WordNet

(chemistry) of or relating to or containing one or more benzene rings; "an aromatic organic compound"
having a strong pleasant odor; "the pine woods were more redolent"- Jean Stafford (同)redolent
a compound derived from ammonia by replacing hydrogen atoms by univalent hydrocarbon radicals (同)aminoalkane

PrepTutorEJDIC

かおりの高い,かんばしい

Wikipedia preview

出典(authority):フリー百科事典『ウィキペディア（Wikipedia）』「2013/10/19 05:56:10」(JST)

wiki en

An aromatic amine is an amine with an aromatic substituent—that is -NH₂, -NH- or nitrogen group(s) attached to an aromatic hydrocarbon, whose structure usually contains one or more benzene rings. Aniline is the simplest example.

Aromatic amines, when protonated, usually have lower pKas (are more acidic) than their non-aromatic analogs. This is due to the delocalization of the lone pair of electrons from the nitrogen into the ring.

Representative anilines
Aromatic amine	CAS number	Properties	Uses
Aniline	62-53-3
o-Toluidine	95-53-4
2,4,6-Trimethylaniline	88-05-1
Anisidine	90-04-0
3-Trifluoromethylaniline	98-16-8		Intermediate for herbicides, metabolite
N-Methylaniline	100-61-8

The general population is exposed to aromatic amines through the diet (e.g. pesticides), pharmaceuticals (e.g. prilocain), hair dyes, smoking, and diesel engine exhaust, as well as through occupational exposure at the workplace (e.g. rubber, textiles, dye industries).^[1]

Aromatic amines in textiles[edit]

Since August 2012, the new standard EN 14362-1:2012 Textiles - Methods for determination of certain aromatic amines derived from azo colorants - Part 1: Detection of the use of certain azo colorants accessible with and without extracting the fibres is effective. It had been officially approved by the European Committee for Standardization (CEN) and supersedes the test standards EN 14362-1: 2003 and EN 14362-2: 2003.

The standard describes a procedure to detect EU banned aromatic amines derived from azo colorants in textile fibres, including natural, man-made, regenerated, and blended fibres. The standard is also relevant for all coloured textiles, e.g. dyed, printed, and coated textiles.^[2]

References[edit]

^ Exposure to Aromatic Amines - Overview on Chemistry Presentation by A. Seidel (2009), Retrieved 09/24/2012
^ New European Standard for Aromatic Amines Derived from Azo Colorants SGS SafeGuard Bulletin, Retrieved 09/24/2012

UpToDate Contents

全文を閲覧するには購読必要です。 To read the full text you will need to subscribe.

1. 食物アレルギーの臨床症状：概要 clinical manifestations of food allergy an overview
2. 膣炎症状が認められる女性に対するアプローチ approach to women with symptoms of vaginitis
3. 気管支神経内分泌（カルチノイド）腫瘍：疫学、危険因子、分類、組織学的検査、診断、および病期分類 bronchial neuroendocrine carcinoid tumors epidemiology risk factors classification histology diagnosis and staging
4. Bacterial vaginosis
5. 非HIV感染患者におけるスルホンアミドアレルギー sulfonamide allergy in non hiv infected patients

English Journal

Determination of mutagenic amines in water and food samples by high pressure liquid chromatography with amperometric detection using a multiwall carbon nanotubes-glassy carbon electrode.

Bueno AM1, Marín MÁ1, Contento AM1, Ríos Á2.
Food chemistry.Food Chem.2016 Feb 1;192:343-50. doi: 10.1016/j.foodchem.2015.07.026. Epub 2015 Jul 8.
A chromatographic method, using amperometric detection, for the sensitive determination of six representative mutagenic amines was developed. A glassy carbon electrode (GCE), modified with multiwall carbon nanotubes (GCE-CNTs), was prepared and its response compared to a conventional glassy carbon e
PMID 26304357

Evaluation and application of microwave-assisted extraction and dispersive liquid-liquid microextraction followed by high-performance liquid chromatography for the determination of polar heterocyclic aromatic amines in hamburger patties.

Aeenehvand S1, Toudehrousta Z1, Kamankesh M2, Mashayekh M1, Tavakoli HR3, Mohammadi A4.
Food chemistry.Food Chem.2016 Jan 1;190:429-35. doi: 10.1016/j.foodchem.2015.05.103. Epub 2015 May 27.
This study developed an analytical method based on microwave-assisted extraction and dispersive liquid-liquid microextraction followed by high-performance liquid chromatography for the determination of three polar heterocyclic aromatic amines from hamburger patties. Effective parameters controlling
PMID 26212992

Effect of an azo dye on the performance of an aerobic granular sludge sequencing batch reactor treating a simulated textile wastewater.

Franca RD1, Vieira A2, Mata AM3, Carvalho GS4, Pinheiro HM5, Lourenço ND6.
Water research.Water Res.2015 Nov 15;85:327-36. doi: 10.1016/j.watres.2015.08.043. Epub 2015 Aug 28.
This study analyzed the effect of an azo dye (Acid Red 14) on the performance of an aerobic granular sludge (AGS) sequencing batch reactor (SBR) system operated with 6-h anaerobic-aerobic cycles for the treatment of a synthetic textile wastewater. In this sense, two SBRs inoculated with AGS from a d
PMID 26343991

Japanese Journal

Paraphenylene diamine exacerbates platelet aggregation and thrombus formation in response to a low dose of collagen

The Journal of Toxicological Sciences 41(1), 123-128, 2016
NAID 130005119786

Determination of human serum semicarbazide-sensitive amine oxidase activity via flow injection analysis with fluorescence detection after online derivatization of the enzymatically produced benzaldehyde with 1,2-diaminoanthraquinone