WordNet
- a chemical agent for use in chemical reactions
PrepTutorEJDIC
- (化学実験の)試薬
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- 1. サルコイドーシスの病因 pathogenesis of sarcoidosis
- 2. 空腹時ケトアシドーシスおよびアルコール性ケトアシドーシス fasting ketosis and alcoholic ketoacidosis
- 3. 血清ビリルビン定量の臨床的側面 clinical aspects of serum bilirubin determination
- 4. 肺サルコイドーシスの臨床症状および診断 clinical manifestations and diagnosis of pulmonary sarcoidosis
- 5. 成人における糖尿病性ケトアシドーシスおよび高浸透圧性高血糖状態：臨床的特徴、評価、および診断 diabetic ketoacidosis and hyperosmolar hyperglycemic state in adults clinical features evaluation and diagnosis
English Journal
- Synthesis of Aryl Tri- and Difluoromethyl Thioethers via a CH-Thiocyanation/Fluoroalkylation Cascade.
- Jouvin K1, Matheis C1, Goossen LJ2.
- Chemistry (Weinheim an der Bergstrasse, Germany).Chemistry.2015 Oct 5;21(41):14324-7. doi: 10.1002/chem.201502914. Epub 2015 Sep 1.
- An AlCl3 -catalyzed CH thiocyanation was discovered and combined with a Langlois-type trifluoromethylation to afford aryl trifluoromethyl thioethers directly from arenes, N-thiocyanatosuccinimide (NTS) and Ruppert-Prakash reagent. An analogous combination with a copper-mediated difluoromethylatio
- PMID 26332514
- Stereo- and Chemodivergent NHC-Promoted Functionalisation of Arylalkylketenes with Chloral.
- Douglas JJ1,2, Churchill G3, Slawin AM1, Fox DJ4, Smith AD5.
- Chemistry (Weinheim an der Bergstrasse, Germany).Chemistry.2015 Sep 25. doi: 10.1002/chem.201503308. [Epub ahead of print]
- Stereo- and chemodivergent enantioselective reaction pathways are observed upon treatment of alkylarylketenes and trichloroacetaldehyde (chloral) with N-heterocyclic carbenes, giving selectively either β-lactones (up to 88:12 dr, up to 94 % ee) or α-chloroesters (up to 94 % ee). Either 2
- PMID 26406613
- Synthesis of Multisubstituted Triphenylenes and Phenanthrenes by Cascade Reaction of o-Iodobiphenyls or (Z)-β-Halostyrenes with o-Bromobenzyl Alcohols through Two Sequential C-C Bond Formations Catalyzed by a Palladium Complex.
- Iwasaki M1, Araki Y1, Iino S1, Nishihara Y1,2.
- The Journal of organic chemistry.J Org Chem.2015 Sep 18;80(18):9247-63. doi: 10.1021/acs.joc.5b01693. Epub 2015 Sep 4.
- o-Bromobenzyl alcohol has been developed as a novel annulating reagent, bearing both nucleophilic and electrophilic substituents, for the facile synthesis of polycyclic aromatic hydrocarbons. A palladium/electron-deficient phosphine catalyst efficiently coupled o-iodobiphenyls or (Z)-β-halostyrenes
- PMID 26322586
Japanese Journal
- 非共平面的に芳香環が集積した分子群に関する特異な反応挙動の解析とその空間構造の特徴解明
- 岡本 昭子,米澤 宣行
- 有機合成化学協会誌 73(4), 339-360, 2015
- … Synthesis of 1-aroylated and 1,8-diaroylated derivatives of 2,7-dimethoxynaphthalene was successfully performed by the action of arenecarboxylic acids or their chlorides with the aid of adequate acidic mediator: Lewis/Brønsted acid or direct condensation reagent. …
- NAID 130005070686
- グルタチオントランスフェラーゼを標的とした分子プローブの開発
- 伊藤 美香,周東 智,伊藤 嘉浩,阿部 洋
- 有機合成化学協会誌 72(7), 822-831, 2014
- … Glutathione S-transferase (GST) are phase II enzymes that catalyze the nucleophilic attack of glutathione (GSH) to a wide range of hydrophobic and electrophilic compounds. … Recently, we found that the electrophilic centre in the dinitrobenzenesulfonamide derivative is attacked by GSH and that this reaction is catalyzed by GST releasing the strong fluorophore. …
- NAID 130004679612
- 可視光（太陽光）促進有機金属触媒反応：フォトレドックス触媒と機能分担型二核錯体触媒系
- 穐田 宗隆,小池 隆司,稲垣 昭子
- 有機合成化学協会誌 72(5), 538-547, 2014
- … The former is effective for generation of radical species from electron-rich substrates such as amine and organoborate, whereas the latter providing carbon-centered radicals is effective for C-C bond formation, in particular, C-CF3 bond formation by the action of electrophilic trifluoromethylating reagents. …
- NAID 130004548604
Related Links
- In general, electrophiles are positively charged species that are attracted to an electron rich centre. In chemistry, an electrophile (literally electron-lover) is a reagent attracted to electrons that participates in a chemical reaction by accepting an ...
Related Pictures
★リンクテーブル★
| リンク元 | 「求電子試薬」「求電子剤」「electrophile」 |
| 関連記事 | 「electrophilic」「reagent」 |
「求電子試薬」
- 英
- electrophile、electrophilic reagent
- 同
- 求電子剤、親電子試薬、陽性試薬 cationoid reagent
- 関
- 求核試薬
「求電子剤」
「electrophile」
「electrophilic」
- 求電子性の、求電子の、親電子の
「reagent」