and communications in heterocyclic chemistry 88(1), 755-763, 2014-01-01
• NAID 40019929290

• SYNTHESIS OF MACROBICYCLES COMPRISING 2,7-DIAMINONAPHTHALENE MOIETY VIA PALLADIUM-CATALYZED AMINATION REACTION (Dedicated to Professor Victor Snieckus on the occasion of his 77th birthday)

• Uglov Alexei N.,Zubrienko Georgii A.,Abel Anton S. [他]
• Heterocycles : an international journal for reviews and communications in heterocyclic chemistry 88(2), 1213-1231, 2014-01-01
• NAID 40019928048

• Regioselective N-Methylation of 6-Chloroindolo[3,2-c]quinolines and Their Amination Reactivity at the C-6 Position

• Wang Ning,Imai Kento,Pang Cui-Qing [他]
• Bulletin of the Chemical Society of Japan 86(7), 864-869, 2013-07
• NAID 40019690922

Related Links

• デュボア アミノ化反応 Du Bois Amination | Chem-Station

デュボア アミノ化反応 Du Bois Amination 概要 ロジウム触媒を用いて系中で金属ナイトレノイド(nitrenoid)を生成させ、C-H挿入型アミノ化を行う手法。アルカンの不活性C-Hに窒素官能基を導入できる大変優れた方法。 基本文献

• Amination | Define Amination at Dictionary.com

Amination definition, to introduce an amino group into (a compound). See more. Thesaurus Translator Reference Word of the Day Blog Slideshows Apps by Dictionary My Account Log Out Log In follow Dictionary.com Dictionary ...

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