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sparteine sulfate

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出典(authority):フリー百科事典『ウィキペディア(Wikipedia)』「2013/01/20 01:13:18」(JST)

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  • Synthesis of Enantiopure Piperazines via Asymmetric Lithiation-Trapping of N-Boc Piperazines: Unexpected Role of the Electrophile and Distal N-Substituent.
  • Firth JD1, O'Brien P1, Ferris L2.
  • Journal of the American Chemical Society.J Am Chem Soc.2015 Dec 31. [Epub ahead of print]
  • A new method for the synthesis of enantiopure α-substituted piperazines via direct functionalization of the intact piperazine ring is described. The approach utilizes the asymmetric lithiation-substitution of an α-methylbenzyl-functionalized N-Boc piperazine using s-BuLi/(-)-sparteine or (+)-spart
  • PMID 26683825
  • Flowing atmospheric pressure afterglow combined with laser ablation for direct analysis of compounds separated by thin-layer chromatography.
  • Cegłowski M1, Smoluch M2, Reszke E3, Silberring J2,4, Schroeder G5.
  • Analytical and bioanalytical chemistry.Anal Bioanal Chem.2015 Nov 12. [Epub ahead of print]
  • A thin-layer chromatography-mass spectrometry (TLC-MS) setup for characterization of low molecular weight compounds separated on standard TLC plates has been constructed. This new approach successfully combines TLC separation, laser ablation, and ionization using flowing atmospheric pressure aftergl
  • PMID 26563110
  • The Use of (-)-Sparteine/Organolithium Reagents for the Enantioselective Lithiation of 7,8-Dipropyltetrathia[7]helicene: Single and Double Kinetic Resolution Procedures.
  • Doulcet J1, Stephenson GR2.
  • Chemistry (Weinheim an der Bergstrasse, Germany).Chemistry.2015 Nov 12. doi: 10.1002/chem.201502958. [Epub ahead of print]
  • The effect of organolithium reagent (RLi: R=nBu, iPr, sBu, tBu), solvent (diethyl ether, diethyl ether/THF and MTBE), and stoichiometry on the (-)-sparteine-mediated silylation of 7,8-dipropyltetrathia[7]helicene shows that, unusually, substantially more than 0.5 equivalent of RLi (R=iPr, sBu, tBu)
  • PMID 26560342


  • Bis(μ-iodo)bis[(-)-sparteine]-dicopper : A Versatile Catalyst for Direct O-Arylation and O-Alkylation of Phenols and Aliphatic Alcohols with Haloarenes
  • Satyanarayana Ponnam,Maheswaran Hariharasarma,Kantam Mannepalli Lakshmi [他],BHARGAVA Suresh
  • Bulletin of the Chemical Society of Japan 84(7), 788-790, 2011-07-15
  • NAID 10029279998
  • Magnetostructural Property of a Twisted Bis($\mu$-hydroxo) Dicopper(II) Core and Its Relevance to Formation of an Active Dioxygen Intermediate
  • Funahashi Yasuhiro,Toyama Tomoaki,Yoshii Kotaro [他],Nishikawa Tomohide,Kishida Mitsumi,Kajita Yuji,Inomata Tomohiko,Ozawa Tomohiro,Wasada-Tsutsui Yuko,Masuda Hideki
  • Jpn J Appl Phys 50(1), 01AJ07-01AJ07-4, 2011-01-25
  • … A precursor compound of a dioxygen adduct, [Cu\text{II2(Sp)2($\mu$-OH)2](ClO4)2$\Cdot$CH2Cl2 (Sp = $(-)$-sparteine) (1$\Cdot$(ClO4)2$\Cdot$CH2Cl2), has been investigated by X-ray structural analysis, magnetic measurement, and molecular orbital calculations. …
  • NAID 150000055177
  • Chiral Ligand Controlled Helix-sense-selective Atom Transfer Radical Polymerization of 1-Phenyldibenzosuberyl Methacrylate
  • , , , , ,
  • Chemistry Letters 40(6), 651-653, 2011
  • … The atom transfer radical polymerization (ATRP) of 1-phenyldibenzosuberyl methacrylate was carried out using (−)-sparteine (SP) as ligand. …
  • NAID 130004426244


[(-)-Sparteine] [90-39-1] | 価格や在庫、物性値などの詳細情報ページです。 ... ・川口の在庫は即日,つくばの在庫は2〜3日以内の出荷となります。・詳細につきましては,お手数ですが営業部までお問い合わせください。
Sigma-Aldrich offers Aldrich-415316, (−)-Sparteine for your research needs. Find product specific information including CAS, MSDS, protocols and references. ... Application Controls asymmetric lithiation/alkylation of prochiral ...



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