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Composition-Dependent Electrocatalytic Activity of Palladium-Iridium Binary Alloy Nanoparticles Supported on the Multiwalled Carbon Nanotubes for the Electro-Oxidation of Formic Acid.

Bao J1, Dou M1, Liu H1, Wang F1, Liu J1, Li Z1, Ji J1.
ACS applied materials & interfaces.ACS Appl Mater Interfaces.2015 Jul 10. [Epub ahead of print]
Surface-functionalized multiwalled carbon nanotubes (MWCNTs) supported Pd100-xIrx binary alloy nanoparticles (Pd100-xIrx/MWCNT) with tunable Pd/Ir atomic ratios were synthesized by a thermolytic process at varied ratios of bis(acetylacetonate) palladium(II) and iridium(III) 2,4-pentanedionate precur
PMID 26132867

In search for new bonding modes of the methylenedithiolato ligand: novel tri- and tetra-metallic clusters.

Anju RS1, Saha K, Mondal B, Roisnel T, Halet JF, Ghosh S.
Dalton transactions (Cambridge, England : 2003).Dalton Trans.2015 Jul 7;44(25):11306-13. doi: 10.1039/c5dt00179j. Epub 2015 Feb 27.
Building upon our earlier results on the chemistry of diruthenium analogue of pentaborane (9) with heterocumulenes, we continued to investigate the reactivity of arachno-[(Cp*Ru)2(B3H8)(CS2H)], 1, (Cp* = η(5)-C5Me5) towards group 7 and 8 transition metal carbonyl compounds under photolytic and ther
PMID 25723783

Key study on the potential of hydrazine bisborane for solid- and liquid-state chemical hydrogen storage.

Pylypko S1, Petit E1, Yot PG1, Salles F1, Cretin M1, Miele P1, Demirci UB1.
Inorganic chemistry.Inorg Chem.2015 May 4;54(9):4574-83. doi: 10.1021/acs.inorgchem.5b00569. Epub 2015 Apr 21.
Hydrazine bisborane N2H4(BH3)2 (HBB; 16.8 wt %) recently re-emerged as a potential hydrogen storage material. However, such potential is controversial: HBB was seen as a hazardous compound up to 2010, but now it would be suitable for hydrogen storage. In this context, we focused on fundamentals of H
PMID 25897476