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出典(authority):フリー百科事典『ウィキペディア(Wikipedia)』「2014/08/22 20:08:41」(JST)
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Zineb |
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IUPAC name
zinc ethane-1,2-diylbis(dithiocarbamate)
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Other names
[[1,2 ethanediylbis[dithiocarbamodithioato](2−)]] zinc,
Dithane Z-78, Aphytora, Amitan
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Identifiers |
CAS number |
12122-67-7 Y |
PubChem |
3032296 |
ChemSpider |
2297309 N |
EC number |
235-180-1 |
KEGG |
C15232 Y |
RTECS number |
ZH3325000 |
Jmol-3D images |
Image 1 |
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[Zn+2].[S-]C(=S)NCCNC(=S)[S-]
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InChI=1S/C4H8N2S4.Zn/c7-3(8)5-1-2-6-4(9)10;/h1-2H2,(H2,5,7,8)(H2,6,9,10);/q;+2/p-2 N
Key: AMHNZOICSMBGDH-UHFFFAOYSA-L N
InChI=1/C4H8N2S4.Zn/c7-3(8)5-1-2-6-4(9)10;/h1-2H2,(H2,5,7,8)(H2,6,9,10);/q;+2/p-2
Key: AMHNZOICSMBGDH-NUQVWONBAD
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Properties |
Molecular formula |
C4H6N2S4Zn |
Molar mass |
275.77 g mol−1 |
Appearance |
pale yellow powder |
Hazards |
EU Index |
006-078-00-2 |
EU classification |
Irritants (Xi)
Sensitizers |
R-phrases |
R37 R43 |
S-phrases |
(S2) S8 S24/25 S46 |
Except where noted otherwise, data are given for materials in their standard state (at 25 °C (77 °F), 100 kPa) |
N (verify) (what is: Y/N?) |
Infobox references |
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Zineb is an organosulfur compound, formally the zinc salt of a bis-dithiocarbamate, which is used as fungicide. It is a pale yellow solid.
Contents
- 1 Synthesis and applications
- 2 See also
- 3 References
- 4 External links
Synthesis and applications
Zineb and is a polymeric complex of zinc with the ethylene bis(dithiocarbamate) anionic ligand.[1] Its uses include control of downy mildews, rusts and redfire disease.[1] It is produced by reacting ethylene bis(dithiocarbamate) sodium salt, "nabam", with zinc sulfate. This procedure can be carried out by mixing nabam and zinc sulfate in the spray tank.[2]
Its uses include control of downy mildews, rusts and redfire disease.[1] In the US it was once registered as a "General Use Pesticide", however all registrations were voluntarily cancelled following an EPA special review.[2] It continues to be used in many other countries. Zineb has been described to interfere with glucocorticoid metabolism, by inhibiting the activity of the enzyme 11beta-hydroxysteroiddehydrogenase type 2, which converts cortisol to cortisone.[3]
See also
- Metam sodium - A related dithiocarbamate salt which is also used as a fungicide
- Maneb - ethylene bis(dithiocarbamate) with manganese instead of zinc
References
- ^ a b c Ullmann's Agrochemicals, Wiley-VCH Staff , Wiley-Vch (COR), 2007 ISBN 3-527-31604-3
- ^ a b Michael A. Kamrin, (1997) Pesticide Profiles: Toxicity, Environmental Impact, and Fate, CRC Press, ISBN 1-56670-190-2
- ^ Atanasov AG, Tam S, Röcken JM, Baker ME,Odermatt A. Inhibition of 11beta-hydroxysteroid dehydrogenase type 2 bydithiocarbamates. Biochem Biophys ResCommun. 2003 Aug 22;308(2):257-62. PubMedPMID: 12901862. http://www.ncbi.nlm.nih.gov/pubmed/12901862
External links
- Pesticide Properties DataBase (PPDB) record for Zineb
English Journal
- Synthesis of nanopesticides by encapsulating pesticide nanoparticles using functionalized carbon nanotubes and application of new nanocomposite for plant disease treatment.
- Sarlak N1, Taherifar A, Salehi F.
- Journal of agricultural and food chemistry.J Agric Food Chem.2014 May 28;62(21):4833-8. doi: 10.1021/jf404720d. Epub 2014 May 15.
- Polymerization of citric acid onto the surface of oxidized multiwall carbon nanotubes led to MWCNT-graft-poly(citric acid) (MWCNT-g-PCA) hybrid materials. Because of the presence of conjugated citric acid branches, synthesized MWCNT-g-PCA hybrid materials were not only soluble in water but also able
- PMID 24832389
- Numerical study of the influence of material parameters on the mechanical behaviour of a rehabilitated edentulous mandible.
- Favot LM1, Berry-Kromer V2, Haboussi M3, Thiebaud F1, Ben Zineb T1.
- Journal of dentistry.J Dent.2014 Mar;42(3):287-97. doi: 10.1016/j.jdent.2013.11.027. Epub 2013 Dec 7.
- OBJECTIVES: The study dealt with full dental prosthetic reconstruction on four implants. The aim was to analyse the influence of material parameters on the mechanical behaviour of the restored mandible compared to the natural mandible.METHODS: A finite element model of an edentulous mandible with pr
- PMID 24321295
- Solid-state UV-MALDI-MS assay of transition metal dithiocarbamate fungicides.
- Ivanova B1, Spiteller M.
- Environmental science and pollution research international.Environ Sci Pollut Res Int.2014 Jan;21(2):1163-77. doi: 10.1007/s11356-013-1837-0. Epub 2013 Jul 24.
- The determination of transition metal containing dithiocarbamate fungicides represents a challenging aspect of analytical object. They have a low stability, low solubility and stabilize versatile coordination monomers, dimers, disulfides and/or S-oxidized derivatives. Their diverse biological activi
- PMID 23881588
Japanese Journal
- Sex ratio and growth performance of gynogenetic diploid barfin flounder Verasper moseri
- Mori Tatsunari,Saito Setsuo,Matsuda Taihei,Kayaba Takaaki,Kishioka Chiharu,Lahrech Zineb,Arai Katsutoshi
- 水産増殖 59(3), 375-382, 2011-09-20
- The effects of rearing temperature and genetic factor on the sex ratio of normal and gynogenetic diploids were examined in barfin flounder Verasper moseri. In addition, growth performance at the age o …
- NAID 120004774853
- マツカワ Verasper moseri 雌性発生二倍体の性比と成長
- 森 立成,齊藤 節雄,松田 泰平 [他],萱場 隆昭,岸岡 稚青,Lahrech Z.,荒井 克俊
- 水産増殖 = The aquiculture 59(3), 375-382, 2011-09-20
- マツカワVerasper moseri雌性発生二倍体及び通常発生群の性比に及ぼす水温と遺伝的要因の影響、並びに成長の違いを調べた。第二極体放出阻止型雌性発生二倍体(G1)および通常発生群の雌比率は、12℃(12.0±0.30)及び14℃(13.6±0.33)飼育群では明確な違いがみられず、16℃(16.1±0.14)飼育群では常に低下した。また、G1の雌比率は7.0~95.1%と雌親魚によって変動 …
- NAID 10029848074
- Rapid and efficient access to meso-2,5-CIS-disubstituted pyrrolidines by double aza-Michael reactions of chiral primary amines
- LeilaCabraldosSantos,Bahlaouan Zineb,Kassimi Khadija El [他]
- Heterocycles 73(-), 751-768, 2007-12-01
- NAID 40015763835
Related Links
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